Citation: HOU Xiang-Yang, WANG Xiao, FU Feng, WANG Ji-Jiang, TANG Long. Syntheses, Characterizations, Magnetic Susceptibility, and Electrochemical Property of Cobalt Complex Based on 2-Phenyl-4-quinolinecarboxylic Acid and Imidazol-Based Linker[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(10): 2245-2250. doi: 10.3969/j.issn.1001-4861.2013.00.300 shu

Syntheses, Characterizations, Magnetic Susceptibility, and Electrochemical Property of Cobalt Complex Based on 2-Phenyl-4-quinolinecarboxylic Acid and Imidazol-Based Linker

1.
Department of Chemistry and Chemical Engineering, Shaanxi Key Laboratory of Chemical Reaction Engineering, Yan'an University, Yan'an, Shaanxi 716000, China

Received Date: 29 January 2013
Available Online: 30 April 2013
Fund Project: 陕西省教育厅科研计划项目(No.11JK0583) (No.11JK0583)陕西省科学技术研究发展计划(No.2013JM2015)资助项目 (No.2013JM2015)

One new metal-organic framework, namely, [Co(pqba)₂(biyb)](1) (2-phenyl-4-quinolinecarboxylic acid=Hpqba, 1,4-bis(imidazol-1-ylmethyl)benzene=biyb), has been synthesized under hydrothermal conditions. The compound 1 was characterized by elemental analysis, IRspectroscopy, and X-ray single-crystal diffraction. Complex 1 crystallizes in the Monoclinic system, C₂/c space group. In 1, the biyb act as bidentate ligands assembling with Co(Ⅱ) ions to a one-dimensional framework, which is further expanded to form a 2D supramolecular structure by π…π stacking interactions with biyb molecules between 1D chains. Thermogravimetric analyses for 1 is discussed. Furthermore, electrochemical property of the 1 shows that electron transfer of Co(Ⅱ) between Co(Ⅲ) in electrolysis is quasi-reversible process, and magnetic susceptibility measurements indicate that compound 1 has dominating antiferromagnetic couplings between metal ions. CCDC: 919474.
- cobalt complex; crystal structure; magnetic susceptibility; electrochemical property
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沈阳化工大学材料科学与工程学院沈阳 110142