Citation: HUANG De-Qian, ZHANG Hong, SHENG Liang-Quan, LIU Zhao-Di, XU Hua-Jie, FAN Su-Hua. A Neodymium(Ⅲ) Coordination Polymer Based on Oxalate and Carbonate Ligands： Synthesis, Structure and Luminescence[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(11): 2497-2502. doi: 10.3969/j.issn.1001-4861.2013.00.283 shu

A Neodymium(Ⅲ) Coordination Polymer Based on Oxalate and Carbonate Ligands： Synthesis, Structure and Luminescence

1.
School of Chemistry and Chemical Engineering, Fuyang Teachers College, Fuyang, Anhui 236037, China

Received Date: 7 January 2013
Available Online: 25 April 2013
Fund Project: 国家自然科学基金(No.21201037) (No.21201037)安徽高校省级自然科学研究项目(No.KJ2012Z310,KJ2011A210)资助项目 (No.KJ2012Z310,KJ2011A210)

Aneodymium(Ⅲ) coordination polymer, namely, {[Nd2(ox)(cb)₂(H₂O)₂]·3H₂O}_n (1) (ox=oxalate, cb=carbonate) (1), has been hydrothermally synthesized and characterized by elemental analysis, IR, TGA, powder X-ray diffraction, and single-crystal X-ray diffraction. Structural determination reveals that the neodymium ions are bridged by μ₂-ox and μ₄-cb ligands to give a 3D framework including 2D channels of 0.53 nm×0.41 nm along the b axis and 0.59 nm×0.84 nm along the c axis, respectively. It can also be described as a (4,5)-connected {4⁴.6²}{4⁴.6⁶} topological 3D framework. Solid-state 1 emits the intensely NIR characteristic luminescence of Nd³⁺ ion at room temperature. CCDC: 917863.
- neodymium(Ⅲ) coordination polymer;crystal structure;oxalate;carbonate;luminescent
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沈阳化工大学材料科学与工程学院沈阳 110142