Citation: WANG Qing, GUO Yong-Min, LI Yi, LI Bao-Zong. Preparation of Chiral Mesoporous Silica Using Phosphatidylcholine as a Chiral Additive[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(11): 2323-2326. doi: 10.3969/j.issn.1001-4861.2013.00.374
-
Helical mesoporous silica nanorods were prepared through a so-gel approach using cetyltrimethylammonium bromide (CTAB) as the template and phosphatidylcholine (PC) as a chiral additive. The molar ratio of PC and CTAB is 1:21. The morphologies and pore architectures were characterized using field emission scanning electron microscopy (FESEM), transmission electron microscopy (TEM), N2 sorptions and X-ray diffraction. It was found that the mesoporous silica nanorods were about 30~50 nm in diameter and about 50~200 nm in length. The TEM images and the small-angle X-diffraction indicated that the pore channels arranged in a two-dimensional hexagonal structure. The FESEM images indicated that the ratio of the left-and right-handed nanorods is almost 1:1. However, the circular dichroism spectrum (CD) indicated that the nanorods tended to form a structure with homochirality at angstrom level. It seems that the chirality of PC has been successfully transferred to the walls of the helical mesoporous silica nanorods.
-
-
[1]
[1] Kresge C T, Leonowicz M E, Beck J S, et al. Nature, 1992, 359:710-712
-
[2]
[2] Corma A. Chem. Rev., 1997,97(6):2373-2419
-
[3]
[3] Wan Y, Zhao D. Chem. Rev., 2007,107:2821-2860
-
[4]
[4] Yoshina I C, Asefa T, Coombs N, et al. Chem. Commun., 1999,24:2539-2540
-
[5]
[5] Wang H N, Wang Y H, Zhou X, et al. Adv. Funct. Mater., 2007,17(4):613-617
-
[6]
[6] Ding J X, Xi C S, Zhou X L, et al. Mater. Lett., 2012,73:17-20
-
[7]
[7] DONG Xiu-Fang(董秀芳), CAO Rui-Lin(曹瑞林), LI Yu(李 裕), et al. Chem. Engineer(Huaxue Gongchengshi), 2010,5: 43-45
-
[8]
[8] WU Hong-Yu(伍宏玉), LI Hai-Tao(李海涛),ZHANG You-Yu (张友玉), et al. Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2012,28(2):257-262
-
[9]
[9] Chen J F, Ding H M, Wang J X, et al. Biomaterials, 2004,25 (4):723-727
-
[10]
[10]Kawasaki T, Ishikawa K, Sekibata H, et al. Tetrahedron Lett., 2004,45(42):7939-7941
-
[11]
[11]Moreau J, Vellutini L, Bied C, et al. J. Am. Chem. Soc., 2001,123:1509-1510
-
[12]
[12]Yang Y G, Nakazawa M, Suzuki M, et al. Chem. Mater., 2004,16(20):3791-3793
-
[13]
[13]Yang Y, Suzuki M, Hanabusa K, et al. J. Am. Chem. Soc., 2007,129(17):581-587
-
[14]
[14]Wan X, Pei X, Yang Y, et al. Nanotechnology, 2008,19: 315603
-
[15]
[15]Li B, Xu Z, Yang Y, et al. Chem. Commun., 2011,47:11495-11497
-
[16]
[16]Zhou L, Hong G, Lu Y, et al. Langmuir, 2009,25:6040-6044
-
[17]
[17]Yang S, Zhao L, Zhao D, et al. J. Am. Chem. Soc., 2006, 128:10460
-
[18]
[18]Yang H, Ozin G A, Kresge C T. Adv. Mater., 1998,10(11): 883-887
-
[19]
[19]Hu Y, Yuan P, Yu C, et al. Chem. Lett., 2008,37:1160-1161
-
[20]
[20]Li Y, Bi L, Yang Y, et al. Chem. Commun., 2010,46:2680
-
[21]
[21]Zhuang W, Bi L, Yang Y, et al. Chin. J. Chem., 2011,29: 883-887
-
[22]
[22]Che S, Liu Z, Tatsumi T. Nature, 2004,429:281-284
-
[23]
[23]Li Y, Wang S, Yang Y, et al. Nanotachnology, 2013,24: 035603
-
[1]
-
-
[1]
Xiaoning TANG , Shu XIA , Jie LEI , Xingfu YANG , Qiuyang LUO , Junnan LIU , An XUE . Fluorine-doped MnO2 with oxygen vacancy for stabilizing Zn-ion batteries. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1671-1678. doi: 10.11862/CJIC.20240149
-
[2]
Bing LIU , Huang ZHANG , Hongliang HAN , Changwen HU , Yinglei ZHANG . Visible light degradation of methylene blue from water by triangle Au@TiO2 mesoporous catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 941-952. doi: 10.11862/CJIC.20230398
-
[3]
Yuanpei ZHANG , Jiahong WANG , Jinming HUANG , Zhi HU . Preparation of magnetic mesoporous carbon loaded nano zero-valent iron for removal of Cr(Ⅲ) organic complexes from high-salt wastewater. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1731-1742. doi: 10.11862/CJIC.20240077
-
[4]
Jie ZHAO , Sen LIU , Qikang YIN , Xiaoqing LU , Zhaojie WANG . Theoretical calculation of selective adsorption and separation of CO2 by alkali metal modified naphthalene/naphthalenediyne. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 515-522. doi: 10.11862/CJIC.20230385
-
[5]
Xiaoling LUO , Pintian ZOU , Xiaoyan WANG , Zheng LIU , Xiangfei KONG , Qun TANG , Sheng WANG . Synthesis, crystal structures, and properties of lanthanide metal-organic frameworks based on 2, 5-dibromoterephthalic acid ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1143-1150. doi: 10.11862/CJIC.20230271
-
[6]
Juntao Yan , Liang Wei . 2D S-Scheme Heterojunction Photocatalyst. Acta Physico-Chimica Sinica, 2024, 40(10): 2312024-. doi: 10.3866/PKU.WHXB202312024
-
[7]
Jingjing QING , Fan HE , Zhihui LIU , Shuaipeng HOU , Ya LIU , Yifan JIANG , Mengting TAN , Lifang HE , Fuxing ZHANG , Xiaoming ZHU . Synthesis, structure, and anticancer activity of two complexes of dimethylglyoxime organotin. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1301-1308. doi: 10.11862/CJIC.20240003
-
[8]
Fan JIA , Wenbao XU , Fangbin LIU , Haihua ZHANG , Hongbing FU . Synthesis and electroluminescence properties of Mn2+ doped quasi-two-dimensional perovskites (PEA)2PbyMn1-yBr4. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1114-1122. doi: 10.11862/CJIC.20230473
-
[9]
Yonghui ZHOU , Rujun HUANG , Dongchao YAO , Aiwei ZHANG , Yuhang SUN , Zhujun CHEN , Baisong ZHU , Youxuan ZHENG . Synthesis and photoelectric properties of fluorescence materials with electron donor-acceptor structures based on quinoxaline and pyridinopyrazine, carbazole, and diphenylamine derivatives. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 701-712. doi: 10.11862/CJIC.20230373
-
[10]
Lu XU , Chengyu ZHANG , Wenjuan JI , Haiying YANG , Yunlong FU . Zinc metal-organic framework with high-density free carboxyl oxygen functionalized pore walls for targeted electrochemical sensing of paracetamol. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 907-918. doi: 10.11862/CJIC.20230431
-
[11]
Jing SU , Bingrong LI , Yiyan BAI , Wenjuan JI , Haiying YANG , Zhefeng Fan . Highly sensitive electrochemical dopamine sensor based on a highly stable In-based metal-organic framework with amino-enriched pores. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1337-1346. doi: 10.11862/CJIC.20230414
-
[12]
Peiran ZHAO , Yuqian LIU , Cheng HE , Chunying DUAN . A functionalized Eu3+ metal-organic framework for selective fluorescent detection of pyrene. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 713-724. doi: 10.11862/CJIC.20230355
-
[13]
Xin XIONG , Qian CHEN , Quan XIE . First principles study of the photoelectric properties and magnetism of La and Yb doped AlN. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1519-1527. doi: 10.11862/CJIC.20240064
-
[14]
Jiakun BAI , Ting XU , Lu ZHANG , Jiang PENG , Yuqiang LI , Junhui JIA . A red-emitting fluorescent probe with a large Stokes shift for selective detection of hypochlorous acid. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1095-1104. doi: 10.11862/CJIC.20240002
-
[15]
Jiaqi AN , Yunle LIU , Jianxuan SHANG , Yan GUO , Ce LIU , Fanlong ZENG , Anyang LI , Wenyuan WANG . Reactivity of extremely bulky silylaminogermylene chloride and bonding analysis of a cubic tetragermylene. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1511-1518. doi: 10.11862/CJIC.20240072
-
[16]
Jin CHANG . Supercapacitor performance and first-principles calculation study of Co-doping Ni(OH)2. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1697-1707. doi: 10.11862/CJIC.20240108
-
[17]
Cheng PENG , Jianwei WEI , Yating CHEN , Nan HU , Hui ZENG . First principles investigation about interference effects of electronic and optical properties of inorganic and lead-free perovskite Cs3Bi2X9 (X=Cl, Br, I). Chinese Journal of Inorganic Chemistry, 2024, 40(3): 555-560. doi: 10.11862/CJIC.20230282
-
[18]
Chuanming GUO , Kaiyang ZHANG , Yun WU , Rui YAO , Qiang ZHAO , Jinping LI , Guang LIU . Performance of MnO2-0.39IrOx composite oxides for water oxidation reaction in acidic media. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1135-1142. doi: 10.11862/CJIC.20230459
-
[19]
Zhihuan XU , Qing KANG , Yuzhen LONG , Qian YUAN , Cidong LIU , Xin LI , Genghuai TANG , Yuqing LIAO . Effect of graphene oxide concentration on the electrochemical properties of reduced graphene oxide/ZnS. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1329-1336. doi: 10.11862/CJIC.20230447
-
[20]
Kai CHEN , Fengshun WU , Shun XIAO , Jinbao ZHANG , Lihua ZHU . PtRu/nitrogen-doped carbon for electrocatalytic methanol oxidation and hydrogen evolution by water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1357-1367. doi: 10.11862/CJIC.20230350
-
[1]
Metrics
- PDF Downloads(0)
- Abstract views(212)
- HTML views(1)