Citation: JIA Hong-Liang, HOU Li-Fen, ZHANG Yu, YUAN Peng-Fei, LI Gang. Synthesis, Structure and Properties of a 2-(p-Bromophenyl)-Imidazole Dicarboxylate-Based Ni(Ⅱ) Coordination Polymer[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(9): 1897-1902. doi: 10.3969/j.issn.1001-4861.2013.00.285
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By the reaction of 2-(p-bromophenyl)-1H-imidazole-4,5-dicarboxylic acid (p-BrPhH3IDC) with Ni(Ⅱ) ion, one coordination polymer, namely,[Ni(p-BrPhH2IDC)2]·2H2O}n (1) has been synthesized under solvothermal condition. Its molecular structure has been characterized by single-crystal X-ray diffraction, elemental analysis and IR spectrum. The results reveal that it is a two-dimensional polymer, and the ligand p-BrPhH3IDC shows strong coordination ability. Furthermore, the existence of intermolecular hydrogen bonds and π…π stacking interactions between the aromatic groups supplies the additional stabilization for the solid-state supramolecular structure of polymer 1. The thermal properties of 1 and its magnetic behaviors have been studied in the temperature range of 2.0~300 K. Magnetic measurement shows that the antiferromagnetic coupling between the Ni(Ⅱ) ions in complex 1 can be observed. CCDC: 913845.
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