Citation: HAO Peng-Fei, YANG Zhi, MA Xiao-Li, LI Jia-Rong. Synthesis, Characterization and Thermal Stability of the Aluminum Boroxine-Linked Compound with N-aryl Substituted β-Diketiminato Ligand[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(9): 1909-1913. doi: 10.3969/j.issn.1001-4861.2013.00.296
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The reaction of LAlH2 (L=(Z)-4-[(2,6-diisopropylphenyl)amino]pent-3-en-2-ylidene-2,6-diisopropylaniline) with 2-trifluoromethylphenylboronic acid resulted in the boroxine-linked organic aluminum compound LAl[OB(2-CF3C6H4)]2(μ-O). Compound is an unique example of a spiro-centered aluminum atom, showing the inorganic AlO3B2 ring fused to the organic C3N2 part. Compound was characterized by 1H NMR, IR, elemental analysis, and single crystal X-ray structural analysis. Furthermore, compound was studied by TG analysis. CCDC: 918118.
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