Citation: YAN Li, WANG Mi-Jia. Synthesis, Crystal Structures and Fluorescence of Two Zn(Ⅱ) Complexes with Schiff Base Ligands[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(11): 2370-2374. doi: 10.3969/j.issn.1001-4861.2013.00.351
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We synthesized two novel Schiff-Base ligands by modificating the aromatic aldehyde: H2L1=N,N'-bis(2-oxy-acetate-3-methoxyl)benzylpropylene diamine, H2L2=N,N'-bis(2-oxy-acetate-3-methoxyl)benzylpropylene (1,3-propane)diamine. [Zn(L1)]·7H2O (1) and [Zn(L2)]·7H2O (2) complexes were prepared by the reaction between H2L1, H2L2 and zinc salts in the solvents of water. The two complexes were structurally characterized by elemental analysis, IR, HNMR and single-crystal X-ray diffraction. The X-ray diffraction results suggest that both the two complexes contain lattice water molecules. The complex 1 exhibits distorted tri-prism geometry and the complex 2 exhibits distorted octahedron geometry. There are lattice water molecules in the complex 1 and 2. In this paper, we research the solid luminescence of these two complexes. The results suggest that they have excellent photoluminescence and will be useful in the optical material. CCDC: 783660: 1;783330: 2.
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