Citation: SHI Jian-Jun, WANG Sheng, HE Ting-Ting, JIANG Li-Ping. Facile Synthesis of Near-Infrared CdTe Quantum Dots via Sonoelectrochemistry and Its Application for Cell Imaging[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(10): 2071-2078. doi: 10.3969/j.issn.1001-4861.2013.00.325
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Aiming at the simplification of synthesis routes and the improvement of photoluminescence quantum yields (PL QYs), a facile and fast method has been developed to synthesize CdTe quantum dots (QDs) precursor in aqueous phase by sonoelectrochemistry without the protection of N2. The high qualities, water-soluble, near-infrared-emitting CdTe QDs were obtained by refluxing of the precursors in oil bath. The morphology, structure and composition of the products were investigated by HRTEMand XRD. The influences of sonoelectrochemical and refluxing parameters on the PLproperties of products were studied. By adjusting the current pulse width, reaction time and reaction temperature, the size- and morphology-controlled CdTe QDs precursors were obtained. CdTe QDs with different emission wavelengths were obtained by followed refluxing. The as-prepared QDs with near-infrared emission of 602 nm were used in the labeling of Hela cell and imaging by confocal laser scanning microscopy (CLSM). Compared with traditional synthesis, sonoelectrochemical route is facile and controllable in the synthesis for water-soluble high-quality QDs, which extends its application in the preparation of nanomaterials.
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[1] Yong K T, Law W C, Roy I, et al. J. Biophotonics, 2011,4(1- 2):9-20 [2] Gui M F, Bao L J, Xia Y S, et al. Biosen. Bioelectron., 2011, 30(1):324-327 [3] Scholes G D. Adv. Funct. Mater., 2008,18(8):1157-1172 [4] Chen L N, Wang J, Li W T, et al. Chem. Commun., 2012, 48:4971-4973 [5] QIU Yue-Qin (邱月琴), CAI Ji-Ye(蔡继业). Mater. Rev. A (Cailiao Daobao A), 2012,26(1):16-19 [6] Chen Z Z, Ren X L, Meng X W, et al. Anal. Chem., 2012, 84(9):4077-4082 [7] Shen H P, Lin H, Liu Y Z, et al. J. Phys. Chem. C, 2012, 116(29):15185-15191 [8] XIE Hai-Yan(谢海燕), PANG Dai-Wen(庞代文). Chin. J. Anal. Chem.(Fenxi Huaxue), 2004,32(8):1099-1103 [9] CHEN Zheng (陈征), DENG Zhen-Bo(邓振波), ZHOU Mao- Yang(周茂杨). Spectrosc Spect Anal(Guangpuxue Yu Guangpu Fenxi), 2012,32(8):2214-2217 [10]Ruland A, Schulz-Drost C, Sgobba V, et al. Adv. Mater., 2011,23(39):4573-4577 [11]Zhou D, Lin M, Chen Z L, et al. Chem. Mater., 2011,23(21): 4857-4862 [12]Menezes F D, Galembeck A, Alves Junior S. Ultrason. Sonochem., 2011,18(5):1008-1011 [13]Luo X T, Han J S, Ning Y, et al. J. Mater. Chem., 2011,21 (18):6569-6575 [14]Samanta A, Deng Z T, Liu Y. Langmuir., 2012,28(21):8205- 8215 [15]WANG Shan-Shan(王珊珊), WANG Xue-Ting(王雪婷), GUO Ming-Ming(郭明明), et al. Chem. J. Chinese Universities (Gaodeng Xuexiao Huaxue Xuebao), 2012,33(9):1195-1204 [16]Pickett N L, Lawson S, Thomas W G, et al. J. Mater. Chem., 1998,8(12):2769-2776 [17]Qu L H, Peng X G, J. Am. Chem. Soc., 2002,124(9):2049- 2055 [18]Peng Z A, Peng X G. J. Am. Chem. Soc., 2001,123(1):183- 184 [19]Talapin D V, Rogach A L, Mekis I, et al. Colloids Surf., A, 2002,202(2/3):145-154 [20]Gaponik N, Talapin D V, Rogach A L, et al. J. Phys. Chem. B, 2002,106(29):7177-7185 [21]He Y, Sai L M, Lu H T, et al. Chem. Mater., 2007,19(3): 359-365 [22]SUI Chao-Xia(睢超霞),ZHANG Wen-Hao(张文豪). Chem. Res. Appl.(Huaxue Yanjiu Yu Yingyong), 2011,23(11):1435 -1440 [23]MAO Bing-Xue(毛炳雪), JIANG Hong-Ji(姜鸿基). Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2012,28(9):1817- 1826 [24]WANG Yi-Lin(王益林), WAN Xin(万鑫), LIU Sheng-Yan (刘声艳), et al. Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2012,28(1):97-102 [25]JIANG Li-Ping(姜立萍), ZHANG Jian-Rong(张剑荣), WANG Jun(王骏), et al. Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2002,18(11):1161-1164 [26]Zhu J J, Aruna S T, Koltypin Y, et al. Chem. Mater., 2000, 12(1):143-147 [27]SHEN Qing-Ming(沈清明), MIN Qian-Hao(闵乾昊), SHI Jian-Jun(石建军), et al. Acta Chim. Sin.(Huaxue Xuebao), 2010,68(13):1319-1324 [28]Qiu X F, Lou Y B, Samia Anna C S, et al. Angew. Chem. Int. Ed., 2005,44(36):5855-5857 [29]Qiu X F, Austin L N, Muscarella P A, et al. Angew. Chem. Int. Ed., 2006,45(34):5656-5659 [30]Shen Q M, Min Q H, Shi J J, et al. Ultrason. Sonochem., 2011,18(1):231-237 [31]Mahendiran C, Ganesan R, Gedanken A. Eur. J. Inorg. Chem., 2009(14):2050-2053 [32]Shi J J, Wang Y J, Ma Y, et al. Ultrason. Sonochem., 2012, 19(5):1039-1043 [33]LU Xia(鹿霞), ZHONG Wen-Ying (钟文英), YU Jun-Sheng (于俊生). Chinese J. Anal. Lab(Fenxi Shiyanshi), 2009,28 (1):36-40 [34]Peng X G, Wickham J, Alivisatos A P. J. Am. Chem. Soc., 1998,120(21):5343-5344 [35]Yu W W, Qu L H, Guo W Z, et al. Chem. Mater., 2003,15 (14):2854-2860 [36]Ge C W, Xu M, Liu J, et al. Chem. Commun., 2008(4):450- 452
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