Citation: CHEN Wen-Tong. Fluorescent, Theoretical and Structural Investigations of a 2, 2’-Biimidazole Cadmium Compound[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(11): 2455-2459. doi: 10.3969/j.issn.1001-4861.2013.00.364
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Anovel cadmium-biimidazole compound [Cd(BIm)2](ClO4)(OH)·2H2O (1) (BIm=2,2'-biimidazole) has been synthesized via a hydrothermal reaction and structurally characterized by single-crystal X-ray diffraction. Compound 1 features an isolated (0D) structure with the cadmium ions coordinating to four nitrogen atoms to give a distorted tetrahedron. Photoluminescent investigation shows that compound 1 exhibits an emission in the blue region. Theoretical study reveals that the emission is ascribed to ligand-to-metal charge transfer (LMCT). The spectral data of FT-IR are also reported. CCDC: 895386.
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[1]
[1] Chou P T, Chi Y, Chung M W, et al. Coord. Chem. Rev., 2011,255:2653-2665
-
[2]
[2] Poddel'sky A I, Cherkasov V K, Abakumov G A. Coord. Chem. Rev., 2009,253:291-324
-
[3]
[3] Phillips A D, Gonsalvi L, Romerosa A, et al. Coord. Chem. Rev., 2004,248:955-993
-
[4]
[4] Tang X Y, Li H X, Chen J X, et al. Coord. Chem. Rev., 2008,252:2026-2049
-
[5]
[5] Jiang P, Guo Z. Coord. Chem. Rev., 2004,248:205-229
-
[6]
[6] LI Qiao-Yun(李巧云), MA Yun-Sheng(马运声), YANG Gao-Wen(杨高文), et al. Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2008,9:1461-1467
-
[7]
[7] HU Zong-Qiu(胡宗球), YE Xiao-Zhao(叶效昭), SONG Xue-Gang(宋学刚), et al. Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2011,10:1993-1998
-
[8]
[8] YANG Li-Ning(杨莉宁), ZHI Yan-Xiang(支燕翔), HEI Jia-Hui(黑佳慧), et al. Chinese J. Spectr. Lab.(Guangpu Shiyanshi), 2012,4:2488-2492
-
[9]
[9] YUAN Yu(原宇), GAO Xiao-Li(高晓丽), ZHU Miao-Li(朱苗 力). Chem. Eng.(Huaxue Gongchengshi), 2009,3:3-5
-
[10]
[10]Ion L, Morales D, Nieto S, et al. Inorg. Chem., 2007,46: 2846-2853
-
[11]
[11]Majumdar P, Peng S M, Goswami S. J. Chem. Soc., Dalton Trans., 1998,10:1569-1574
-
[12]
[12]Gruia L M, Rochon F D, Beauchamp A L. Inorg. Chim. Acta, 2007,360:1825-1840
-
[13]
[13]Rigaku, Crystal Clear Version 1.35, Rigaku Corporation, 2002.
-
[14]
[14]Siemens, SHELXTLTM Ver. 5 Reference Manual, Siemens Energy, Automation Inc., Madison, Wisconsin, USA, 1994.
-
[15]
[15]Pujar M A, Bharamgoudar T D, Sathyanarayana D N. Transition. Met. Chem., 1988,13:423-425
-
[16]
[16]Sang R, Xu L. Inorg. Chem., 2005,44:3731-3737
-
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