Citation: GUAN Lei, WANG Ying, LÜ Shan, ZHANG Zhong-Jin, FAN Wen-Ting, GAO Wei. Synthesis, Crystal Structure and Properties of Nickel Complex Containing Pyridine [Ni(py)₃(H₂O)₃](1,5-nds)[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(10): 2079-2084. doi: 10.3969/j.issn.1001-4861.2013.00.336 shu

Synthesis, Crystal Structure and Properties of Nickel Complex Containing Pyridine [Ni(py)₃(H₂O)₃](1,5-nds)

1.
1 School of Chemistry and Materials Science, Liaoning University of Petroleum and Chemical Engineering, Fushun, Liaoning 113001, China;

Received Date: 4 August 2012
Available Online: 5 May 2013
Fund Project: 辽宁石油化工大学博士科研启动经费(No.2011XJJ-033) (No.2011XJJ-033)

The mononuclear containing N-donor ligand Ni(Ⅱ) complex [Ni(py)₃(H₂O)₃](1,5-nds) (py=pyridine, 1,5-nds=1,5-naphthalene-disulfonate anion) was synthesized by slow evaporation method in water. It was characterized by X-ray crystal diffraction, IR, thermal analysis, UV-Vis spectroscopy, etc. The characterization results of X-ray single crystal diffraction show that the crystal of the complex crystallized in monoclinic system with space group C2/c. The unit cell parameters include a=1.56946(17) nm, b=1.21995(12) nm, c=1.45471(16) nm, β=14.5471(16)°, V=2.7651(5) nm³, Z=4. The magnetic and fluorescent properties of the complex were studied. CCDC: 947286.
- nickel anion; complex; thermal stability property; crystal structure; pyridine
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沈阳化工大学材料科学与工程学院沈阳 110142

Synthesis, Crystal Structure and Properties of Nickel Complex Containing Pyridine [Ni(py)3(H2O)3](1,5-nds)

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通讯作者: 陈斌, bchen63@163.com

Synthesis, Crystal Structure and Properties of Nickel Complex Containing Pyridine [Ni(py)₃(H₂O)₃](1,5-nds)