Citation: XIONG Ying, LOU Zhen-Ning, SHAN Wei-Jun, REN Fu-Qiang, LI Ye-Xia, ZANG Shu-Liang. Recovery of Mo(Ⅵ) from Re(Ⅶ)-Containing Wastewater by Chemically Modified Orange Waste:Competitiveness and Selectivity[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(8): 1717-1723. doi: 10.3969/j.issn.1001-4861.2013.00.317
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New adsorption gel (OW-NH2) was prepared by chemically immobilizing functional group of amine orange waste. For the system of Mo(Ⅵ) coexisted with Re(Ⅶ), Pb(Ⅱ), Fe(Ⅲ), Zn(Ⅱ), Mn(Ⅶ) Ca(Ⅱ) and Cu(Ⅱ), the gel exhibits selectivity only for Mo(Ⅵ). The maximum adsorption capacity for Mo(Ⅵ) is 1.71 mmol·g-1, and the adsorption behavior obeys the Langmuir model. The adsorption mechanism of molybdenum anion could be explained as the anion exchange reactions. In addition, the excellent adsorption characteristics for Mo(Ⅵ) are confirmed by separation of Mo(Ⅵ) from Mo-Re containing industrial effluent.
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Keywords:
- adsorption;biomass;molybdenum;rhenium
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