Citation: YUAN Guo-Zan, RONG Lu-Lu, QIAO Xue-Long, XIA Yin-Pan, GUO Ting, WEI Xian-Wen. Synthesis, Crystal Structures and Properties of One Binuclear Zinc Complex from a Novel 2-Substituted-8-Hydroxyquinoline Ligand[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(8): 1769-1776. doi: 10.3969/j.issn.1001-4861.2013.00.310
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A 2-substituted-8-hydroxyquinoline ligand (E)-2-[2-(4-Methoxyphenyl)ethenyl]-8-hydroxyquinoline (HL) was synthesized in two steps from the readily available and cheap 8-hydroxyquinaldine and characterized by LC-MS, NMR spectroscopy, elemental analysis and X-ray crystallography. Using solvothermal method, a crystalline complex Zn2L4(1) was obtained by reacting Zn(Ⅱ) ions with ligand HL. X-ray structural analysis shows that 1 exhibits a binuclear core, which is bridged by two 8-hydroxyquinoline rings. The supramolecular structure of 1 features a 3D supramolecular structure constructed by π…π aromatic stacking interactions, nonclassical C-H…O hydrogen bonds and C-H…π interactions. The aggregation behavior of zinc salts and HL in solutions was investigated with UV-vis and PL spectra. Additionally, we also studied the photophysical properties of compound 1 by PL. The results showed that complex 1 exhibits a red shift compared with free ligand HL and emits yellow luminescence. CCDC:923979,HL;923980,1.
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