Citation: HUANG Bin, CHEN Yun-Cong, GUO Zi-Jian, HE Wei-Jiang. A New Sensitive Fluorescent H2S Probe Based on Cu2+ Complex[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(11): 2283-2288. doi: 10.3969/j.issn.1001-4861.2013.00.347
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As the third gasotransmitter after NOand CO, hydrogen sulfide plays essential biological roles in living systems, and developing sensitive fluorescent probe for the rapid tracking of endogenous H2S is attracting much attention. Anew H2S fluorescent probe was constructed in this study based on a copper complex formed by a new NBD fluorescent ligand, in which a Cu2+ chelator was incorporated. This probe displays very weak emission owing to the emission quenching effect of Cu2+, and it is able to sense H2S by exhibiting distinct emission enhancement upon H2S addition. The S2-induced Cu2+ removal from this complex was proposed as the sensing mechanism of this Cu2+ complex-based probe. Besides the quick response, the high sensing selectivity over other anion of this probe has also been confirmed, and its detection limit was estimated to be ~0.2 μmol·L-1, and the linear range is 1~20 μmol·L-1.
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-
[1]
[1] Szabo C. Nat. Rev. Drug Discovery 2007,6:917-935
-
[2]
[2] Lowicka E, Beltowski J. Pharmacol. Rep., 2007,59:4-24
-
[3]
[3] Li L, Rose P, Moore P K. Annu. Rev. Pharmacol. Toxicol.,2011,51:169-187
-
[4]
[4] DU Jun-Bao (杜军保), CHEN Xiao-Bo(陈小波), GENG Bin(耿彬),et al. J.PekingUniv.:HealthSci.(Beijing DaxueXuebao: Yixue Ban), 2002,34(2):187-187
-
[5]
[5] QIU Wen-Bing(邱文冰), JIN Hong(金红), WANG Dong-Ming(王东明). Adv. Cardiovasc. Dis. (Xinxueguan BingxueJinzhan), 2006,27(suppl 1):84-87
-
[6]
[6] Yang G D, Wu L Y, Jiang B, et al. Science, 2008,322:587-590
-
[7]
[7] Yang C, Yang Z, Zhang M, et al. PLoS ONE, 2011,6:e21971
-
[8]
[8] Li L, Bhatia M, Zhu Y Z, et al. FASEB J., 2005,19:1196-1198
-
[9]
[9] Blackstone E, Morrison M, Roth M B. Science, 2005,308:518-518
-
[10]
[10]Eto K, Asada T A, Arima K, et al. Biochem. Biophys. Res.Commun., 2002,293:1485-1488
-
[11]
[11]Kamoun P, Belardinelli M-C, Chabli A, et al. Am. J. Med.Genet. Part A, 2003,116:310-311
-
[12]
[12]Yang W, Yang G, Jia X, et al. J. Physiol., 2005,569:519-531
-
[13]
[13]Fiorucci S, Antonelli E, Mencarelli A, et al.Hepatology,2005,42:539-548
-
[14]
[14]Lei W, Dasgupta P K. Anal. Chim. Acta, 1989,226:165-170
-
[15]
[15]Jimnez D, Matinez-manez R, Sancenon F, et al. J. Am.Chem. Soc., 2003,125:9000-9001
-
[16]
[16]Richardson C J, Magee E A M, Cummings J H. Clin. Chim.Acta, 2000,293:115-125
-
[17]
[17]Searcy D G, Peterson M A. Anal. Biochem., 2004,324:269-275
-
[18]
[18]Radford-Knoery J, Cutter G A. Anal. Chem., 1993,65:976-982
-
[19]
[19]Berube P R, Parkinson P D, Hall E R. J. Chromatogr. A,1999,830:485-489
-
[20]
[20]Kabil O, Banerjee R. J. Biol. Chem., 2010,285:21903-21907
-
[21]
[21]Olson K R. Biochim. Biophys. Acta Bioenerg., 2009,1787:856-863
-
[22]
[22]Furne J, Saeed A, Levitt M D. Am. J. Physiol. Regul. Integr.Comp. Physiol., 2008,295:R1479-R1485
-
[23]
[23]Lippert A R, New E J, Chang C J. J. Am. Chem. Soc., 2011,133:10078-10080
-
[24]
[24]Peng H, Cheng Y, Dai C, et al. Angew. Chem. Int. Ed.,2011,50:9672-9765
-
[25]
[25]Liu C, Pan J, Li S, Zhao Y, et al. Angew. Chem. Int. Ed.,2011,50:10327-10329
-
[26]
[26]Qian Y, Karpus J, Kabil O, et al. Nat. Commun., 2011,2:495
-
[27]
[27]Chen Y, Zhu C, Yang Z, et al. Angew. Chem. Int. Ed.,2013,52:1688-1691
-
[28]
[28]Sasakura K, Hanaoka K, Shibuya N, et al. J. Am. Chem.Soc., 2011,133:18003-18005
-
[29]
[29]Hou F, Huang L, Xi P, et al. Inorg. Chem., 2012,51:2454-2460
-
[30]
[30]Hou F, Huang L, Xi P, et al. Dalton Trans., 2012,41:5799-5804
-
[31]
[31]Xuan W, Sheng C, Cao Y, et al. Angew. Chem. Int. Ed.2012,51:2282-2284
-
[32]
[32]Lin V S, Chang C J. Curr. Opin. Chem. Biol., 2012,16:595-601
-
[33]
[33]Qian F, Zhang C, Zhang Y, et al. J. Am. Chem. Soc., 2009,131:1460-1468
-
[34]
[34]Uchiyama S, Santa T, Fukushima T, et al. J. Chem. Soc.,Perkin Trans. 2., 1998:2165-2174
-
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