Citation: CHEN Jing, XIE Ji-Min, XIA Chang-Kun, ZHU Yu, CHEN Jia. Synthesis, Characterization and Photoluminescent Property of a Hexanuclear Nickel(Ⅱ) Complex with Trithiocyanuric Acid[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(11): 2433-2437. doi: 10.3969/j.issn.1001-4861.2013.00.339 shu

Synthesis, Characterization and Photoluminescent Property of a Hexanuclear Nickel(Ⅱ) Complex with Trithiocyanuric Acid

1.
School of Chemistry and Chemical Engineering, Jiangsu University, Zhenjiang, Jiangsu 212013, China

Received Date: 16 February 2013
Available Online: 18 March 2013
Fund Project: 国家自然科学基金(No.21171075/B010303) (No.21171075/B010303)教育部博士点基金(No.20093227110009) (No.20093227110009)江苏省自然科学基金(No.BK2010166)资助项目。 (No.BK2010166)

The title complex, [Ni6(H₂O)₆(HTMT)₆]·3(C₂H₅)₃N·7H₂O (1) (H₃TMT=trithiocyanuric acid), was synthesized by slow evaperation, which was characterized by IR, elemental analysis, and single crystal X-ray diffraction. This complex crystallizes in trigonal, space group R3c, with a=b=1.8697(3) nm, c=3.9825(8) nm, γ=120°, V=12.057(4) nm³, C₃₆H₇₇N₂₁Ni₆O₁₃S₁₈, M_r=1941.36, D_c=1.596 gcm^-3, Z=6, μ=1.91 mm^-1, F(000)=6095, the final R=0.047, wR=0.151 for [Ni₆(H₂O)₆(HTMT)₆]·3(C₂H₅)₃N·7H₂O (1) observed reflections (I>2σ(I)). X-ray diffraction analysis reveals that the six nickel(Ⅱ) atoms are bridged by six HTMT^2- and six water molecules into a hexanuclear building unit, the neutral hexanuclear building units are further connected into a three-dimensional framework through the O-H…O and O-H…N hydrogen bonding interactions. The photoluminescent property of complex (I) was also studied at room temperature.
- nickel complex;trithiocyanuric acid;photoluminescent property
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沈阳化工大学材料科学与工程学院沈阳 110142