Citation: LU Yun, ZHANG Deng, FAN Xin-Rong, WAN Hong-Xiang, XU Yan. Synthesis，Structural Characterization and Properties of Two New Layered Lanthanide Sulfates Containing 12-Membered-Rings[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(12): 2623-2630. doi: 10.3969/j.issn.1001-4861.2013.00.381 shu

Synthesis，Structural Characterization and Properties of Two New Layered Lanthanide Sulfates Containing 12-Membered-Rings

1.
1 College of Chemistry and Chemical Engineering, State Key Laboratory of Materials-oriented Chemical Engineering, Nanjing University of Technology, Nanjing 210009, China;

Received Date: 6 December 2012
Available Online: 4 May 2013
Fund Project: 教育部博士点新教师基金(No.20113221120002) (No.20113221120002)江苏省科技厅自然科学基金(No.BK2012823)资助项目。 (No.BK2012823)

Employing solvothermal method, two new lanthanide sulfates [Tb₂(SO₄)₅][(CH₃)₂NH₂]₄(1) and [Y₂(SO₄)₅][(CH₃)₂NH₂]₄(2) with two-dimensional layered structures have been synthesized and characterized by single-crystal XRD, ICP, IR and TGA. Both of the two compounds crystallize in the triclinic space group p1. Crystal data for 1, a=0.988 7(3) nm, b=1.106 1(3) nm, c=1.535 4(4) nm, α=70.45(4)°, β=75.12(3)°, γ=67.11(3)°, Z=2. For 2, a=0.9816(5) nm, b=1.100 1(5) nm, c=1.528 6(8) nm, α=70.44(6)°, β=75.45(6)°, γ=67.48(6)°, Z=2. Crystal structure analysis reveals that both of the inorganic frameworks of Compound 1 and 2 have layered two-dimensional architectures which are formed by two types of double stranded chains and 12-membered rings (12MRs). The solid state luminescent properties of compounds 1 were investigated and it displays a typical luminescent property of Tb³⁺ with excitation wavelength at 369 nm. CCDC: 941147, 1; 941148 2.
- solvothermal method;lanthanide sulfate;crystal structure;luminescent
1. [1]
  [1] Cheetham A K, Ferey G, Loiseau T. Angew. Chem., 1999, 38:3268
2. [2]
  [2] Rao C N R, Natarajan S, Choudhury A, et al. Acc. Chem. Res., 2001, 34:80-87
3. [3]
  [3] Meier W M, Oslon D H, Baerlocher C. Atlas of Zeolite Structure Types. Amsterdam: Elsevier, 1996.
4. [4]
  [4] Li C, Huang K L, Chi Y N, et al. Inorg. Chem., 2006, 48: 2012-2017
5. [5]
  [5] Xie L H, Liu S X, Gao C Y, et al. Inorg. Chem., 2007, 46: 7782-7788
6. [6]
  [6] Choudhury A, Kumar U, Rao C N R, et al. Angew. Chem. Int. Ed., 2002, 41:185-185
7. [7]
  [7] Harrison W T, Phillips M L, Stanchfield J, et al. Angew. Chem., 2000, 39:3808-3810
8. [8]
  [8] Rao C N R, Behera J N, Dan M. Chem. Soc. Rev., 2006, 35: 375
9. [9]
  [9] Zhang D, Lu Y, Xu Y, et al. Inorg. Chem., 2013, 52:3253-3258
10. [10]
  [10] Zheng L, Zhang Z B, Zhu D R, et al. Inorg. Chem. Commun., 2011, 14:258-260
11. [11]
  [11] Zheng L, Qiu X M, Xu Y, et al. CrystEngComm, 2011, 13: 2714-2720
12. [12]
  [12] Choudhury A, Krishnamoorthy J, Rao C N R. Chem. Commun., 2001:2610-2611
13. [13]
  [13] Yaghi O′M, O Keefe M, Ockwig N W, et al. Nature, 2003, 423: 705-714
14. [14]
  [14] Zheng L, Qiu X M, Zhang Z B, et al. Inorg. Chem. Commun., 2011, 14:906-909
15. [15]
  [15] LI Hui (李辉), ZHU Ya-Lin (朱亚林), ZHENG Lei (郑磊), et al. Chinese J. Inorg. Chem. (Wuji Huaxue Xuebao), 2011, 12:2453-2458
16. [16]
  [16] ZHOU Wan-Li (周万里), XU Yan (许岩). Chinese J. Inorg. Chem. (Wuji Huaxue Xuebao), 2011, 27:2507-2512
17. [17]
  [17] Zheng L, Xu Y, Zhang X L, et al. CrystEngComm, 2010, 12: 694-696
18. [18]
  [18] Zhou W L, Ding X R, Zhang Z B, et al. Z. Anorg. Allg. Chem., 2009, 636:882-885
19. [19]
  [19] Xu Y, Ding S, Zheng X. J. Solid State Chem., 2007, 180: 2020-2023
20. [20]
  [20] Zhang Q, Lu C, Yang W, et al. Inorg. Chem. Commun., 2004, 7:889-894
21. [21]
  [21] Ding S H, Xu Y, Nie L B, et al. J. Cluster. Sci., 2006, 17: 627-636
22. [22]
  [22] Ju W W, Zhang D, Zhu D R, et al. Inorg. Chem., 2012, 51: 13373-13379
23. [23]
  [23] Zhang D, Zheng L, Qiu X M, et al. RSC Advances, 2012, 2: 217-225
24. [24]
  [24] Zhu Y L, Sun X C, Zhu D R, et al. Inorg. Chim. Acta, 2009, 362:2565-2568
25. [25]
  [25] Zhou W L, Chen Q, Zhu D R, et al. Z. Anorg. Allg. Chem., 2009, 635:572-576
26. [26]
  [26] Zhou W L, Chen Q, Jiang N, et al. Inorg. Chim. Acta, 2009, 362:3299-3302
27. [27]
  [27] Zhou W L, Xu Y, Han L J, et al. Dalton Trans., 2010, 39: 3681-3686
28. [28]
  [28] Sheldrick G M. SHELXTL version 5.10, Bruker AXS Inc., Madsion, Wisconsion, USA, 1997.
29. [29]
  [29] Wang D, Yu R B, Wang H, et al. Microporous Mesoporous Mater., 2007, 101:66-72
30. [30]
  [30] Song J L, Zhao H H, Mao J G, et al. Chem. Mater., 2004, 16:1884-1889
31. [31]
  [31] Zhang D, Lu Y, Xu Y, et al. CrystEngComm, 2012, 14:6627-6638
32. [32]
  [32] de Lill D T, de Bettencourt-Dias A, Cahill C L, et al. Inorg. Chem., 2007, 46:3960-3965
33. [33]
  [33] ZHANG Deng (张登), LU Yun (吕赟), XU Xin (许新). Chinese J. Inorg. Chem. (Wuji Huaxue Xuebao), 2012, 28: 1298-1304
34. [34]
  [34] LI Hui (李辉), ZHENG Lei (郑磊), ZHANG Deng (张登), et al. Chinese J. Inorg. Chem. (Wuji Huaxue Xuebao), 2012, 28:1477-1482
1. [1]
  Xinting XIONG , Zhiqiang XIONG , Panlei XIAO , Xuliang NIE , Xiuying SONG , Xiuguang YI . Synthesis, crystal structures, Hirshfeld surface analysis, and antifungal activity of two complexes Na(Ⅰ)/Cd(Ⅱ) assembled by 5-bromo-2-hydroxybenzoic acid ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1661-1670. doi: 10.11862/CJIC.20240145
2. [2]
  Xin MA , Ya SUN , Na SUN , Qian KANG , Jiajia ZHANG , Ruitao ZHU , Xiaoli GAO . A Tb₂ complex based on polydentate Schiff base: Crystal structure, fluorescence properties, and biological activity. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1347-1356. doi: 10.11862/CJIC.20230357
3. [3]
  Jingjing QING , Fan HE , Zhihui LIU , Shuaipeng HOU , Ya LIU , Yifan JIANG , Mengting TAN , Lifang HE , Fuxing ZHANG , Xiaoming ZHU . Synthesis, structure, and anticancer activity of two complexes of dimethylglyoxime organotin. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1301-1308. doi: 10.11862/CJIC.20240003
4. [4]
  Xiaoling LUO , Pintian ZOU , Xiaoyan WANG , Zheng LIU , Xiangfei KONG , Qun TANG , Sheng WANG . Synthesis, crystal structures, and properties of lanthanide metal-organic frameworks based on 2, 5-dibromoterephthalic acid ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1143-1150. doi: 10.11862/CJIC.20230271
5. [5]
  Haitang WANG , Yanni LING , Xiaqing MA , Yuxin CHEN , Rui ZHANG , Keyi WANG , Ying ZHANG , Wenmin WANG . Construction, crystal structures, and biological activities of two Ln^Ⅲ₃ complexes. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1474-1482. doi: 10.11862/CJIC.20240188
6. [6]
  Yingchun ZHANG , Yiwei SHI , Ruijie YANG , Xin WANG , Zhiguo SONG , Min WANG . Dual ligands manganese complexes based on benzene sulfonic acid and 2, 2′-bipyridine: Structure and catalytic properties and mechanism in Mannich reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1501-1510. doi: 10.11862/CJIC.20240078
7. [7]
  Zhaoyang WANG , Chun YANG , Yaoyao Song , Na HAN , Xiaomeng LIU , Qinglun WANG . Lanthanide(Ⅲ) complexes derived from 4′-(2-pyridyl)-2, 2′∶6′, 2″-terpyridine: Crystal structures, fluorescent and magnetic properties. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1442-1451. doi: 10.11862/CJIC.20240114
8. [8]
  Shuwen SUN , Gaofeng WANG . Two cadmium coordination polymers constructed by varying Ⅴ-shaped co-ligands: Syntheses, structures, and fluorescence properties. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 613-620. doi: 10.11862/CJIC.20230368
9. [9]
  Yonghui ZHOU , Rujun HUANG , Dongchao YAO , Aiwei ZHANG , Yuhang SUN , Zhujun CHEN , Baisong ZHU , Youxuan ZHENG . Synthesis and photoelectric properties of fluorescence materials with electron donor-acceptor structures based on quinoxaline and pyridinopyrazine, carbazole, and diphenylamine derivatives. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 701-712. doi: 10.11862/CJIC.20230373
10. [10]
  Huan ZHANG , Jijiang WANG , Guang FAN , Long TANG , Erlin YUE , Chao BAI , Xiao WANG , Yuqi ZHANG . A highly stable cadmium(Ⅱ) metal-organic framework for detecting tetracycline and p-nitrophenol. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 646-654. doi: 10.11862/CJIC.20230291
11. [11]
  Ruikui YAN , Xiaoli CHEN , Miao CAI , Jing REN , Huali CUI , Hua YANG , Jijiang WANG . Design, synthesis, and fluorescence sensing performance of highly sensitive and multi-response lanthanide metal-organic frameworks. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 834-848. doi: 10.11862/CJIC.20230301
12. [12]
  Xiaoxia WANG , Ya'nan GUO , Feng SU , Chun HAN , Long SUN . Synthesis, structure, and electrocatalytic oxygen reduction reaction properties of metal antimony-based chalcogenide clusters. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1201-1208. doi: 10.11862/CJIC.20230478
13. [13]
  Lu LIU , Huijie WANG , Haitong WANG , Ying LI . Crystal structure of a two-dimensional Cd(Ⅱ) complex and its fluorescence recognition of p-nitrophenol, tetracycline, 2, 6-dichloro-4-nitroaniline. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1180-1188. doi: 10.11862/CJIC.20230489
14. [14]
  Kaimin WANG , Xiong GU , Na DENG , Hongmei YU , Yanqin YE , Yulu MA . Synthesis, structure, fluorescence properties, and Hirshfeld surface analysis of three Zn(Ⅱ)/Cu(Ⅱ) complexes based on 5-(dimethylamino) isophthalic acid. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1397-1408. doi: 10.11862/CJIC.20240009
15. [15]
  Meirong HAN , Xiaoyang WEI , Sisi FENG , Yuting BAI . A zinc-based metal-organic framework for fluorescence detection of trace Cu²⁺. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1603-1614. doi: 10.11862/CJIC.20240150
16. [16]
  Shuyan ZHAO . Field-induced Co^Ⅱ single-ion magnet with pentagonal bipyramidal configuration. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1583-1591. doi: 10.11862/CJIC.20240231
17. [17]
  Siyi ZHONG , Xiaowen LIN , Jiaxin LIU , Ruyi WANG , Tao LIANG , Zhengfeng DENG , Ao ZHONG , Cuiping HAN . Targeting imaging and detection of ovarian cancer cells based on fluorescent magnetic carbon dots. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1483-1490. doi: 10.11862/CJIC.20240093
18. [18]
  Peiran ZHAO , Yuqian LIU , Cheng HE , Chunying DUAN . A functionalized Eu³⁺ metal-organic framework for selective fluorescent detection of pyrene. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 713-724. doi: 10.11862/CJIC.20230355
19. [19]
  Jiakun BAI , Ting XU , Lu ZHANG , Jiang PENG , Yuqiang LI , Junhui JIA . A red-emitting fluorescent probe with a large Stokes shift for selective detection of hypochlorous acid. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1095-1104. doi: 10.11862/CJIC.20240002
20. [20]
  Jinlong YAN , Weina WU , Yuan WANG . A simple Schiff base probe for the fluorescent turn-on detection of hypochlorite and its biological imaging application. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1653-1660. doi: 10.11862/CJIC.20240154

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(306)
HTML views(42)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142