Citation: HAO Jin-Ming, LI Huan-Huan, LI Guang-Yue, CUI Guang-Hua. Two Dimensional Cadmium (Ⅱ) Coordination Polymer Constructed from Flexible Bis(triazole) Ligand：Synthesis, Structure and Fluorescence Property[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(11): 2450-2454. doi: 10.3969/j.issn.1001-4861.2013.00.361 shu

Two Dimensional Cadmium (Ⅱ) Coordination Polymer Constructed from Flexible Bis(triazole) Ligand：Synthesis, Structure and Fluorescence Property

1.
College of Chemical Engineering, Hebei United University, Tangshan, Hebei 063009, China

Received Date: 28 January 2013
Available Online: 9 June 2013
Fund Project: 国家自然科学基金(No.11247281) (No.11247281)河北省教育厅优秀青年基金(No.Y2012010)资助项目 (No.Y2012010)

The new coordination polymer named, {[Cd(L)(HBTC)(H₂O)]·H₂O}_n (L=1,2-bis(1,2,4-triazol-1-ylmethyl)benzene, H₃BTC=1,3,5-benzenetricarboxylic acid) has been synthesized hydrothermally and characterized by elemental analysis, IR spectroscopy, thermogravimetric (TG) analysis and single-crystal X-ray diffraction analysis. The cadmium center is six coordinated with three OCOO-atoms from two different HBTC^2- dianions and one water molecule locate in the equatorial positions, while apical sites are occupied by two Natoms from two distinct Lligands in a distorted octahedral geometry. The structural analysis shows that the complex possesses a two-dimensional 2D (4,4) layer structure, and displays a three-dimensional (3D) supramolecular structure via multiple intermolecular O-H…O hydrogen bonds. The fluorescence property of the complex also has been studied. CCDC: 917952.
- cadmium(Ⅱ) complex;crystal structure;fluorescence property;(4, 4) network
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沈阳化工大学材料科学与工程学院沈阳 110142