Citation: WANG Shi, CUI Lin-Fang, LI Xing-Ao, WANG Lian-Hui, HUANG Wei. Synthesis, Crystal Structure and Magnetic Properties of a Tetragonally Compressed High-Spin Mn(Ⅲ) Schiff Base Complex[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(8): 1733-1737. doi: 10.3969/j.issn.1001-4861.2013.00.313
-
The synthesis, crystal structure and magnetic properties of a new six-coordinated high-spin (HS) Mn(Ⅲ) Schiff base complex, [MnⅢ(3-MeO-sal-N(1,5,9,13))]ClO4H2O (1) are described. The ligand 3-MeO-sal-N(1,5,9,13) is a hexadentate Schiff base obtained from N,N'-bis(3-aminopropyl)-1,3-propanediamine and 2-hydroxy-3-methoxy benzaldehyde. Compound 1 crystallizes in monoclinic space group P21/c, with a=0.806 43(2) nm, b=2.049 31(4) nm, c=1.709 74(3) nm, β=101.302 0(10)°, V=2.770 77(10) nm3, Z=4, R=0.055 4 and wR=0.136 0 (I >2σ(I)). Single crystal X-ray diffraction analysis reveals that the Mn site has a tetragonally compressed octahedral geometry. The magnetic susceptibilities measurements indicate the HS ground state in the temperature range 1.8~300 K. The magnetic data are well fitted by Zero-Field-Splitting (ZFS) Hamiltonian, showing a D >0 parameter, in line with the compressed octahedron pattern. CCDC: 926103.
-
-
[1]
[1] Sessoli R, Tsai H L, Schake A R, et al. J. Am. Chem. Soc., 1993,115:1804-1816
-
[2]
[2] Miyasaka H, Saitoh A, Abe S. Coord. Chem. Rev., 2007,251: 2622-2664
-
[3]
[3] Mantel C, Hassan A K, Pecaut J, et al. J. Am. Chem. Soc., 2003,125:12337-12344
-
[4]
[4] Goldsmith C R, Cole A P, Stack T D P. J. Am. Chem. Soc., 2005,127:9904-9912
-
[5]
[5] Triller M U, Pursche D, Hsieh W Y, et al. Inorg. Chem., 2003,42:6274-6283
-
[6]
[6] Romain S, Duboc C, Neese F, et al. Chemistry, 2009,15:980-988
-
[7]
[7] Murray K S. Eur. J. Inorg. Chem., 2008:3101-3121
-
[8]
[8] Garcia Y, Gütlich P. Topics in Current Chemistry: Vol.234. Gülich P, Goodwin H A Ed., Berlin: Springer-Verlag, 2004: 49-62
-
[9]
[9] Liu Z, Liang S, Di X, et al. Inorg. Chem. Commun., 2008, 11:783-786
-
[10]
[10] Bera M, Biradha K, Ray D. Inorg. Chim. Acta, 2004,357: 3556-3562
-
[11]
[11] Morgan G G, Murnaghan K D, MullerBunz H, et al. Angew. Chem. Int. Ed., 2006,45:7192-7195
-
[12]
[12] Pandurangan K, Gildea B, Murray C, et al. Chem. Eur. J., 2012,18:2021-2029
-
[13]
[13] Wang S, Ferbinteanu M, Marinescu C, et al. Inorg. Chem., 2010,49:9839-9851
-
[14]
[14] SMART, SAINT, and XPREP, Area Detector Control and Data Integration and Reduction Software; Bruker Analytical X-ray Instruments Inc.: Madison, WI, 1995.
-
[15]
[15] Sheldrick G M. SHELX97, Programs for Crystal Structure Analysis, University of Göttingen, Göttingen, Germany, 1998.
-
[16]
[16] Tregenna-Piggott P L W. Inorg. Chem., 2008,47:448-453
-
[17]
[17] Scheifele Q, Piplinger C, Neese F, et al. Inorg. Chem., 2008,47:439-447
-
[18]
[18] Shores M P, Sokol J J, Long J R. J. Am. Chem. Soc., 2002, 124:2279-2292
-
[1]
-
-
[1]
Yingchun ZHANG , Yiwei SHI , Ruijie YANG , Xin WANG , Zhiguo SONG , Min WANG . Dual ligands manganese complexes based on benzene sulfonic acid and 2, 2′-bipyridine: Structure and catalytic properties and mechanism in Mannich reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1501-1510. doi: 10.11862/CJIC.20240078
-
[2]
Qilu DU , Li ZHAO , Peng NIE , Bo XU . Synthesis and characterization of osmium-germyl complexes stabilized by triphenyl ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1088-1094. doi: 10.11862/CJIC.20240006
-
[3]
Haitang WANG , Yanni LING , Xiaqing MA , Yuxin CHEN , Rui ZHANG , Keyi WANG , Ying ZHANG , Wenmin WANG . Construction, crystal structures, and biological activities of two LnⅢ3 complexes. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1474-1482. doi: 10.11862/CJIC.20240188
-
[4]
Jingjing QING , Fan HE , Zhihui LIU , Shuaipeng HOU , Ya LIU , Yifan JIANG , Mengting TAN , Lifang HE , Fuxing ZHANG , Xiaoming ZHU . Synthesis, structure, and anticancer activity of two complexes of dimethylglyoxime organotin. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1301-1308. doi: 10.11862/CJIC.20240003
-
[5]
Yan LIU , Jiaxin GUO , Song YANG , Shixian XU , Yanyan YANG , Zhongliang YU , Xiaogang HAO . Exclusionary recovery of phosphate anions with low concentration from wastewater using a CoNi-layered double hydroxide/graphene electronically controlled separation film. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1775-1783. doi: 10.11862/CJIC.20240043
-
[6]
Xin MA , Ya SUN , Na SUN , Qian KANG , Jiajia ZHANG , Ruitao ZHU , Xiaoli GAO . A Tb2 complex based on polydentate Schiff base: Crystal structure, fluorescence properties, and biological activity. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1347-1356. doi: 10.11862/CJIC.20230357
-
[7]
Zhaoyang WANG , Chun YANG , Yaoyao Song , Na HAN , Xiaomeng LIU , Qinglun WANG . Lanthanide(Ⅲ) complexes derived from 4′-(2-pyridyl)-2, 2′∶6′, 2″-terpyridine: Crystal structures, fluorescent and magnetic properties. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1442-1451. doi: 10.11862/CJIC.20240114
-
[8]
Xinting XIONG , Zhiqiang XIONG , Panlei XIAO , Xuliang NIE , Xiuying SONG , Xiuguang YI . Synthesis, crystal structures, Hirshfeld surface analysis, and antifungal activity of two complexes Na(Ⅰ)/Cd(Ⅱ) assembled by 5-bromo-2-hydroxybenzoic acid ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1661-1670. doi: 10.11862/CJIC.20240145
-
[9]
Yuanpei ZHANG , Jiahong WANG , Jinming HUANG , Zhi HU . Preparation of magnetic mesoporous carbon loaded nano zero-valent iron for removal of Cr(Ⅲ) organic complexes from high-salt wastewater. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1731-1742. doi: 10.11862/CJIC.20240077
-
[10]
Doudou Qin , Junyang Ding , Chu Liang , Qian Liu , Ligang Feng , Yang Luo , Guangzhi Hu , Jun Luo , Xijun Liu . Addressing Challenges and Enhancing Performance of Manganese-based Cathode Materials in Aqueous Zinc-Ion Batteries. Acta Physico-Chimica Sinica, 2024, 40(10): 2310034-. doi: 10.3866/PKU.WHXB202310034
-
[11]
Zongfei YANG , Xiaosen ZHAO , Jing LI , Wenchang ZHUANG . Research advances in heteropolyoxoniobates. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 465-480. doi: 10.11862/CJIC.20230306
-
[12]
Chuanming GUO , Kaiyang ZHANG , Yun WU , Rui YAO , Qiang ZHAO , Jinping LI , Guang LIU . Performance of MnO2-0.39IrOx composite oxides for water oxidation reaction in acidic media. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1135-1142. doi: 10.11862/CJIC.20230459
-
[13]
Endong YANG , Haoze TIAN , Ke ZHANG , Yongbing LOU . Efficient oxygen evolution reaction of CuCo2O4/NiFe-layered bimetallic hydroxide core-shell nanoflower sphere arrays. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 930-940. doi: 10.11862/CJIC.20230369
-
[14]
Qiangqiang SUN , Pengcheng ZHAO , Ruoyu WU , Baoyue CAO . Multistage microporous bifunctional catalyst constructed by P-doped nickel-based sulfide ultra-thin nanosheets for energy-efficient hydrogen production from water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1151-1161. doi: 10.11862/CJIC.20230454
-
[1]
Metrics
- PDF Downloads(0)
- Abstract views(157)
- HTML views(26)