Citation: LI Shu-Cun, ZHAO Min-Shou, JIAO Ti-Feng. Effect of Addition of Boron on Structure and Electrochemical Characteristic of Ti0.26Zr0.07V0.24Mn0.1Ni0.33 Alloy[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(10): 2119-2125. doi: 10.3969/j.issn.1001-4861.2013.00.279
-
The results show that all alloys are composed of V-based solid solution with body-centered-cube (BCC) structure and C14 Laves phase with hexagonal structure. The addition of Bincreases the discharge capacity of Ti0.26Zr0.07V0.24Mn0.1Ni0.33 alloy electrode and Ti0.26Zr0.07V0.24Mn0.1Ni0.33B0.1 alloy delivers the discharge capacity of 476.7 mAh·g-1at discharge current of 60 mA·g-1. The addition of Bdecreases the high-rate discharge ability of the alloy electrode in some extent. EISindicates that addition of Bdecreases the dynamic performance, which makes the charge transfer resistance (Rct) increases and the exchange current density (I0) decreases markedly. Considerable improvement in the high-temperature dischargeability is observed by addition of B, and the discharge capacity is up to 525.6 mAh·g-1 at 343 Kfor Ti0.26Zr0.07V0.24Mn0.1Ni0.33B0.025 alloy electrode.
-
-
[1]
[1] Fenga F, Genga M, Northwoodb D O. Int. J. Hydrogen Energy, 2001,26:725-734 [2] QIAO Yu-Qing(乔玉卿), ZHAO Min-Shou(赵敏寿), LI Mei- Ye(李梅晔). Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2006,22(3):415-420 [3] Liu Y F, Pan H G, Gao M X, Wang Q D. J. Mater. Chem., 2011,21:4743-4755 [4] DENG Xiao-Xia(邓小霞), CHENG Hong-Hui(程宏辉), LI Shen-Lan(李慎兰), et al. Acta Metal Sin.(Jinshu Xuebao), 2007,43(9):977-982 [5] LUO Yong-Chun(罗永春), ZHANG Tie-Jun(张铁军), WANG Duo(王铎), et al. Acta Phys.-Chim. Sin.(Wuli Huaxue Xuebao), 2010,26(9):2397-2404 [6] Chen W. X. J. Alloys Compd., 2001,319:119-123 [7] JIA Yan-Min(贾彦敏), LIU Fei-Ye(刘飞烨), XIAO Xue- Zhang(肖学章), et al. Acta Phys.-Chim. Sin.(Wuli Huaxue Xuebao), 2009,25(2):247-252 [8] Gao X P, Sun Y M, Higuchi E, et al. Electrochim. Acta, 2000,45:3099-3104 [9] Cho S W, Enoki H, Akiiba E. J. Alloys Compd., 2000,307: 304-310 [10]Xu J L, Niu D, Fan Y J. J Power Sources, 2012,198:383- 388 [11]Qiao Y Q, Zhao M S, Zhu X J, et al. Int. J. Hydrogen Energy, 2007,32:3427-3434 [12]Shu K Y, Yang X G, Zhang S K, et al. J. Alloys Compd., 2000,306:122-126 [13]Tsukahara M, Kamiya T, Takahashi K, et al. J Electrochem. Soc., 2000,147:2941-2947 [14]Qiao Y, Zhao M, Zhu X, et al. J. Rare Earths, 2007,25:341- 347 [15]Tadokoro M, Nogami M, Chikano Y, et al. J. Alloys Compd., 1993,192:179-181 [16]Hu W K, Ye Z, Noreus D. J. Alloys Compd., 1998,280:314- 320 [17]Bordeanx C, Bernard F, Cerand N. Int. J. Hydro. Energy, 1997,22(5):475-479 [18]Audry C, Bernard P, Champion Y, et al. J. Alloys Compd., 2002,330/332:871-874 [19]Wang C S, Wang X H, Lei Y Q. Int. J. Hydrogen Energy, 1997,22(12):1117-1124 [20]Kuriyama N, Sakai T, Miyamura H, et al. J. Alloys Compd., 1993,202(1/2):183-197 [21]Park J Y, Park C N, Park C J, et al. Int. J. Hydrogen Energy, 2007,32(17):4215-4219
-
[1]
-
-
[1]
Xinpeng LIU , Liuyang ZHAO , Hongyi LI , Yatu CHEN , Aimin WU , Aikui LI , Hao HUANG . Ga2O3 coated modification and electrochemical performance of Li1.2Mn0.54Ni0.13Co0.13O2 cathode material. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1105-1113. doi: 10.11862/CJIC.20230488
-
[2]
Jiahong ZHENG , Jiajun SHEN , Xin BAI . Preparation and electrochemical properties of nickel foam loaded NiMoO4/NiMoS4 composites. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 581-590. doi: 10.11862/CJIC.20230253
-
[3]
Qi Li , Pingan Li , Zetong Liu , Jiahui Zhang , Hao Zhang , Weilai Yu , Xianluo Hu . Fabricating Micro/Nanostructured Separators and Electrode Materials by Coaxial Electrospinning for Lithium-Ion Batteries: From Fundamentals to Applications. Acta Physico-Chimica Sinica, 2024, 40(10): 2311030-. doi: 10.3866/PKU.WHXB202311030
-
[4]
Zhihuan XU , Qing KANG , Yuzhen LONG , Qian YUAN , Cidong LIU , Xin LI , Genghuai TANG , Yuqing LIAO . Effect of graphene oxide concentration on the electrochemical properties of reduced graphene oxide/ZnS. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1329-1336. doi: 10.11862/CJIC.20230447
-
[5]
Qin ZHU , Jiao MA , Zhihui QIAN , Yuxu LUO , Yujiao GUO , Mingwu XIANG , Xiaofang LIU , Ping NING , Junming GUO . Morphological evolution and electrochemical properties of cathode material LiAl0.08Mn1.92O4 single crystal particles. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1549-1562. doi: 10.11862/CJIC.20240022
-
[6]
Qingtang ZHANG , Xiaoyu WU , Zheng WANG , Xiaomei WANG . Performance of nano Li2FeSiO4/C cathode material co-doped by potassium and chlorine ions. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1689-1696. doi: 10.11862/CJIC.20240115
-
[7]
Yuanchao LI , Weifeng HUANG , Pengchao LIANG , Zifang ZHAO , Baoyan XING , Dongliang YAN , Li YANG , Songlin WANG . Effect of heterogeneous dual carbon sources on electrochemical properties of LiMn0.8Fe0.2PO4/C composites. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 751-760. doi: 10.11862/CJIC.20230252
-
[8]
Hongyi LI , Aimin WU , Liuyang ZHAO , Xinpeng LIU , Fengqin CHEN , Aikui LI , Hao HUANG . Effect of Y(PO3)3 double-coating modification on the electrochemical properties of Li[Ni0.8Co0.15Al0.05]O2. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1320-1328. doi: 10.11862/CJIC.20230480
-
[9]
Wenxiu Yang , Jinfeng Zhang , Quanlong Xu , Yun Yang , Lijie Zhang . Bimetallic AuCu Alloy Decorated Covalent Organic Frameworks for Efficient Photocatalytic Hydrogen Production. Acta Physico-Chimica Sinica, 2024, 40(10): 2312014-. doi: 10.3866/PKU.WHXB202312014
-
[10]
Tiantian MA , Sumei LI , Chengyu ZHANG , Lu XU , Yiyan BAI , Yunlong FU , Wenjuan JI , Haiying YANG . Methyl-functionalized Cd-based metal-organic framework for highly sensitive electrochemical sensing of dopamine. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 725-735. doi: 10.11862/CJIC.20230351
-
[11]
Lu XU , Chengyu ZHANG , Wenjuan JI , Haiying YANG , Yunlong FU . Zinc metal-organic framework with high-density free carboxyl oxygen functionalized pore walls for targeted electrochemical sensing of paracetamol. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 907-918. doi: 10.11862/CJIC.20230431
-
[12]
Jing SU , Bingrong LI , Yiyan BAI , Wenjuan JI , Haiying YANG , Zhefeng Fan . Highly sensitive electrochemical dopamine sensor based on a highly stable In-based metal-organic framework with amino-enriched pores. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1337-1346. doi: 10.11862/CJIC.20230414
-
[13]
Kai CHEN , Fengshun WU , Shun XIAO , Jinbao ZHANG , Lihua ZHU . PtRu/nitrogen-doped carbon for electrocatalytic methanol oxidation and hydrogen evolution by water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1357-1367. doi: 10.11862/CJIC.20230350
-
[14]
Wenjiang LI , Pingli GUAN , Rui YU , Yuansheng CHENG , Xianwen WEI . C60-MoP-C nanoflowers van der Waals heterojunctions and its electrocatalytic hydrogen evolution performance. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 771-781. doi: 10.11862/CJIC.20230289
-
[15]
Juan WANG , Zhongqiu WANG , Qin SHANG , Guohong WANG , Jinmao LI . NiS and Pt as dual co-catalysts for the enhanced photocatalytic H2 production activity of BaTiO3 nanofibers. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1719-1730. doi: 10.11862/CJIC.20240102
-
[16]
Bo YANG , Gongxuan LÜ , Jiantai MA . Nickel phosphide modified phosphorus doped gallium oxide for visible light photocatalytic water splitting to hydrogen. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 736-750. doi: 10.11862/CJIC.20230346
-
[17]
Zhengyu Zhou , Huiqin Yao , Youlin Wu , Teng Li , Noritatsu Tsubaki , Zhiliang Jin . Synergistic Effect of Cu-Graphdiyne/Transition Bimetallic Tungstate Formed S-Scheme Heterojunction for Enhanced Photocatalytic Hydrogen Evolution. Acta Physico-Chimica Sinica, 2024, 40(10): 2312010-. doi: 10.3866/PKU.WHXB202312010
-
[18]
Qiangqiang SUN , Pengcheng ZHAO , Ruoyu WU , Baoyue CAO . Multistage microporous bifunctional catalyst constructed by P-doped nickel-based sulfide ultra-thin nanosheets for energy-efficient hydrogen production from water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1151-1161. doi: 10.11862/CJIC.20230454
-
[19]
Zhiwen HU , Weixia DONG , Qifu BAO , Ping LI . Low-temperature synthesis of tetragonal BaTiO3 for piezocatalysis. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 857-866. doi: 10.11862/CJIC.20230462
-
[20]
Guimin ZHANG , Wenjuan MA , Wenqiang DING , Zhengyi FU . Synthesis and catalytic properties of hollow AgPd bimetallic nanospheres. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 963-971. doi: 10.11862/CJIC.20230293
-
[1]
Metrics
- PDF Downloads(0)
- Abstract views(200)
- HTML views(3)