Citation: DENG Yi-Fang, CHEN Man-Sheng, ZHANG Chun-Hua, KUANG Dai-Zhi, NIE Xue, YANG Ying-Qun, LI Wei. Synthesis, Crystal Structure and Photoluminescent Property of Zn(Ⅱ) Complex Constructed from 1,3-Benzenedicarboxylate and 1,4-Di(1-imidazoly)benzene[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(10): 2195-2199. doi: 10.3969/j.issn.1001-4861.2013.00.365 shu

Synthesis, Crystal Structure and Photoluminescent Property of Zn(Ⅱ) Complex Constructed from 1,3-Benzenedicarboxylate and 1,4-Di(1-imidazoly)benzene

1.
1 Key Laboratory of Preparation and Applications of Environmental Friendly Materials, Chinese Ministry of Education, Jilin Normal University, Siping, Jilin 136000, China;

Received Date: 8 May 2013
Available Online: 9 June 2013
Fund Project: 湖南省自然科学基金(No.13JJ6069) (No.13JJ6069)湖南省教育厅创新平台开放基金(No.11K009) (No.11K009)

Anew 2D Zn(Ⅱ) metal-organic framework, [Zn₂(dib)(1,3-BDC)₂(H₂O)] (1), has been synthesized by the hydrothermal reaction of 1,3-benzenedicarboxylate with ZnSO₄·7H₂Oin the presence of 1,4-di(1-imidazoly)benzene (dib=1,4-di(1-imidazoly)benzene, 1,3-H₂BDC=1,3-benzenedicarboxylate). The crystal is of monoclinic system, space group P2₁/n, with a=0.80367(12) nm, b=1.3327(2) nm, c=2.3725(4) nm, β=97.394(3)°, V=2.5199(7) nm³, Z=4, F(000)=1392, R=0.0520 and wR=0.0994 (I>2σ(I)). The two central zinc(Ⅱ) ions in the complex locate in a different coordination geometry, one is a distorted tetrahedral and the other is a distorted square-pyramidal coordination geometry, respectively. The dib ligand acts as a bridging ligand, which links the 1D double-chain into 2D layer structure. The net is linked into three-dimensional supramolecular network by O-H…Ohydrogen bonds. CCDC: 895702.
- hydrothermal synthesis; zinc(Ⅱ) complex; crystal structure; luminescence property
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沈阳化工大学材料科学与工程学院沈阳 110142