Citation: QI Jin-Li, ZHENG Yue-Qing, XU Wei. Use of p-Formylbenzoate to Construct two Copper(Ⅱ) Complexes:Syntheses, Crystal Structures and Magnetic Properties[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(11): 2405-2414. doi: 10.3969/j.issn.1001-4861.2013.00.380
-
Two new Cu(Ⅱ) complexes, [Cu(phen)(H2O)(fba)(ClO4)]·H2O (1) and ∞1[Cu(bpy)(H2O)(fba)2](2)(phen=phenanthroline, bpy=2,2'-bipyridine Hfba=p-formylbenzoic acid) were synthesized by solution-based method and characterized by single-crystal, powder X-ray diffraction methods, IR spectroscopy, TG-DTAanalyses, elemental analyses, and magnetic measurements. Compound 1 is a mononuclear structure crystallizing in the space group P1 and 2 shows a 1D chain structure which belongs to the space group Pbca. Through non-covalent interactions the complex molecules are assembled into 3D supramolecular network structures. The variable temperature magnetic measurements of 1 shows a weak ferromagnetic and antiferromagnetic behavior in the range of 300~7 and 7~2 K, respectively, while the 2's suggests very weak ferromagnetic interactions between Cu(Ⅱ) ions in the experimental temperature range. CCDC: 912745, 1;CCDC: 912746, 2.
-
-
[1]
[1] Dimiza F, Papadopoulos A N, Tangoulis V, et al. J. Inorg. Biochem., 2012,107:54-64
-
[2]
[2] ZHOU Hong(周宏), YU Shan-Shan(于珊珊), DUAN Hai-Bao (段海宝), et. al. Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2013,29(7):1357-1384
-
[3]
[3] LI Qing-Xiang(李庆祥), XIANG Ai-Hua(向爱华), MENG Xiang-Gao(孟祥高). Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2013,29(7):1428-1432
-
[4]
[4] Xu W, Liu W, Yang Y F, et al. Inorg. Chim. Acta, 2011, 365:297-301
-
[5]
[5] Zhou X X, Liu M S, Lin X M, et al. Inorg. Chim. Acta, 2009,362:1441-1447
-
[6]
[6] Dimiza F, Papadopoulos A N, Tangoulis V, et al. J. Inorg. Biochem., 2012,107:54-64
-
[7]
[7] KUANG Yun-Fei(邝云飞), LI Chang-Hong(李昶红), LI Wei (李薇), et al. Chinese. J. Struct. Chem.(Jiegou Huaxue), 2007,26(7):749-752
-
[8]
[8] Hou G G, Ma J P, Wang L, et al. CrystEngComm, 2010,12: 4287-4303
-
[9]
[9] Jian F F, Wang Z X, Bai Z P, et al. Transition Met. Chem., 1999,24(5):589-594
-
[10]
[10]Baca S G, Simonov Y A, Gdaniec M, et al. Inorg. Chem. Commun., 2003,6:685-689
-
[11]
[11]Sertcelik M, Tercan B, Sahin E, et al. Acta Cryst., 2009, E65:m326-m327
-
[12]
[12]Deng Z P, Gao S, Ng S W. Acta Cryst., 2006,E62:m2904-m2905
-
[13]
[13]Deng Z P, Gao S, Huo L H, et al. Acta Cryst., 2007,E63: m2818
-
[14]
[14]Dimiza F, Perdih F, Tangoulis V, et al. J. Inorg. Biochem., 2011,105:476-489
-
[15]
[15]Moncol J, Jomova K, Porubska M. Acta Cryst., 2012,C68: m85-m89
-
[16]
[16]LI Wei(李薇), LI Chang-Hong(李昶红), YANG Ying-Qun(杨 颖群), et al. Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2006,22(1):101-105
-
[17]
[17]Qi J L, Xu W. Acta Cryst., 2012,E68:m1062-m1063
-
[18]
[18]Qi J L, Xu W, Zheng Y Q. Z. Naturforsch., 2012,67b:1185-1190
-
[19]
[19]Sheldrick G M. SHELXS-97, Program for the Solution of Crystal Structure, Germany: University of Göttingen, 1997.
-
[20]
[20]Sheldrick G M. SHELXL-97, Program for the Refinement of Crystal Structure, Germany: University of Göttingen, 1997.
-
[21]
[21]Addison A W, Rao N. J. Chem. Soc., Dalton Trans., 1984: 1349-1356
-
[22]
[22]Nakamoto K. Infrared and Rama Spectra of Inorganic and Coordination Compounds. 4th Ed. New York: Wiley, 1986.
-
[23]
[23]Hall J W. Theses for the Doctorate of University of North Carolina. 1977.
-
[1]
-
-
[1]
Xinting XIONG , Zhiqiang XIONG , Panlei XIAO , Xuliang NIE , Xiuying SONG , Xiuguang YI . Synthesis, crystal structures, Hirshfeld surface analysis, and antifungal activity of two complexes Na(Ⅰ)/Cd(Ⅱ) assembled by 5-bromo-2-hydroxybenzoic acid ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1661-1670. doi: 10.11862/CJIC.20240145
-
[2]
Xiaoling LUO , Pintian ZOU , Xiaoyan WANG , Zheng LIU , Xiangfei KONG , Qun TANG , Sheng WANG . Synthesis, crystal structures, and properties of lanthanide metal-organic frameworks based on 2, 5-dibromoterephthalic acid ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1143-1150. doi: 10.11862/CJIC.20230271
-
[3]
Jingjing QING , Fan HE , Zhihui LIU , Shuaipeng HOU , Ya LIU , Yifan JIANG , Mengting TAN , Lifang HE , Fuxing ZHANG , Xiaoming ZHU . Synthesis, structure, and anticancer activity of two complexes of dimethylglyoxime organotin. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1301-1308. doi: 10.11862/CJIC.20240003
-
[4]
Xin MA , Ya SUN , Na SUN , Qian KANG , Jiajia ZHANG , Ruitao ZHU , Xiaoli GAO . A Tb2 complex based on polydentate Schiff base: Crystal structure, fluorescence properties, and biological activity. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1347-1356. doi: 10.11862/CJIC.20230357
-
[5]
Haitang WANG , Yanni LING , Xiaqing MA , Yuxin CHEN , Rui ZHANG , Keyi WANG , Ying ZHANG , Wenmin WANG . Construction, crystal structures, and biological activities of two LnⅢ3 complexes. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1474-1482. doi: 10.11862/CJIC.20240188
-
[6]
Yingchun ZHANG , Yiwei SHI , Ruijie YANG , Xin WANG , Zhiguo SONG , Min WANG . Dual ligands manganese complexes based on benzene sulfonic acid and 2, 2′-bipyridine: Structure and catalytic properties and mechanism in Mannich reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1501-1510. doi: 10.11862/CJIC.20240078
-
[7]
Shuyan ZHAO . Field-induced CoⅡ single-ion magnet with pentagonal bipyramidal configuration. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1583-1591. doi: 10.11862/CJIC.20240231
-
[8]
Zhaoyang WANG , Chun YANG , Yaoyao Song , Na HAN , Xiaomeng LIU , Qinglun WANG . Lanthanide(Ⅲ) complexes derived from 4′-(2-pyridyl)-2, 2′∶6′, 2″-terpyridine: Crystal structures, fluorescent and magnetic properties. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1442-1451. doi: 10.11862/CJIC.20240114
-
[9]
Huan ZHANG , Jijiang WANG , Guang FAN , Long TANG , Erlin YUE , Chao BAI , Xiao WANG , Yuqi ZHANG . A highly stable cadmium(Ⅱ) metal-organic framework for detecting tetracycline and p-nitrophenol. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 646-654. doi: 10.11862/CJIC.20230291
-
[10]
Ruikui YAN , Xiaoli CHEN , Miao CAI , Jing REN , Huali CUI , Hua YANG , Jijiang WANG . Design, synthesis, and fluorescence sensing performance of highly sensitive and multi-response lanthanide metal-organic frameworks. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 834-848. doi: 10.11862/CJIC.20230301
-
[11]
Xiaoxia WANG , Ya'nan GUO , Feng SU , Chun HAN , Long SUN . Synthesis, structure, and electrocatalytic oxygen reduction reaction properties of metal antimony-based chalcogenide clusters. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1201-1208. doi: 10.11862/CJIC.20230478
-
[12]
Lu LIU , Huijie WANG , Haitong WANG , Ying LI . Crystal structure of a two-dimensional Cd(Ⅱ) complex and its fluorescence recognition of p-nitrophenol, tetracycline, 2, 6-dichloro-4-nitroaniline. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1180-1188. doi: 10.11862/CJIC.20230489
-
[13]
Kaimin WANG , Xiong GU , Na DENG , Hongmei YU , Yanqin YE , Yulu MA . Synthesis, structure, fluorescence properties, and Hirshfeld surface analysis of three Zn(Ⅱ)/Cu(Ⅱ) complexes based on 5-(dimethylamino) isophthalic acid. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1397-1408. doi: 10.11862/CJIC.20240009
-
[14]
Meirong HAN , Xiaoyang WEI , Sisi FENG , Yuting BAI . A zinc-based metal-organic framework for fluorescence detection of trace Cu2+. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1603-1614. doi: 10.11862/CJIC.20240150
-
[15]
Peng ZHOU , Xiao CAI , Qingxiang MA , Xu LIU . Effects of Cu doping on the structure and optical properties of Au11(dppf)4Cl2 nanocluster. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1254-1260. doi: 10.11862/CJIC.20240047
-
[16]
Yonghui ZHOU , Rujun HUANG , Dongchao YAO , Aiwei ZHANG , Yuhang SUN , Zhujun CHEN , Baisong ZHU , Youxuan ZHENG . Synthesis and photoelectric properties of fluorescence materials with electron donor-acceptor structures based on quinoxaline and pyridinopyrazine, carbazole, and diphenylamine derivatives. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 701-712. doi: 10.11862/CJIC.20230373
-
[17]
Xinyu ZENG , Guhua TANG , Jianming OUYANG . Inhibitory effect of Desmodium styracifolium polysaccharides with different content of carboxyl groups on the growth, aggregation and cell adhesion of calcium oxalate crystals. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1563-1576. doi: 10.11862/CJIC.20230374
-
[18]
Peng XU , Shasha WANG , Nannan CHEN , Ao WANG , Dongmei YU . Preparation of three-layer magnetic composite Fe3O4@polyacrylic acid@ZiF-8 for efficient removal of malachite green in water. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 544-554. doi: 10.11862/CJIC.20230239
-
[19]
Zhiwen HU , Weixia DONG , Qifu BAO , Ping LI . Low-temperature synthesis of tetragonal BaTiO3 for piezocatalysis. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 857-866. doi: 10.11862/CJIC.20230462
-
[20]
Guimin ZHANG , Wenjuan MA , Wenqiang DING , Zhengyi FU . Synthesis and catalytic properties of hollow AgPd bimetallic nanospheres. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 963-971. doi: 10.11862/CJIC.20230293
-
[1]
Metrics
- PDF Downloads(0)
- Abstract views(177)
- HTML views(10)