Citation: YU Jiang-Xi, KUANG Dai-Zhi, FENG Yong-Lan, ZHANG Fu-Xing, WANG Jian-Qiu, JIANG Wu-Jiu, ZHU Xiao-Ming, PENG Yan, YANG Yi. Synthesis, Characterization, Fluorescence, Thermal Property and Quantum Chemistry of Triphenyltin 9-Anthroicarboxylate[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(12): 2688-2694. doi: 10.3969/j.issn.1001-4861.2013.00.373
-
A new organotin complex [PH3Sn(O2CC14H9)(CH3OH)]2·CH3OH has been synthesized by the reaction of triphenyltin hydroxide with 9-anthroic acid in methanol. It was characterized by IR, 1H and 13C NMR, elemental analysis and X-ray crystal diffraction. Crystal structure shows a distorted trigonal bipyramidal configuration with five-coordination for the central tin atom. In the crystal, O-H…O hydrogen-bond interactions exist between the methanol O atom and the carbonyl O atom in an adjacent complex molecule, and between the neighboring methanol O atoms, resulting in the formation of a 1D S-shaped chain. Due to the C-H…π interactions between anthryl-H and anthracene ring, the obtained chain is further linked to form 1D ladderlike structure. Finally, a 2D network has been generated by the C-H…π interactions between methyl-H and benzene ring in the neighbouring 1D ladderlike chains. Fluorescence spectra of the complex reveals a strong emission band at 460 nm when excited with 360 nm radiation at room temperature. Thermogravimetric analysis shows that the complex is stable up to 240 ℃. The stability of the complex, the orbital energies and composition characteristics of some frontier molecular orbitals have been investigated at LANL2DZ level with G03W software. CCDC: 899826.
-
-
[1]
[1] Chandrasekhar V, Gopal K, Thilagar P. Acc. Chem. Res., 2007, 40 (6):420-434
-
[2]
[2] TIAN Lai-Jin (田来进), YANG Hong-Jun (杨红军), ZHENG Xiao-Liang (郑晓亮), et al. Chinese J. Inorg. Chem. (Wuji Huaxue Xuebao), 2009, 25 (7):1205-1211
-
[3]
[3] Davies A G, Gielen M, Pannell K H, et al. Tin Chemistry. Chichester: John Wiley & Sons, 2008:431, 667
-
[4]
[4] CAO Zuo-Ying (曹佐英), XU Hai-Feng (许海峰), TANG Rui-Ren (唐瑞仁), et al. Chinese J. Inorg. Chem. (Wuji Huaxue Xuebao), 2008, 24 (3):474-478
-
[5]
[5] DU Zhi-Ping (杜治平), LIU Liang (刘亮), WANG Gong-Ying (王公应), et al. Chinese J. Inorg. Chem. (Wuji Huaxue Xuebao), 2009, 25 (12):2225-2228
-
[6]
[6] Suzuki T, Takakura I, Yoda M. Eur. Polym. J., 1971, 7 (8): 1105-1110
-
[7]
[7] Davies A G. Organotin Chemistry. Weinheim: Wiley-VCH Verlag GmbH & Co. KGaA, 2004:383
-
[8]
[8] TIAN Lai-Jin (田来进), SUN Yu-Xi (孙玉希), ZHENG Xiao-Liang (郑晓亮), et al. Chinese J. Inorg. Chem. (Wuji Huaxue Xuebao), 2006, 22 (4):629-632
-
[9]
[9] Kovala-Demertzi D, Dokorou V, Primikiri A, et al. J. Inorg. Biochem., 2009, 103 (5):738-744
-
[10]
[10] Lecat J L, Devaud M. J. Organomet. Chem., 1983, 244 (3): 217-224
-
[11]
[11] Kovala-Demertzi D. J. Organomet. Chem., 2006, 691 (8):1767-1774
-
[12]
[12] WANG Zhi-Hong (王志宏), WANG He (王贺), GUO Yan-Zhao (郭彦召), et al. Chinese J. Inorg. Chem. (Wuji Huaxue Xuebao), 2012, 28 (9):1926-1934
-
[13]
[13] YU Jiang-Xi (庾江喜), KUANG Dai-Zhi (邝代治), YIN Du-Lin (尹笃林), et al. Chinese J. Inorg. Chem. (Wuji Huaxue Xuebao), 2010, 26 (8):1507-1510
-
[14]
[14] KUANG Dai-Zhi (邝代治), YU Jiang-Xi (庾江喜), YIN Du-Lin (尹笃林), et al. Chinese J. Inorg. Chem. (Wuji Huaxue Xuebao), 2010, 26 (12):2303-2306
-
[15]
[15] Chandrasekhar V, Thilagar P, Steiner A, et al. Chem.-Eur. J., 2006, 12 (34):8847-8861
-
[16]
[16] George M S. SHELXTL-97: Program for Crystal Structure Analysis. Göttingen: University of Göttingen, 1997.
-
[17]
[17] KUANG Dai-Zhi (邝代治), CHEN Zhi-Min (陈志敏), ZHANG Fu-Xing (张复兴), et al. Chinese J. Inorg. Chem. (Wuji Huaxue Xuebao), 2006, 22 (11):1947-1951
-
[18]
[18] KE Yi-Kan (柯以侃), DONG Hui-Ru (董慧茹). Analysis Chemistry handbook, Vol.3 (分析化学手册:第三分册). Beijing: Chemical Industry Press, 1998:932, 935
-
[19]
[19] XIE Qing-Lan (谢庆兰), XU Xiao-Hua (徐效华), ZHANG Dian-Kun (张殿坤), et al. Acta Chimica Sinica (Huaxue Xuebao), 1992, 50 (5):508-514
-
[20]
[20] Geng W Q, Zhou H P, Cheng L H, et al. Polyhedron, 2012, 31 (1):738-747
-
[21]
[21] Alcock N W, Timms R E. J. Chem. Soc. A, 1968:1873-1876
-
[22]
[22] Bondi A. J. Phys. Chem., 1964, 68 (3):441-451 Table 1 Crystal data and structure refinement parameters of the complex Hydrogen atoms are omitted for clarity
-
[1]
-
-
[1]
Haitang WANG , Yanni LING , Xiaqing MA , Yuxin CHEN , Rui ZHANG , Keyi WANG , Ying ZHANG , Wenmin WANG . Construction, crystal structures, and biological activities of two LnⅢ3 complexes. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1474-1482. doi: 10.11862/CJIC.20240188
-
[2]
Xin MA , Ya SUN , Na SUN , Qian KANG , Jiajia ZHANG , Ruitao ZHU , Xiaoli GAO . A Tb2 complex based on polydentate Schiff base: Crystal structure, fluorescence properties, and biological activity. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1347-1356. doi: 10.11862/CJIC.20230357
-
[3]
Xinting XIONG , Zhiqiang XIONG , Panlei XIAO , Xuliang NIE , Xiuying SONG , Xiuguang YI . Synthesis, crystal structures, Hirshfeld surface analysis, and antifungal activity of two complexes Na(Ⅰ)/Cd(Ⅱ) assembled by 5-bromo-2-hydroxybenzoic acid ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1661-1670. doi: 10.11862/CJIC.20240145
-
[4]
Jingjing QING , Fan HE , Zhihui LIU , Shuaipeng HOU , Ya LIU , Yifan JIANG , Mengting TAN , Lifang HE , Fuxing ZHANG , Xiaoming ZHU . Synthesis, structure, and anticancer activity of two complexes of dimethylglyoxime organotin. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1301-1308. doi: 10.11862/CJIC.20240003
-
[5]
Xiaoling LUO , Pintian ZOU , Xiaoyan WANG , Zheng LIU , Xiangfei KONG , Qun TANG , Sheng WANG . Synthesis, crystal structures, and properties of lanthanide metal-organic frameworks based on 2, 5-dibromoterephthalic acid ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1143-1150. doi: 10.11862/CJIC.20230271
-
[6]
Yingchun ZHANG , Yiwei SHI , Ruijie YANG , Xin WANG , Zhiguo SONG , Min WANG . Dual ligands manganese complexes based on benzene sulfonic acid and 2, 2′-bipyridine: Structure and catalytic properties and mechanism in Mannich reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1501-1510. doi: 10.11862/CJIC.20240078
-
[7]
Zhaoyang WANG , Chun YANG , Yaoyao Song , Na HAN , Xiaomeng LIU , Qinglun WANG . Lanthanide(Ⅲ) complexes derived from 4′-(2-pyridyl)-2, 2′∶6′, 2″-terpyridine: Crystal structures, fluorescent and magnetic properties. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1442-1451. doi: 10.11862/CJIC.20240114
-
[8]
Jing SU , Bingrong LI , Yiyan BAI , Wenjuan JI , Haiying YANG , Zhefeng Fan . Highly sensitive electrochemical dopamine sensor based on a highly stable In-based metal-organic framework with amino-enriched pores. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1337-1346. doi: 10.11862/CJIC.20230414
-
[9]
Peiran ZHAO , Yuqian LIU , Cheng HE , Chunying DUAN . A functionalized Eu3+ metal-organic framework for selective fluorescent detection of pyrene. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 713-724. doi: 10.11862/CJIC.20230355
-
[10]
Shuwen SUN , Gaofeng WANG . Two cadmium coordination polymers constructed by varying Ⅴ-shaped co-ligands: Syntheses, structures, and fluorescence properties. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 613-620. doi: 10.11862/CJIC.20230368
-
[11]
Yuanpei ZHANG , Jiahong WANG , Jinming HUANG , Zhi HU . Preparation of magnetic mesoporous carbon loaded nano zero-valent iron for removal of Cr(Ⅲ) organic complexes from high-salt wastewater. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1731-1742. doi: 10.11862/CJIC.20240077
-
[12]
Tiantian MA , Sumei LI , Chengyu ZHANG , Lu XU , Yiyan BAI , Yunlong FU , Wenjuan JI , Haiying YANG . Methyl-functionalized Cd-based metal-organic framework for highly sensitive electrochemical sensing of dopamine. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 725-735. doi: 10.11862/CJIC.20230351
-
[13]
Xiaoning TANG , Junnan LIU , Xingfu YANG , Jie LEI , Qiuyang LUO , Shu XIA , An XUE . Effect of sodium alginate-sodium carboxymethylcellulose gel layer on the stability of Zn anodes. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1452-1460. doi: 10.11862/CJIC.20240191
-
[14]
Lu XU , Chengyu ZHANG , Wenjuan JI , Haiying YANG , Yunlong FU . Zinc metal-organic framework with high-density free carboxyl oxygen functionalized pore walls for targeted electrochemical sensing of paracetamol. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 907-918. doi: 10.11862/CJIC.20230431
-
[15]
Qilu DU , Li ZHAO , Peng NIE , Bo XU . Synthesis and characterization of osmium-germyl complexes stabilized by triphenyl ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1088-1094. doi: 10.11862/CJIC.20240006
-
[16]
Huan ZHANG , Jijiang WANG , Guang FAN , Long TANG , Erlin YUE , Chao BAI , Xiao WANG , Yuqi ZHANG . A highly stable cadmium(Ⅱ) metal-organic framework for detecting tetracycline and p-nitrophenol. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 646-654. doi: 10.11862/CJIC.20230291
-
[17]
Ruikui YAN , Xiaoli CHEN , Miao CAI , Jing REN , Huali CUI , Hua YANG , Jijiang WANG . Design, synthesis, and fluorescence sensing performance of highly sensitive and multi-response lanthanide metal-organic frameworks. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 834-848. doi: 10.11862/CJIC.20230301
-
[18]
Xiaoxia WANG , Ya'nan GUO , Feng SU , Chun HAN , Long SUN . Synthesis, structure, and electrocatalytic oxygen reduction reaction properties of metal antimony-based chalcogenide clusters. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1201-1208. doi: 10.11862/CJIC.20230478
-
[19]
Lu LIU , Huijie WANG , Haitong WANG , Ying LI . Crystal structure of a two-dimensional Cd(Ⅱ) complex and its fluorescence recognition of p-nitrophenol, tetracycline, 2, 6-dichloro-4-nitroaniline. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1180-1188. doi: 10.11862/CJIC.20230489
-
[20]
Kaimin WANG , Xiong GU , Na DENG , Hongmei YU , Yanqin YE , Yulu MA . Synthesis, structure, fluorescence properties, and Hirshfeld surface analysis of three Zn(Ⅱ)/Cu(Ⅱ) complexes based on 5-(dimethylamino) isophthalic acid. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1397-1408. doi: 10.11862/CJIC.20240009
-
[1]
Metrics
- PDF Downloads(0)
- Abstract views(185)
- HTML views(14)