Citation: CHEN Xiao-Li, QIAO Ya-Li, GAO Lou-Jun, LÜ Jun-Fang, CUI Hua-Li. Structural and Spectral Study of Terbium 4-Hydroxypyridine-2, 6-Dicarboxylic Acid Coordination Polymer[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(11): 2357-2362. doi: 10.3969/j.issn.1001-4861.2013.00.363 shu

Structural and Spectral Study of Terbium 4-Hydroxypyridine-2, 6-Dicarboxylic Acid Coordination Polymer

1.
Shaanxi Key Laboratory of Chemical Reaction Engineering, Department of Chemistry and Chemical Engineering, Yanan University, Yan'an, Shaanxi 716000, China

Received Date: 25 February 2013
Available Online: 25 June 2013
Fund Project: 国家自然科学基金(No.21101133) (No.21101133)陕西省教育厅专项科研基金(No.11JK0565)资助项目。 (No.11JK0565)

A 2D Tb^Ⅲ coordination polymer [Tb(cam)(H₂O)₃]_n·nH₂O (1) (H₃cam=4-Hydroxypyridine-2,6-dicarbo-xylic acid) was synthesized under hydrothermal conditions and characterized by elemental analysis, IR spectrum, single-crystal X-ray diffraction, UV-Vis, Fluorescence, TGA and XRD. The Tb^Ⅲ ion is eight-coordinate with a slightly distorted dodecahedron geometry. One Tb^Ⅲ ion joined with three (cam)^3- ions to form a 2D layered with (4·8²) topological. The neighboring layers are linked into 3D supramolecular network through hydrogen bonding interaction. The luminescence experiments show that 1 exhibits typical Tb^Ⅲ-centered emissions in the solid state, the energy level difference was well matched and the emission of terbium complex was characteristic and high. CCDC: 922429.
- terbium coordination polymer;crystal structure;hydrothermal synthesis;spectral analysis
1. [1]
  [1] HUANG Chun-hui(黄春辉). Coordination Chemistry of Rare Earth(稀土配位化学). Beijing: Science Press, 1997.
2. [2]
  [2] CHEN Yi-Ping(陈义平), ZHAO Ling-Yan(赵玲艳), ZHANG Han-Hui(张汉辉), et al. Spectroscopy and Spectral Anlysis (Guangpu Yu Guangpu Fenxi), 2010,30(1):174-178
3. [3]
  [3] Binnemans K. Chem. Rev., 2009,109(9):4283-4374
4. [4]
  [4] Reineke T M, Eddaoudi M, Yaghi O M, et al. J. Am. Chem. Soc., 2000,122:4843-4844
5. [5]
  [5] Hu D H, Luo F, Zheng J M, et al. Cryst. Growth Des., 2007, 7:1733-1737
6. [6]
  [6] Kiritsis V, Michaelides A, Skoulika S, et al. Inorg. Chem., 1998,37:3407-3410
7. [7]
  [7] Spichal Z, Petricek V, Pinkas J, et al. Polyhedron, 2008,27: 283-288
8. [8]
  [8] Mahata P, Natarajan S. Inorg. Chem., 2007,46:1250-1258
9. [9]
  [9] Chen B L, Wang L B, Xiao Y Q, et al. Angew. Chem., Int. Ed., 2009,48:500-503
10. [10]
  [10]LU Wen-Guan(卢文贯), LIU Hong-Wen(刘宏文), et al. Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2010,26(8): 1450-1456
11. [11]
  [11]Zhao X Q, Zhao B, Cheng, et al. Inorg. Chem., 2009,48: 11048-11057
12. [12]
  [12]Zhao X Q, Chen Z, Cheng P, et al. Inorg. Chem. Commun., 2007,10:1433-1436
13. [13]
  [13]Chen Z, Fang M, Cheng P, et al. Z. Anorg. Allg. Chem., 2008,634:382-386
14. [14]
  [14]Zhao X Q, Cui P, Cheng P, et al. Discussion of Faraday Soc., 2011,40:805-809
15. [15]
  [15]Sheldrick G M. SHELXS-97 and SHELXL-97, Program for X-ray Crystal Structure Solution and Refinement, Göttingen University, Germany, 1997.
16. [16]
  [16]Wang C G, Xing Y H, Li Z P, et al. Cryst. Growth Des., 2009,9(3):1525-1530
17. [17]
  [17]Gao H L, Yi L, Zhao B, et al. Inorg. Chem., 2006,45:5980-5988
18. [18]
  [18]Kazuo Nakamoto(中本一雄), Translated by HUANG De-Ru (黄德如), WANG Ren-Qin(汪仁庆). Infrared and Raman Spectra of Inorganic and Coordination Compounds(无机和配位化合物的红外和拉曼光谱). Beijing: Chemistry Industry Press, 1986.
19. [19]
  [19]MEI Hong-Xing(梅洪鑫), LI Guang-Man(李光满), ZHANG Han-Hui(张汉辉), et al. Spectroscopy and Spectral Analysis (Guangpu Yu Guangpu Fenxi), 2012,32(1):166-170
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沈阳化工大学材料科学与工程学院沈阳 110142