Citation: LIU Guang-Xiang. Synthesis, Crystal Structure and Magnetic Property of a Copper(Ⅱ) Coordination Polymer Constructed from Nicotinic Acid[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(9): 1914-1920. doi: 10.3969/j.issn.1001-4861.2013.00.290
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A new three-dimensional (3D) coordination polymer of[Cu2(nic)4(H2O)]n (1) (Hnic=nicotinic acid) has been prepared and characterized by elemental analysis, IR spectroscopy, and single-crystal X-ray diffraction. The crystal is of monoclinic, space group P21/c with a=1.071 56(3) nm, b=1.958 79(6) nm, c=1.379 50(3) nm, β=104.498 (2)°, V=2.803 31(13) nm3, Dc=1.501 g·cm-3, Z=4, F(000)=1 280, Goof=1.014, R1=0.041 7, wR2=0.113 2. Complex 1 shows a 3D uninodal 5-connected framework with (44·66) topology. Moreover, Magnetic susceptibility measurements demonstrate that complex 1 exhibits antiferromagnetic interaction within the binuclear units. CCDC: 921590.
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