Citation: LI Shu-Jing, ZHANG Xiao-Peng, LIU Jian, ZHENG Wei, LI Cheng-Hui. Synthesis and Characterization of Chiral 2,5-Bis(4,5-pinene-2-pyridyl) Pyrazine and Its Rhenium(Ⅰ) Complex[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(8): 1745-1752. doi: 10.3969/j.issn.1001-4861.2013.00.295
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The chiral ligand 2,5-bis(4,5-pinene-2-pyridyl) pyrazine (L) and its rhenium(Ⅰ) complex [Re(CO)3Cl(L)]·DMF were synthesized. X-ray crystallographic analysis show that L crystallizes in monoclinic P21 space group while [Re(CO)3Cl(L)]·DMF crystallizes in orthorhombic P212121 space group. The Re(Ⅰ) atom is six-coordinated by two nitrogen atoms (N1, N2) from the chiral ligand, three carbon atoms (C1, C2 and C3) from CO, and one chlorine atom (Cl1). Both ligand and [Re(CO)3Cl(L)]·DMF show optical activity as manifested by the CD and VCD spectra. Upon excitation, the ligand and Re(Ⅰ) complex emit at 420 and 650 nm, respectively. Both the ligand and Re(Ⅰ) complex show second-order non-linear optic (NLO) properties, and the second harmonic generation (SHG) responses are ~0.4 and ~0.3 times that of urea, respectively. CCDC: 921976, complex; 921977, ligand.
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