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Citation: WANG Yin-Ge, LIU Qian-Qian, ZHAI Li-Xin, QIAN Hui-Fen, HUANG Wei. Structural and Spectral Studies of Cis Cadmium(Ⅱ), Manganese(Ⅱ) and Nickel(Ⅱ) Complexes Having 2-Thiophenimidazo[4,5-f][1,10]phenanthroline and 2-(5-Bromothiophen)imidazo[4,5-f][1,10]phenanthroline Ligands[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(8): 1687-1695. doi: 10.3969/j.issn.1001-4861.2013.00.294 shu

Structural and Spectral Studies of Cis Cadmium(Ⅱ), Manganese(Ⅱ) and Nickel(Ⅱ) Complexes Having 2-Thiophenimidazo[4,5-f][1,10]phenanthroline and 2-(5-Bromothiophen)imidazo[4,5-f][1,10]phenanthroline Ligands

  • 1.

    1College of Sciences, Nanjing University of Technology, Nanjing 210009, China;

  • Received Date: 16 February 2013
    Available Online: 28 May 2013

    Fund Project: 国家自然科学基金(No.21171088) (No.21171088)

  • Three mononuclear cadmium(Ⅱ), manganese(Ⅱ) and nickel(Ⅱ) complexes having 2-thiophenimidazo[4,5-f][1,10]phenanthroline (TIP) and 2-(5-bromothiophen)imidazo[4,5-f][1,10]phenanthroline (5-Br-TIP) ligands formulated as [cis-Cd(NO3)(TIP)2] (1), [cis-MnCl2(5-Br-TIP)2] (2) and [cis-NiCl2(TIP)2] (3), have been synthesized and structurally compared. They are characterized by elemental analysis, FT-IR, UV-Vis spectra, luminescence spectra and X-ray single-crystal structural analysis. All of them are 1:2 mononuclear complexes with the same cis configuration, among which complex 1 is eight-coordinated and the others are six-coordinated. Ligands TIP and 5-Br-TIP in complex 1~3 are essentially planar with the dihedral angles between imidazole and thiophene rings in the range of 3.9(1)°~9.2(1)°. CCDC: 922633, 1; 922634, 2; 922635, 3.
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    1. [1]

      [1] Prat O, Lopez E, Mathis G. Anal. Biochem., 1991,195:283-289

    2. [2]

      [2] Hsiao W L W, Mo Z Y, Fang M, et al. Mutat Res-Genet Toxicol E. M., 2000,471:45-55

    3. [3]

      [3] Hong Y N, Lam J W Y, Tang B Z. Chem. Commun., 2009, 29:4332-4553

    4. [4]

      [4] Beauvais L G, Shores M P, Long J R. J. Am. Chem. Soc., 2000,122:2763-2772

    5. [5]

      [5] Turnbull G A, Andrew P, Barnes W L. Appl. Phys. Lett., 2003,82:313-315

    6. [6]

      [6] Chou H H, Hsu C Y, Lin Y S, et al. Tetrahedron, 2012,68: 767-773

    7. [7]

      [7] Gratzel M. Inorg. Chem., 2005,44:6841-6851

    8. [8]

      [8] Chang Y J, Chow T J. J. Mater. Chem., 2011,21:9523-9532

    9. [9]

      [9] Mushrush M, Facchetti A, Lefenfeld M. J. Am. Chem. Soc., 2003,125:9414-9423

    10. [10]

      [10] Ponomarenko S A, Kirchmeyer S, Elschner A. Adv. Funct. Mater., 2003,13:591-596

    11. [11]

      [11] Chen C Y, Lu H C, Wu C G, et al. Adv. Funct. Mater., 2007,17:29-36

    12. [12]

      [12] Huang W, Tanaka H, Ogawa T, et al. Adv. Mater., 2010,22: 2753-2758

    13. [13]

      [13] Ammann M, Rang A, Schalley A, et al. Eur. J. Org. Chem., 2006:1940-1948

    14. [14]

      [14] Wu C G, Lu H C, Chen L N, et al. J. Polym. Sci., Part A: Polym. Chem., 2008,46:1586-1597

    15. [15]

      [15] Araki K, Endo H, Masuda G, et al. Chem. Eur. J., 2004,10: 3331-3340

    16. [16]

      [16] Vos J G, Kelly J M. Dalton Trans., 2006:4869-4883

    17. [17]

      [17] Batista R M F, Costa S P G, Belsley M, et al. Dye Pigment., 2009,80:329-336

    18. [18]

      [18] Goze C, Sabatini C, Barbieri A, et al. Eur. J. Inorg. Chem., 2008:1293-1299

    19. [19]

      [19] Tzalis D, Tor Y. Tetrahedron Lett., 1995,36:6017-6020

    20. [20]

      [20] Schafer B, Gorls H, Meyer S, et al. Eur. J. Inorg. Chem., 2007:4056-4063

    21. [21]

      [21] Rau S, Fischer R, Jager M, et al. Eur. J. Inorg. Chem., 2004:2001-2003

    22. [22]

      [22] Frey J, Kraus T, Heitz V, et al. Chem. Commun., 2005:5310-5312

    23. [23]

      [23] Tzalis D, Tor Y. Angew. Chem. Int. Ed., 1997,36:2666-2668

    24. [24]

      [24] (a)Hu B, Fu S J, Xu F, et al. J. Org. Chem., 2011,76:4444-4456 (b)Huang W, Masuda G, Maeda S, et al. Chem. Eur. J., 2006,12:607-619 (c)Huang W, Tanaka H, Ogawa T. J. Phys. Chem. C, 2008, 112:11513-11526 (d)Huang W, Masuda G, Maeda S, et al. Inorg. Chem., 2008,47:468-480 (e)Wang L, You W, Huang W, et al. Inorg. Chem., 2009,48: 4295-4305 (f)Huang W, Wang L, Tanaka H, et al. Eur. J. Inorg. Chem., 2009:1321-1320 (g)Zhang B, Cao K S, Xu Z A, et al. Eur. J. Inorg. Chem., 2012:3844-3851 (h)Xu F, Peng Y X, Hu B, et al. CrystEngComm, 2012,14: 8023-8032 (i)HU Bin(胡斌), YAN Liu-Shui(颜流水), ZHANG Ai-Qin (张爱琴). Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2012,28:2540-2547 (j)Liu Q Q, Geng J, Wang X X, et al. Polyhedron, 2013,59: 52-57 (k)Hu B, Liu Q Q, Tao, T, Zhang K, et al. Inorg. Chim. Acta, 2013,394:576-582 (l)Tao T, Peng Y X, Huang W, et al. J. Org. Chem., 2013, 78:2472-2481

    25. [25]

      [25] Wang X L, Chen Y Q, Zhang J X, et al. Z. Anorg. Allg. Chem., 2010,636:830-834

    26. [26]

      [26] (a)Zheng C G, Ma C L, Yu X W, et al. Chem. Biodiversity, 2011,8:1486-1496 (b)Karnahl M, Krieck S, Gorls H, et al. Eur. J. Inorg. Chem., 2009:4962-4971 (c)Batista R M F, Costa S P G, Belsley M, et al. Tetrahedron, 2008,64:9230-9238

    27. [27]

      [27] Siemens. SAINT v4 Software Reference Manual. Madison, Wisconsin, USA: Siemens Analytical X-Ray Systems, Inc.; 2000.

    28. [28]

      [28] Sheldrick G M. SADABS, Program for Empirical Absorption Correction of Area Dectector Data. Germany: Univ. of Gottingen, 2000.

    29. [29]

      [29] Siemens. SHELXTL, Version 6.10 Reference Manual. Madison, Wisconsin, USA: Siemens Analytical X-Ray Systems, Inc.; 2000.

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