Citation: QI Jin-Li, ZHENG Yue-Qing, XU Wei. Use of p-Formylbenzoate to Construct two Copper(Ⅱ) Complexes：Syntheses, Crystal Structures and Magnetic Properties[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(11): 2405-2414. doi: 10.3969/j.issn.1001-4861.2013.00.380 shu

Use of p-Formylbenzoate to Construct two Copper(Ⅱ) Complexes：Syntheses, Crystal Structures and Magnetic Properties

1.
Center of Applied Solid State Chemistry Research, Ningbo University, Ningbo, Zhejiang 315211, China

Received Date: 28 April 2013
Available Online: 28 June 2013
Fund Project: 应用非线性科学与技术浙江省重中之重学科开放基金(No.xkzl2006) (No.xkzl2006)

Two new Cu(Ⅱ) complexes, [Cu(phen)(H₂O)(fba)(ClO₄)]·H₂O (1) and _∞¹[Cu(bpy)(H₂O)(fba)₂](2)(phen=phenanthroline, bpy=2,2'-bipyridine Hfba=p-formylbenzoic acid) were synthesized by solution-based method and characterized by single-crystal, powder X-ray diffraction methods, IR spectroscopy, TG-DTAanalyses, elemental analyses, and magnetic measurements. Compound 1 is a mononuclear structure crystallizing in the space group P1 and 2 shows a 1D chain structure which belongs to the space group Pbca. Through non-covalent interactions the complex molecules are assembled into 3D supramolecular network structures. The variable temperature magnetic measurements of 1 shows a weak ferromagnetic and antiferromagnetic behavior in the range of 300~7 and 7~2 K, respectively, while the 2's suggests very weak ferromagnetic interactions between Cu(Ⅱ) ions in the experimental temperature range. CCDC: 912745, 1;CCDC: 912746, 2.
- syntheses;crystal structure;non-covalent interactions;magnetic properties
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沈阳化工大学材料科学与工程学院沈阳 110142