Citation: CHEN Shun-Yu, YANG E, LIU Zi-Sheng. Synthesis, Crystal Structure and Luminescent Property of a Cd(Ⅱ) Coordination Polymer Constructed by 2-Amino-1, 4-benzenedicarboxylate and 2-Imidazolidinone[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(11): 2485-2490. doi: 10.3969/j.issn.1001-4861.2013.00.350 shu

Synthesis, Crystal Structure and Luminescent Property of a Cd(Ⅱ) Coordination Polymer Constructed by 2-Amino-1, 4-benzenedicarboxylate and 2-Imidazolidinone

1.
1 College of Chemistry and Chemical Engineering, Fujian Normal University, Fuzhou 350007, China;

Received Date: 6 March 2013
Available Online: 13 June 2013
Fund Project: 国家自然科学基金(No.60976019) (No.60976019)高等学校博士学科点专项科研基金(No.20093223110002) (No.20093223110002)福建师范大学优秀青年学者培养基金(No.FJSDJK2012063) (No.FJSDJK2012063)福建省教委基金(No.JB11002,JB10007)资助项目。 (No.JB11002,JB10007)

Anew coordination polymer, namely [Cd(NH₂bdc)(e-urea)]_n (1) (H₂NH₂bdc=2-amino^-1,4-benzenedicar-boxylic acid, e-urea=2-imidazolidinone) has been urothermally synthesized by using urea derivative 2-imidazoli-dinone as solvent and its structure and fluorescence property have also been investigated. The crystallography analysis reveals that the centric Cd(Ⅱ) ion is seven coordinated by carboxylate oxygen atoms from NH₂bdc ligands and oxygen atoms of e-urea molecules forming a distorted pentagonal-bipyramidal coordination geometry. The adjacent Cd(Ⅱ) centers are bridged by oxygen atoms of e-urea molecules and carboxylate groups of NH₂bdc ligands forming an infinite 1Dchain. Thus 1Dchains are further connected together by NH₂bdc ligands into a 3D coordination framework with 1D tunnels. Luminescent study shows that complex 1 displays a strong blue emission at room temperature. CCDC: 902023.
- cadmium coordination polymer;2-amino-1, 4-benzenedicarboxylic acid;2-imidazolidinone;urothermal synthesis; photoluminescence
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沈阳化工大学材料科学与工程学院沈阳 110142