Citation: ZHOU Xian-Ju, ZHOU Kai-Ning, WANG Zhi-Liang, XIAO Teng-Jiao, ZHAO Xiao-Qi, LI Qing-Xu. Synthesis, Structure and Fluorescent Properties of Europium Complexes with Cinnamic Acid and Its Derivates[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(9): 1870-1876. doi: 10.3969/j.issn.1001-4861.2013.00.288
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Europium complexes with cinnamic acid (HL) and its para-substitued derivates R-L (R=CH3, Cl, NO2, OCH3, OH) have been synthesized, and their crystal structures have been determined. The results of single-crystal X-Ray diffraction have shown that {[Eu2(CH3-L)6(DMF)(H2O)]·2DMF·H2O}n (1) and {[Eu2(Cl-L)6(DMF)(H2O)]·2DMF·H2O}n (2) are 1D chain coordination polymers while {[Eu2(NO2-L)6(DMF)(H2O)]·2DMF·H2O}2 (3) is binuclear structured. The complexes have been characterized by FT-IR, UV-Vis and photoluminescence (PL) spectroscopy. The influence of substituted groups' electron-withdrawing effect has been discussed. The effect of coordinated solvent molecular on complexes' luminescent properties has been investigated. CCDC:856461, 1; 856460, 2; 856462, 3.
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[1]
[1] Lammle K, Trevethan T, Schwarz A, et al. Nano Lett., 2010, 10:2965-2971
-
[2]
[2] Hang T, Zhang W, Ye H Y, et al. Chem. Soc. Rev., 2011, 40:3577-3598
-
[3]
[3] Llqwellyn P L, Horcajada P, Maurin G, et al. J. Am. Chem. Soc., 2009,131:13002-13008
-
[4]
[4] Binnemans K. Chem. Rev., 2009,109:4283-4374
-
[5]
[5] Bünzli J C G, Piguet C. Chem. Soc. Rev., 2005,34:1048-1077
-
[6]
[6] Strasser C A, Chien C H, Lopez M D G, et al. Angew. Chem. Int. Ed., 2011,50:946-950
-
[7]
[7] Tang H, Tang H, Zhang Z, et al. Synth. Metals, 2009,159: 72-77
-
[8]
[8] Li C Y, Zhang X B, Qiao L, et al. Anal. Chem., 2009,81: 9993-10001
-
[9]
[9] Vigato P A, Peruzzo V, Tanburini S. Coord. Chem. Rev., 2009,253:1099-1201
-
[10]
[10] Singh J, Dutta P K. J. Macro. Sci. A, 2011,48:246-253
-
[11]
[11] Gao W Y, Niu Y, Chen Y, et al. Cryst. Eng. Comm., 2012, 14:6115-6117
-
[12]
[12] Alliger G E, Müller P, Do L H, et al. Inorg. Chem., 2011, 50:4107-4115
-
[13]
[13] Riley K E, Hobza P. Cryst. Growth Des., 2011,11:4272-4278
-
[14]
[14] Lam A W H, Wong W T, Gao S, et al. Eur. J. Inorg. Chem., 2003:149-163
-
[15]
[15] Yan B, Zhang H J, Wang S B, et al. J. Chin. Chem. Soc., 1997,44:567-573
-
[16]
[16] Arnaud N, Georges J. Analyst, 2000,125:1487-1490
-
[17]
[17] Oyang L, Sun H L, Wang X Y, et al. J. Mole. Struc., 2005, 740:175-180
-
[18]
[18] Roh S G, Oh J B, Nah M K, et al. Bull. Korean Chem. Soc., 2004,25:1503-1507
-
[19]
[19] YANG Yan-Hong(杨艳红), LI Ye(李野), NIU Shu-Yun(牛淑 云), et al. Chin. J. Appl. Chem.(Yingyong Huaxue), 2010, 27:1055-1059
-
[20]
[20] MAO Jia-Yuan(茅嘉原), FANG Hong-Xin(方红新), XU Qing-Feng(徐庆峰), et al. Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2008,24:1046-1050
-
[21]
[21] Lu Y, Miller J D. J. Colloid Interface Sci., 2002,256:41-52
-
[22]
[22] Kariakin A, Davydov D, Peterson J A, et al. Biochem., 2002,41:13514-13525
-
[23]
[23] Cui Z, Ren H, Liu G, et al. J. Rare Earths, 2006,24:724-727
-
[24]
[24] Seward C, Hu N X, Wang S. J. Chem. Soc., Dalton Trans., 2001:134-137
-
[25]
[25] Manson J L, Arif A M, IncarvitoC C D, et al. J. Solid State Chem., 1999,145:369-378
-
[26]
[26] Pretsch E, Bühlmann P, Affplter C. Translated by RONG Guo-Bin(荣国斌). Structure Determination of Organic Compounds Tables of Spectral Data(波谱数据表有机化合物 的结构解析). Shanghai: Shanghai University of Polytechn-ology Press, 2002:397
-
[27]
[27] Yang W, Hou Q, Liu C, et al. J. Mater. Chem., 2003,13: 1351-1355
-
[28]
[28] Li Y, Zou Y. Adv. Mater., 2008,20:2952-2958
-
[29]
[29] ZHOU Xian-Ju(周贤菊), CHEN Jia(陈加), YANG Xiao-Dong(杨小东). Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2012,28:932-936
-
[30]
[30] Erostyák J, Buzády A, Hornyák I, et al. J. Photochem. Photobio. A, 1998,115:21-26
-
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