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Citation: ZENG Jing-Hui, SONG Jiang-Feng, YANG Yuan-You, HOU Qin, LUO De-Li, LIAO Jia-Li, YANG Ji-Jun, TANG Jun, LIU Ning, WANG Dong-Qi. Simulation of Hydrogen-Deuterium Exchange Behavior in the Sphere Pd-Filled Column[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(8): 1626-1632. doi: 10.3969/j.issn.1001-4861.2013.00.301 shu

Simulation of Hydrogen-Deuterium Exchange Behavior in the Sphere Pd-Filled Column

  • 1.

    1 Key Laboratory of Radiation Physics and Technology (Sichuan University), Ministry of Education; Institute of Nuclear Science and Technology, Sichuan University, Chengdu 610064, China;

  • Received Date: 21 January 2013
    Available Online: 28 May 2013

    Fund Project: 国际磁约束聚变能计划专项(No.2010GB112001) (No.2010GB112001)特殊学科点 (No.J1210004)资助项目。 (No.J1210004)

  • A hydrogen-deuterium exchange reaction model was constructed by combining the Sphere Particle Exchange Model (SPEM) and the Gas-Solid Surface Exchange Model, and programmed in terms of numerical algorithm using FORTRAN language to simulate the H-D exchange reaction in a column filled with palladium (Pd) particles. This model was then used to study the influence of the properties of Pd material, including its size and density in the column, the length of the column, the velocity of the gas flow and temperature, etc., on the exchange reaction. The calculation show that low flow velocity, high density and small size of Pd particles, longer column and higher temperature may accelerate the exchange reaction of D by H, while the diameter of column has no effect when the diffusion model used here holds.
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