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Citation: YUAN Ye, REN Hao, SUN Fu-Xing. γ-Cyclodextrin Porous Aromatic Frameworks Applied to Capture CO2[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(8): 1645-1648. doi: 10.3969/j.issn.1001-4861.2013.00.297 shu

γ-Cyclodextrin Porous Aromatic Frameworks Applied to Capture CO2

  • 1.

    Jilin University State Key Laboratory of Inorganic Synthesis & Preparative Chemistry, Jilin University, Changchun 130012, China

  • Received Date: 19 January 2013
    Available Online: 17 May 2013

    Fund Project: 吉林大学“挑战杯”大学生课外学术科技作品竞赛项目(No.450060487477)资助项目。 (No.450060487477)

  • According to the famous chemist Yaghi's theory, hydroxyl group possesses the specific adsorption for CO2. In this paper, we report the synthesis of novel γ-cyclodextrin porous aromatic frameworks (CD-PAF-1) based on γ-cyclodextrin as building units with hydroxyl dehydration reaction. The material was characterized by fourier transform infrared spectroscopy (FTIR), thermogravimetric analysis (TGA), powder X-ray diffraction (PXRD), scanning electron microscopy (SEM), CO2 and N2 gas sorption. A TG analysis showed that CD-PAF-1 is thermally stable up to 220 ℃ in air. CD-PAF-1 also has a high chemical stability and cannot be dissolved or decomposed in common solvents or concentrated hydrochloric acid. As we designed, hydroxyl groups in the skeletons adsorb a large amount of CO2. However, they do not adsorb N2 gas molecules. According to these features, CD-PAF-1 may be applied to capture and separate CO2 in industry.
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