Citation: ZHAI Hua-Song, WANG Kun-Peng, YU Chun-Yan, ZHAI Guang-Mei, DONG Hai-Liang, XU Bing-She. Effect of N2 Flow Rate on Morphology, Optical and Electrical Properties of GaN[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(10): 2027-2033. doi: 10.3969/j.issn.1001-4861.2013.00.323
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GaN micro/nanostructures were synthesized by chemical vapor deposition method (CVD) on Si (100) substrate with catalyst Ni, Ga and NH3 as raw materials. Effect of N2 flow rate on the morphology as well as optical and electrical properties of GaNwere researched. The morphology, structure, composition, optical and electrical properties were characterized by Field emission scanning electron microscopy (SEM), Transmission electron microscopy(TEM), X-ray diffraction (XRD), Energy dispersive X-ray spectroscopy (EDS), Photoluminescence (PL) and Hall effect measurement system (HMS-3000). The results indicate that with the increase of N2 flow rate, the morphology of GaNevolved from microrods to vermicular-like wires and then to smooth nanowires. All samples are hexagonal wurtzite, and show near-band-edge UVemission peaks of 383 nm and blue light emission peaks of about 470 nm. Hall test results show that all samples are p-type. Furthermore, the morphology evolution mechanisms of GaNare analyzed.
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[1] Qian F, Li Y, Gradecak S, et al. Nat. Mater., 2008,7:701- 706 [2] Tomioka K, Motohisa J, Hara S, et al. Nano Lett, 2010,10(5): 1639-1644 [3] Schwarz U T, Pindl M, Wegscheider W, et al. Appl. Phys. Lett., 2005,86(16):161112-161115 [4] ZHU Lin(朱琳), YU Chun-Yan(余春燕), LIANG Jian(梁建), et al. Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2013, 29(1):63-68 [5] Seryogin G, Shalish I, Moberlychan W, et al. Nano Technol., 2005,16:2342-2345 [6] Dong Z H, Xue C S, Zhuang H Z, et al. Nano struct., 2005, 27:32-37 [7] Cai X M, Djuri?觢ic A B, Xie M H, et al. Appl. Phys. Lett., 2005, 87(18):183103-183105 [8] Wang L, Zhang X, Huang R, et al. Solid State Commun., 2004,130(11):769-772 [9] Yin L W, Bando Y, Zhu Y C, et al. Appl. Phys. Lett., 2004, 84(19):3912-3914 [10]Tu L W, Hsiao C L, Chi T W, et al. Appl. Phys. Lett., 2003, 82(10):1601-1603 [11]Kim H M, Kim D S, Kim D Y, et al. Appl. Phys. Lett., 2002,81(12):2193-2195 [12]Kim H M, Kim D S, Park Y S, et al. Adv Mater., 2002,14 (13-14):991-993 [13]Li Z J, Chen X L, Li H J, et al. Appl. Phys. A, 2001,72(5): 629-632 [14]LIANG Jian(梁建), LIU Hai-Rui(刘海瑞), WANG Xiao-Ning (王晓宁), et al. Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2013,29(5):1019-1024 [15]Chung R B, Han C, Pan C C, et al. Appl. Phys. Lett., 2012, 101(13):131113-131116 [16]WANG Xiao-Yong(王晓勇), ZHONG Ming(种明), ZHAO De -Gang(赵德刚), et al. Acta Phys. Sin.(Wuli Xuebao), 2012, 61(21):217302-217307 [17]Kwon H Y, Shin M J, Choi Y J, et al. Cryst. Growth Des., 2009,311(16);4146-4151 [18]Hersee S D, Sun X Y, Wang X. Nano Lett, 2006,6(8):1808 -1811 [19]Seong H K, Jeong H, Ha R, et al. Mater. Int., 2008,14(3): 353-356 [20]Xiang X, Cao C B, Zhai H Z, et al. Appl. Phys. A, 2005,80 (5):1129-1132 [21]Lü W, Wu L L, Wu Y S, et al. Cryst. Growth Des., 2007, 307(1):1-5 [22]CAO Yu-Ping(曹玉萍), XUE Cheng-Shan(薛成山), SHI Feng(石锋), et al. J. Funct. Mater.(Gongneng Cailiao), 2010, 41(2):264-267 [23]Beh K P, Yam F K, Low L L, et al. Acuum, 2013,95:6-11 [24]Cai X M, Djuri?觢ic A B, Xie M H, Thin Solid Films., 2006, 515(3):984-989 [25]Shi F, Zhang D D, Xue C S. Mater. Sci. Eng. B, 2010,167 (2):80-84 [26]Huang C T, Song J H, Lee W F, et al. J. Am. Chem. Soc., 2010,132(13):4766-4771 [27]Low L L, Yam F K, Beh K P, et al. Appl. Surf. Sci., 2011, 258(1):542-546 [28]Kang S, Kang B K, Kim S W, et al. Cryst. Growth Des., 2010,10(6):2581-2584 [29]Wei X F, Shi F. Appl. Surf. Sci., 2011,257(23):9931-9934 [30]Furtmayr F, Vielemeyer M, Stutzmann M, et al. J. Appl. Phys., 2008,104(3):034309-034315 [31]Navamathavan R, Ra Y H, Song K Y, et al. Appl. Phys., 2011,11(1):77-81 [32]Wang Y, Xue C, Zhuang H, et al. Appl. Surf. Sci., 2009, 255:7719-7722 [33]Seryogin G, Shalish I, Moberlychan W, et al. Nanotechnology, 2005,16:2342-2345 [34]Low L L,Yam F K,Beh K P, et al. Appl. Surf. Sci., 2011, 258(1):542-546 [35]Su Y, Gao M, Meng X, et al. J. Phys. Chem. Solids., 2009, 70(7):1062-1065 [36]Zhang G Y, Tong Y Z, Yang Z J, et al. Appl. Phys. Lett., 1997,71(23):3376-3378 [37]Kim J R, Kim B K, Lee I J, et al. Phys. Rev. B, 2004,69 (23):233303-233306 [38]Li J Y, An L, Lu C G, et al. Nano Lett., 2006,6(2):148-152
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