Citation: SHI Jian-Jun, WANG Sheng, HE Ting-Ting, JIANG Li-Ping. Facile Synthesis of Near-Infrared CdTe Quantum Dots via Sonoelectrochemistry and Its Application for Cell Imaging[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(10): 2071-2078. doi: 10.3969/j.issn.1001-4861.2013.00.325 shu

Facile Synthesis of Near-Infrared CdTe Quantum Dots via Sonoelectrochemistry and Its Application for Cell Imaging

1.
1 School of Chemical Engineering, Anhui University of Science and Technology, Huainan, Anhui 232001, China;

Received Date: 3 April 2013
Available Online: 4 June 2013
Fund Project: 国家自然基金(No.21075061) (No.21075061)安徽省自然科学基金(No.1208085MB27) (No.1208085MB27)江苏省新型环保重点实验室开放课题基金(No.AE201107)资助项目 (No.AE201107)

Aiming at the simplification of synthesis routes and the improvement of photoluminescence quantum yields (PL QYs), a facile and fast method has been developed to synthesize CdTe quantum dots (QDs) precursor in aqueous phase by sonoelectrochemistry without the protection of N₂. The high qualities, water-soluble, near-infrared-emitting CdTe QDs were obtained by refluxing of the precursors in oil bath. The morphology, structure and composition of the products were investigated by HRTEMand XRD. The influences of sonoelectrochemical and refluxing parameters on the PLproperties of products were studied. By adjusting the current pulse width, reaction time and reaction temperature, the size- and morphology-controlled CdTe QDs precursors were obtained. CdTe QDs with different emission wavelengths were obtained by followed refluxing. The as-prepared QDs with near-infrared emission of 602 nm were used in the labeling of Hela cell and imaging by confocal laser scanning microscopy (CLSM). Compared with traditional synthesis, sonoelectrochemical route is facile and controllable in the synthesis for water-soluble high-quality QDs, which extends its application in the preparation of nanomaterials.
- sonoelectrochemistry; cadmium telluride; near-infrared quantum dots; controllable precursor; cell imaging
1. [1]
  [1] Yong K T, Law W C, Roy I, et al. J. Biophotonics, 2011,4(1- 2):9-20 [2] Gui M F, Bao L J, Xia Y S, et al. Biosen. Bioelectron., 2011, 30(1):324-327 [3] Scholes G D. Adv. Funct. Mater., 2008,18(8):1157-1172 [4] Chen L N, Wang J, Li W T, et al. Chem. Commun., 2012, 48:4971-4973 [5] QIU Yue-Qin (邱月琴), CAI Ji-Ye(蔡继业). Mater. Rev. A (Cailiao Daobao A), 2012,26(1):16-19 [6] Chen Z Z, Ren X L, Meng X W, et al. Anal. Chem., 2012, 84(9):4077-4082 [7] Shen H P, Lin H, Liu Y Z, et al. J. Phys. Chem. C, 2012, 116(29):15185-15191 [8] XIE Hai-Yan(谢海燕), PANG Dai-Wen(庞代文). Chin. J. Anal. Chem.(Fenxi Huaxue), 2004,32(8):1099-1103 [9] CHEN Zheng (陈征), DENG Zhen-Bo(邓振波), ZHOU Mao- Yang(周茂杨). Spectrosc Spect Anal(Guangpuxue Yu Guangpu Fenxi), 2012,32(8):2214-2217 [10]Ruland A, Schulz-Drost C, Sgobba V, et al. Adv. Mater., 2011,23(39):4573-4577 [11]Zhou D, Lin M, Chen Z L, et al. Chem. Mater., 2011,23(21): 4857-4862 [12]Menezes F D, Galembeck A, Alves Junior S. Ultrason. Sonochem., 2011,18(5):1008-1011 [13]Luo X T, Han J S, Ning Y, et al. J. Mater. Chem., 2011,21 (18):6569-6575 [14]Samanta A, Deng Z T, Liu Y. Langmuir., 2012,28(21):8205- 8215 [15]WANG Shan-Shan(王珊珊), WANG Xue-Ting(王雪婷), GUO Ming-Ming(郭明明), et al. Chem. J. Chinese Universities (Gaodeng Xuexiao Huaxue Xuebao), 2012,33(9):1195-1204 [16]Pickett N L, Lawson S, Thomas W G, et al. J. Mater. Chem., 1998,8(12):2769-2776 [17]Qu L H, Peng X G, J. Am. Chem. Soc., 2002,124(9):2049- 2055 [18]Peng Z A, Peng X G. J. Am. Chem. Soc., 2001,123(1):183- 184 [19]Talapin D V, Rogach A L, Mekis I, et al. Colloids Surf., A, 2002,202(2/3):145-154 [20]Gaponik N, Talapin D V, Rogach A L, et al. J. Phys. Chem. B, 2002,106(29):7177-7185 [21]He Y, Sai L M, Lu H T, et al. Chem. Mater., 2007,19(3): 359-365 [22]SUI Chao-Xia(睢超霞),ZHANG Wen-Hao(张文豪). Chem. Res. Appl.(Huaxue Yanjiu Yu Yingyong), 2011,23(11):1435 -1440 [23]MAO Bing-Xue(毛炳雪), JIANG Hong-Ji(姜鸿基). Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2012,28(9):1817- 1826 [24]WANG Yi-Lin(王益林), WAN Xin(万鑫), LIU Sheng-Yan (刘声艳), et al. Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2012,28(1):97-102 [25]JIANG Li-Ping(姜立萍), ZHANG Jian-Rong(张剑荣), WANG Jun(王骏), et al. Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2002,18(11):1161-1164 [26]Zhu J J, Aruna S T, Koltypin Y, et al. Chem. Mater., 2000, 12(1):143-147 [27]SHEN Qing-Ming(沈清明), MIN Qian-Hao(闵乾昊), SHI Jian-Jun(石建军), et al. Acta Chim. Sin.(Huaxue Xuebao), 2010,68(13):1319-1324 [28]Qiu X F, Lou Y B, Samia Anna C S, et al. Angew. Chem. Int. Ed., 2005,44(36):5855-5857 [29]Qiu X F, Austin L N, Muscarella P A, et al. Angew. Chem. Int. Ed., 2006,45(34):5656-5659 [30]Shen Q M, Min Q H, Shi J J, et al. Ultrason. Sonochem., 2011,18(1):231-237 [31]Mahendiran C, Ganesan R, Gedanken A. Eur. J. Inorg. Chem., 2009(14):2050-2053 [32]Shi J J, Wang Y J, Ma Y, et al. Ultrason. Sonochem., 2012, 19(5):1039-1043 [33]LU Xia(鹿霞), ZHONG Wen-Ying (钟文英), YU Jun-Sheng (于俊生). Chinese J. Anal. Lab(Fenxi Shiyanshi), 2009,28 (1):36-40 [34]Peng X G, Wickham J, Alivisatos A P. J. Am. Chem. Soc., 1998,120(21):5343-5344 [35]Yu W W, Qu L H, Guo W Z, et al. Chem. Mater., 2003,15 (14):2854-2860 [36]Ge C W, Xu M, Liu J, et al. Chem. Commun., 2008(4):450- 452
1. [1]
  Jiakun BAI , Ting XU , Lu ZHANG , Jiang PENG , Yuqiang LI , Junhui JIA . A red-emitting fluorescent probe with a large Stokes shift for selective detection of hypochlorous acid. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1095-1104. doi: 10.11862/CJIC.20240002
2. [2]
  Siyi ZHONG , Xiaowen LIN , Jiaxin LIU , Ruyi WANG , Tao LIANG , Zhengfeng DENG , Ao ZHONG , Cuiping HAN . Targeting imaging and detection of ovarian cancer cells based on fluorescent magnetic carbon dots. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1483-1490. doi: 10.11862/CJIC.20240093
3. [3]
  Tiantian MA , Sumei LI , Chengyu ZHANG , Lu XU , Yiyan BAI , Yunlong FU , Wenjuan JI , Haiying YANG . Methyl-functionalized Cd-based metal-organic framework for highly sensitive electrochemical sensing of dopamine. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 725-735. doi: 10.11862/CJIC.20230351
4. [4]
  Jiahong ZHENG , Jiajun SHEN , Xin BAI . Preparation and electrochemical properties of nickel foam loaded NiMoO₄/NiMoS₄ composites. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 581-590. doi: 10.11862/CJIC.20230253
5. [5]
  Zhihuan XU , Qing KANG , Yuzhen LONG , Qian YUAN , Cidong LIU , Xin LI , Genghuai TANG , Yuqing LIAO . Effect of graphene oxide concentration on the electrochemical properties of reduced graphene oxide/ZnS. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1329-1336. doi: 10.11862/CJIC.20230447
6. [6]
  Qin ZHU , Jiao MA , Zhihui QIAN , Yuxu LUO , Yujiao GUO , Mingwu XIANG , Xiaofang LIU , Ping NING , Junming GUO . Morphological evolution and electrochemical properties of cathode material LiAl_0.08Mn_1.92O₄ single crystal particles. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1549-1562. doi: 10.11862/CJIC.20240022
7. [7]
  Qingtang ZHANG , Xiaoyu WU , Zheng WANG , Xiaomei WANG . Performance of nano Li₂FeSiO₄/C cathode material co-doped by potassium and chlorine ions. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1689-1696. doi: 10.11862/CJIC.20240115
8. [8]
  Lu XU , Chengyu ZHANG , Wenjuan JI , Haiying YANG , Yunlong FU . Zinc metal-organic framework with high-density free carboxyl oxygen functionalized pore walls for targeted electrochemical sensing of paracetamol. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 907-918. doi: 10.11862/CJIC.20230431
9. [9]
  Yuanchao LI , Weifeng HUANG , Pengchao LIANG , Zifang ZHAO , Baoyan XING , Dongliang YAN , Li YANG , Songlin WANG . Effect of heterogeneous dual carbon sources on electrochemical properties of LiMn_0.8Fe_0.2PO₄/C composites. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 751-760. doi: 10.11862/CJIC.20230252
10. [10]
  Xinpeng LIU , Liuyang ZHAO , Hongyi LI , Yatu CHEN , Aimin WU , Aikui LI , Hao HUANG . Ga₂O₃ coated modification and electrochemical performance of Li_1.2Mn_0.54Ni_0.13Co_0.13O₂ cathode material. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1105-1113. doi: 10.11862/CJIC.20230488
11. [11]
  Jing SU , Bingrong LI , Yiyan BAI , Wenjuan JI , Haiying YANG , Zhefeng Fan . Highly sensitive electrochemical dopamine sensor based on a highly stable In-based metal-organic framework with amino-enriched pores. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1337-1346. doi: 10.11862/CJIC.20230414
12. [12]
  Zeyu XU , Anlei DANG , Bihua DENG , Xiaoxin ZUO , Yu LU , Ping YANG , Wenzhu YIN . Evaluation of the efficacy of graphene oxide quantum dots as an ovalbumin delivery platform and adjuvant for immune enhancement. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1065-1078. doi: 10.11862/CJIC.20240099
13. [13]
  Hongyi LI , Aimin WU , Liuyang ZHAO , Xinpeng LIU , Fengqin CHEN , Aikui LI , Hao HUANG . Effect of Y(PO₃)₃ double-coating modification on the electrochemical properties of Li[Ni_0.8Co_0.15Al_0.05]O₂. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1320-1328. doi: 10.11862/CJIC.20230480
14. [14]
  Di WU , Ruimeng SHI , Zhaoyang WANG , Yuehua SHI , Fan YANG , Leyong ZENG . Construction of pH/photothermal dual-responsive delivery nanosystem for combination therapy of drug-resistant bladder cancer cell. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1679-1688. doi: 10.11862/CJIC.20240135
15. [15]
  Donghui PAN , Yuping XU , Xinyu WANG , Lizhen WANG , Junjie YAN , Dongjian SHI , Min YANG , Mingqing CHEN . Preparation and in vivo tracing of ⁶⁸Ga-labeled PM_2.5 mimetic particles for positron emission tomography imaging. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 669-676. doi: 10.11862/CJIC.20230468
16. [16]
  Xinyu ZENG , Guhua TANG , Jianming OUYANG . Inhibitory effect of Desmodium styracifolium polysaccharides with different content of carboxyl groups on the growth, aggregation and cell adhesion of calcium oxalate crystals. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1563-1576. doi: 10.11862/CJIC.20230374
17. [17]
  Jinlong YAN , Weina WU , Yuan WANG . A simple Schiff base probe for the fluorescent turn-on detection of hypochlorite and its biological imaging application. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1653-1660. doi: 10.11862/CJIC.20240154
18. [18]
  Xiaosong PU , Hangkai WU , Taohong LI , Huijuan LI , Shouqing LIU , Yuanbo HUANG , Xuemei LI . Adsorption performance and removal mechanism of Cd(Ⅱ) in water by magnesium modified carbon foam. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1537-1548. doi: 10.11862/CJIC.20240030
19. [19]
  Guangming YIN , Huaiyao WANG , Jianhua ZHENG , Xinyue DONG , Jian LI , Yi'nan SUN , Yiming GAO , Bingbing WANG . Preparation and photocatalytic degradation performance of Ag/protonated g-C₃N₄ nanorod materials. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1491-1500. doi: 10.11862/CJIC.20240086
20. [20]
  Xinting XIONG , Zhiqiang XIONG , Panlei XIAO , Xuliang NIE , Xiuying SONG , Xiuguang YI . Synthesis, crystal structures, Hirshfeld surface analysis, and antifungal activity of two complexes Na(Ⅰ)/Cd(Ⅱ) assembled by 5-bromo-2-hydroxybenzoic acid ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1661-1670. doi: 10.11862/CJIC.20240145

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(151)
HTML views(2)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142