Citation: ZHANG Hua, XU Xiao-Wu, WU Fang-Ying. Synthesis of s-Triazine Derivatives and Application of Heavy Metal Ions Recognition[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(11): 2394-2398. doi: 10.3969/j.issn.1001-4861.2013.00.375 shu

Synthesis of s-Triazine Derivatives and Application of Heavy Metal Ions Recognition

1.
Department of Chemistry, Nanchang University, Nanchang 330031, China

Received Date: 29 March 2013
Available Online: 9 June 2013
Fund Project: 国家自然科学基金(No.21365014) (No.21365014)江西省自然科学基金(No.20132BAB203011)资助项目。 (No.20132BAB203011)

Anew compound, namely 2,4-di(2-thiazole)-6-[2-(4-N,N-dimethylamino)phenylethenyl]-1,3,5-s-triazine (2), was synthesized and fully characterized. Compound 2 displayed double absorption peaks at 355 and 416 nm in the acetonitrile-water mixed medium. In the presence of various metal ions, a new absorption band peaking at 520 nm was appeared for Cu²⁺, Hg²⁺ and Fe³⁺ ions. The binding stoichiometry of compound 2 with Cu²⁺, Hg²⁺ and Fe³⁺ ions was 1:1 and the association constants were 1.9×10⁵, 6.6×10³ and 2.7×10³ L·mol^-1, respectively. Compound 4 exhibited similar spectral response to metal ions with compound 2. The binding mode for compounds 2 with these heavy metal ions was investigated using₁H NMR spectral titration as well. The results suggested that Cu²⁺, Hg²⁺ and Fe³⁺ ions coordinated with the Natom of the triazine and the Satom of thiophene cooperatively.
- s-triazine derivatives;colorimetric assay;Cu²⁺;Hg²⁺;Fe³⁺
1. [1]
  [1] Georgopoulos P G, Roy A, Yonone-Lioy M J, et al. Toxicol. Environ. Health B, 2001,4(4):341-394
2. [2]
  [2] Silva J J R F, Williams R J P. The Biological Chemistry of Elements: The Inorganic of Life. 2nd Ed. New York: Oxford University Press, 2001:315-335
3. [3]
  [3] LÜQing-Luan(吕庆銮), ZHANG Miao(张苗), YUE Ning-Ning(岳宁宁), et al. Chem. J. Chinese Universities (Gaodeng Xuexiao Huaxue Xuebao), 2009,30(3):460-464
4. [4]
  [4] Dalapatia S, Janaa S, Alamb M A, et al. Sens. Actuators B, 2011,160(1):1106-1111
5. [5]
  [5] Desai V, Kaler S G. Am. Clin. Nutr., 2008,88(3):855S-858S
6. [6]
  [6] Mao J, He Q, Liu W S. Talanta., 2010,80(5):2093-2098
7. [7]
  [7] Gupta V K, Jain A K, Agarwal S, et al. Talanta., 2007,71 (5):1964-1968
8. [8]
  [8] Liu W M, Xu L W, Zhang H Y, et al. Org. Biomol. Chem., 2009,7:660-664
9. [9]
  [9] Romero T, Caballero A, EsPinosa A, et al. Dalton Trans., 2009,28(12):2121-2129
10. [10]
  [10]Nendza M, Herbst T, Kussatz C. Chemosphere., 1997,35(9): 1875-1885
11. [11]
  [11]Avirah R R, Jyothish K, Ramaiah D. Org. Lett., 2007,9(1): 121-124
12. [12]
  [12]Shiraishi Y, Maehara H, Ishizumi K, et al. Org. Lett., 2007, 9(16):3125-3128
13. [13]
  [13]Lin W Y, Yuan L, Cao X W, et al. Eur. Org. Chem., 2008, 29:4981-4987
14. [14]
  [14]Bohrer D, Heitmann U, Huang M D, et al. Spectrochim. Acta B, 2007,62(9):1012-1018
15. [15]
  [15]Soylak M, Cay R S. J. Hazard. Mater., 2007,146(1/2):142-147
16. [16]
  [16]Korn M, de Andrade J B, de Jesus D S, et al. Talanta, 2006,69(1):16-24
17. [17]
  [17]GUO Min(郭敏), TONG Lü-Bing(佟履冰), JIANG Li(姜李), et al. Chinese J. Inorg. Chem. (Wuji Huaxue Xuebao), 2009,25(6):956-961
18. [18]
  [18]Lin Y W, Huang C C, Chang H T. Analyst, 2011,136:863-871
19. [19]
  [19]Ai K, Liu Y, Lu L. J. Am. Chem. Soc., 2009,131(27):9496-9497
20. [20]
  [20]OU Sheng-Ju(区升举), ZHANG Bing-Guang(张丙广), LIAO Hai-Ping(廖海平), et al. Chinese J. Inorg. Chem. (Wuji Huaxue Xuebao), 2006,22(5):817-822
21. [21]
  [21]Dambal H K, Yelamaggad C V. Tetrahedron Lett., 2012, 53:186-190
22. [22]
  [22]ZHANG Hua(张华), LIU Ai-Hong(刘爱红), WU Fang-Ying (吴芳英). Acta Chim. Sinica(Huaxue Xuebao), 2012, 70:1001-1007
23. [23]
  [23]Yuan M, Li Y, Li J, et al. Org. Lett., 2007,9:2313-2316
24. [24]
  [24]Ekmekci Z, Yilmaz M D, Akkaya E U. Org. Lett., 2008, 10:461-464
25. [25]
  [25]Sheng R L, Wang P F, Gao Y H, et al. Org. Lett., 2008,10: 5015-5018
26. [26]
  [26]LIU Yu(刘育), YOU Chang-Cheng(尤长城), ZHANG Heng-Yi(张衡益). Supramolecular Chemistry(超分子化学). Tianjin: Nankai University Press, 2001: Chapter 7
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沈阳化工大学材料科学与工程学院沈阳 110142