Citation: ZHANG Chun-Li, QIN Ling, XU Ji-Gui, ZHENG He-Gen. Synthesis, Crystal Structure and Optical Properties of Ni(Ⅱ) Coordination Polymer Constructed by 4, 4’-Biphenyl Imidazole and Isophthalic Acid Ligands[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(11): 2347-2350. doi: 10.3969/j.issn.1001-4861.2013.00.378
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A 2Dcomplex [Ni(H2O)(MPA)(4,4'-bibp)]n (1), based on mixed-ligands, bibp (bibp =4,4'-bisimidazolyl-biphenyl) and H2MPA (H2MPA=m-phthalic acid), has been synthesized by hydrothermal method and characterized by elemental analysis, IRspectra, TGA, XRD, and the crystal structure was determined by single-crystal X-ray diffraction. The complex crystallizes in the monoclinic system, space group Pc and features a 2D layered structure. The solid UV-Vis properties of ligands and the complex 1 were studied at room temperature. CCDC: 940196.
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