Citation: SUN Chang-Yan, LI Yang, LI Wen-Jun, CHE Ping. Templating Synthesis and Structures of Microporous Lanthanide Supramolecular Complexes Based on 2-Carboxycinnamic Acid[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(10): 2140-2144. doi: 10.3969/j.issn.1001-4861.2013.00.318 shu

Templating Synthesis and Structures of Microporous Lanthanide Supramolecular Complexes Based on 2-Carboxycinnamic Acid

1.
Beijing Key Laboratory for Science and Application of Functional Molecular and Crystalline Materials, School of Chemistry and Biological Engineering, University of Science and Technology Beijing, Beijing 100083, China

Received Date: 28 December 2012
Available Online: 16 June 2013
Fund Project: 国家自然科学基金(No.21101013) (No.21101013)中央高校基本科研业务费专项资金(No.FRF-SD-13-002B)资助项目 (No.FRF-SD-13-002B)

Two microporous lanthanide supramolecular complexes [Ln(CCA)(OH)(phen)(H₂O)]_n·n(phen)·nH₂O(Ln=Yb, 1; Er, 2; H₂CCA=2-carboxycinnamic acid; phen=1,10-phenanthraline) were obtained through hydrothermal reaction and characterized by elemental analysis, IRand single-crystal X-ray diffraction. The results show that the two complexes are isostructural and in the two complexes, dinuclear Ln₂(OH)₂ units are linked by CCA²-ligands to form 1Dinfinite double-stranded chains. There are two kinds of phen ligands. One adopts a chelating-bidentate coordination mode, the other is not involved in the coordination and acts as templating ligands, which leads to the formation of supramolecular networks with microporous structures. CCDC: 917027, 1; 917028, 2.
- 2-carboxycinnamic acid; lanthanide complex; microporous structure; template
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沈阳化工大学材料科学与工程学院沈阳 110142