Citation: GAO Zhu-Qing, LI Hong-Jin, GU Jin-Zhong. Synthesis, Crystal Structure and Magnetic Properties of a Zn-Nd Heterometallic Coordination Polymer Constructed by 2-Propyl-1H-imidazole-4, 5-dicarboxylic Acid[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(11): 2460-2464. doi: 10.3969/j.issn.1001-4861.2013.00.343 shu

Synthesis, Crystal Structure and Magnetic Properties of a Zn-Nd Heterometallic Coordination Polymer Constructed by 2-Propyl-1H-imidazole-4, 5-dicarboxylic Acid

1.
1 School of Chemical and Biological Engineering, Taiyuan University of Science and Technology, Taiyuan 030021, China;

Received Date: 16 February 2013
Available Online: 25 May 2013
Fund Project:

Anovel 3d-4f heterometallic coordination polymer, namely, {[NdZn(H₂pimda)₃(Hpimda)(H₂O)₂]·H₂O}_n (1), (H₃pimda=2-propyl-1H-imidazole-4,5-dicarboxylic acid) has been hydrothermally synthesized by using Nd₂O₃, Zn(NO₃)₂·6H₂O and H₃ pimda as raw materials, and characterized by elemental analysis, IR, TG analysis and single crystal X-ray diffraction. The complex 1 crystallizes in the monoclinic system, space group P2₁/c with a=1.19078(2) nm, b=1.30784(3) nm, c=2.74070(5) nm, β=97.9300(10)°, V=4.22741(14) nm³, D_c=1.652 g·cm^-3, Z=4, R=0.0492 and wR=0.1115 (I>2σ(I)). Polymer 1 possesses two-dimensional (2D) network, which further build three-dimensional (3D) supramolecular architecture via N-H…O hydrogen-bonding interactions. Variable temperature magnetic susceptibility studies reveal that complex 1 displays weak antiferromagnetic coupling between the neighboring Nd(Ⅲ) ions. CCDC: 906826.
- 3d-4f coordination polymer;2-propyl-1H-imidazole-4, 5-dicarboxylic acid;hydrogen bond;magnetic property
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沈阳化工大学材料科学与工程学院沈阳 110142