Citation: ZHANG Yong, HU Jia-Wei, ZHOU Xia, CHEN Shi-Ming, MA Zhi-Gang, CHEN Xue-Mei. Synthesis, Crystal Structure and SOD Activity of Ni(Ⅱ) Complex with₁, 1, 4, 7, 7-Pentakis (1H-benzimidazol-2-ylmethyl)-1, 4, 7-triazaheptane[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(11): 2491-2496. doi: 10.3969/j.issn.1001-4861.2013.00.348 shu

Synthesis, Crystal Structure and SOD Activity of Ni(Ⅱ) Complex with₁, 1, 4, 7, 7-Pentakis (1H-benzimidazol-2-ylmethyl)-1, 4, 7-triazaheptane

1.
1 School of Chemical and Materials Engineering, Hubei Polytechnic University, Huangshi, Hubei 435003, China;

Received Date: 20 February 2013
Available Online: 3 May 2013
Fund Project: 国家自然科学基金(No.51173060)资助项目。 (No.51173060)

The title complex [Ni(DTPB)H₂Cl]Cl(BF4)₂·4H₂O (DTPB＝1, 1, 4, 7, 7-pentakis(1H-benzimidazol-2-ylmethyl)-1, 4, 7-triazaheptane) has been synthesized and structurally characterized, and its superoxide dismutase (SOD) catalytic activity was investigated by UVspectra. The results showed that the title complex exhibited distorted octahedron geometry, it can inhibit pyrogallol oxidation, IC₅₀ of the complex was 29.8 mg·L^-1, and its SOD activity was affected by reaction temperatures and pH values. CCDC: 606551.
- nickel(Ⅱ) complex;benzimidazole;crystal structure;SOD activity
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通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Synthesis, Crystal Structure and SOD Activity of Ni(Ⅱ) Complex with1, 1, 4, 7, 7-Pentakis (1H-benzimidazol-2-ylmethyl)-1, 4, 7-triazaheptane

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通讯作者: 陈斌, bchen63@163.com

Synthesis, Crystal Structure and SOD Activity of Ni(Ⅱ) Complex with₁, 1, 4, 7, 7-Pentakis (1H-benzimidazol-2-ylmethyl)-1, 4, 7-triazaheptane