Citation: ZHOU Xian-Ju, ZHOU Kai-Ning, WANG Zhi-Liang, XIAO Teng-Jiao, ZHAO Xiao-Qi, LI Qing-Xu. Synthesis, Structure and Fluorescent Properties of Europium Complexes with Cinnamic Acid and Its Derivates[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(9): 1870-1876. doi: 10.3969/j.issn.1001-4861.2013.00.288 shu

Synthesis, Structure and Fluorescent Properties of Europium Complexes with Cinnamic Acid and Its Derivates

1.
1 Department of Mathematics and Physics, Chongqing University of Posts and Telecommunications, Chongqing 400065, China;

Received Date: 25 September 2012
Available Online: 13 May 2013
Fund Project: 国家自然科学基金(No.20903123) (No.20903123)教育部重点项目(No.211154) (No.211154)重庆市自然科学基金(No.KJ110532,CSTC2011jjA1425) (No.KJ110532,CSTC2011jjA1425)

Europium complexes with cinnamic acid (HL) and its para-substitued derivates R-L (R=CH₃, Cl, NO₂, OCH₃, OH) have been synthesized, and their crystal structures have been determined. The results of single-crystal X-Ray diffraction have shown that {[Eu₂(CH₃-L)₆(DMF)(H₂O)]·2DMF·H₂O}_n (1) and {[Eu₂(Cl-L)6(DMF)(H₂O)]·2DMF·H₂O}_n (2) are 1D chain coordination polymers while {[Eu₂(NO₂-L)₆(DMF)(H₂O)]·2DMF·H₂O}₂ (3) is binuclear structured. The complexes have been characterized by FT-IR, UV-Vis and photoluminescence (PL) spectroscopy. The influence of substituted groups' electron-withdrawing effect has been discussed. The effect of coordinated solvent molecular on complexes' luminescent properties has been investigated. CCDC:856461, 1; 856460, 2; 856462, 3.
- Eu³⁺ complexes;cinnamic acid;crystal structure;luminescent properties
1. [1]
  [1] Lammle K, Trevethan T, Schwarz A, et al. Nano Lett., 2010, 10:2965-2971
2. [2]
  [2] Hang T, Zhang W, Ye H Y, et al. Chem. Soc. Rev., 2011, 40:3577-3598
3. [3]
  [3] Llqwellyn P L, Horcajada P, Maurin G, et al. J. Am. Chem. Soc., 2009,131:13002-13008
4. [4]
  [4] Binnemans K. Chem. Rev., 2009,109:4283-4374
5. [5]
  [5] Bünzli J C G, Piguet C. Chem. Soc. Rev., 2005,34:1048-1077
6. [6]
  [6] Strasser C A, Chien C H, Lopez M D G, et al. Angew. Chem. Int. Ed., 2011,50:946-950
7. [7]
  [7] Tang H, Tang H, Zhang Z, et al. Synth. Metals, 2009,159: 72-77
8. [8]
  [8] Li C Y, Zhang X B, Qiao L, et al. Anal. Chem., 2009,81: 9993-10001
9. [9]
  [9] Vigato P A, Peruzzo V, Tanburini S. Coord. Chem. Rev., 2009,253:1099-1201
10. [10]
  [10] Singh J, Dutta P K. J. Macro. Sci. A, 2011,48:246-253
11. [11]
  [11] Gao W Y, Niu Y, Chen Y, et al. Cryst. Eng. Comm., 2012, 14:6115-6117
12. [12]
  [12] Alliger G E, Müller P, Do L H, et al. Inorg. Chem., 2011, 50:4107-4115
13. [13]
  [13] Riley K E, Hobza P. Cryst. Growth Des., 2011,11:4272-4278
14. [14]
  [14] Lam A W H, Wong W T, Gao S, et al. Eur. J. Inorg. Chem., 2003:149-163
15. [15]
  [15] Yan B, Zhang H J, Wang S B, et al. J. Chin. Chem. Soc., 1997,44:567-573
16. [16]
  [16] Arnaud N, Georges J. Analyst, 2000,125:1487-1490
17. [17]
  [17] Oyang L, Sun H L, Wang X Y, et al. J. Mole. Struc., 2005, 740:175-180
18. [18]
  [18] Roh S G, Oh J B, Nah M K, et al. Bull. Korean Chem. Soc., 2004,25:1503-1507
19. [19]
  [19] YANG Yan-Hong(杨艳红), LI Ye(李野), NIU Shu-Yun(牛淑云), et al. Chin. J. Appl. Chem.(Yingyong Huaxue), 2010, 27:1055-1059
20. [20]
  [20] MAO Jia-Yuan(茅嘉原), FANG Hong-Xin(方红新), XU Qing-Feng(徐庆峰), et al. Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2008,24:1046-1050
21. [21]
  [21] Lu Y, Miller J D. J. Colloid Interface Sci., 2002,256:41-52
22. [22]
  [22] Kariakin A, Davydov D, Peterson J A, et al. Biochem., 2002,41:13514-13525
23. [23]
  [23] Cui Z, Ren H, Liu G, et al. J. Rare Earths, 2006,24:724-727
24. [24]
  [24] Seward C, Hu N X, Wang S. J. Chem. Soc., Dalton Trans., 2001:134-137
25. [25]
  [25] Manson J L, Arif A M, IncarvitoC C D, et al. J. Solid State Chem., 1999,145:369-378
26. [26]
  [26] Pretsch E, Bühlmann P, Affplter C. Translated by RONG Guo-Bin(荣国斌). Structure Determination of Organic Compounds Tables of Spectral Data(波谱数据表有机化合物的结构解析). Shanghai: Shanghai University of Polytechn-ology Press, 2002:397
27. [27]
  [27] Yang W, Hou Q, Liu C, et al. J. Mater. Chem., 2003,13: 1351-1355
28. [28]
  [28] Li Y, Zou Y. Adv. Mater., 2008,20:2952-2958
29. [29]
  [29] ZHOU Xian-Ju(周贤菊), CHEN Jia(陈加), YANG Xiao-Dong(杨小东). Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2012,28:932-936
30. [30]
  [30] Erostyák J, Buzády A, Hornyák I, et al. J. Photochem. Photobio. A, 1998,115:21-26
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沈阳化工大学材料科学与工程学院沈阳 110142