Citation: LU Yan, SONG Ying, SUN Qiu, WANG Fu-Ping. Thermoelectric Properties of Conducting Polyaniline Co-Doped with Hydrochloric Acid and Sulfosalicylic Acid[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(9): 1887-1892. doi: 10.3969/j.issn.1001-4861.2013.00.276
-
Polyaniline (PANi) co-doped with hydrochloric acid (HCl) and sulfosalicylic acid (SSA) were synthesized by chemical oxidization polymerization with aniline as monomer and ammonium persulfate as oxidant. The structures of the polyaniline were characterized by XRD, SEM and FTIR. Effects of the molar concentration ratio (cSSA:cHCl) on the thermoelectric properties of the polyaniline co-doped with HCl and SSA in different proportions were investigated under the same condition. It was found that the electrical conductivity of the polyaniline increased as increasing of cSSA:cHCl, while the changes in Seebeck coefficient showed an opposite trend. The power factor of cSSA:cHCl=0.25:1 sample reaches 0.46 μW·m-1·K-2 at 175℃, which is 1.7 and 1.9 times than that of SSA doped and HCl doped polyaniline, respectively. This indicates that the co-doping with an appropriate ratio of organic acid and inorganic acid is more effective to improve the thermoelectric properties of polyaniline than single acid.
-
-
[1]
[1] Du Y, Shen S Z, Cai K F, et al. Prog. Polym. Sci., 2012,37: 820-841
-
[2]
[2] Dubey N, Leclerc M. J. Polym. Sci. Pol. Phys., 2011,49:467-475
-
[3]
[3] LIU Jun(刘军), ZHANG Lian-Meng(张联盟), HE Li(何莉), et al. J. Wuhan Univ. Technol.(Wuhan Ligongdaxue Xuebao), 2003,18:53-55
-
[4]
[4] Yoon C O, Kim J H, Sung H K, et al. Synth. Metal, 1996,81: 75-80
-
[5]
[5] Yan H, Ohta T, Toshima N. Macromol. Mater. Eng., 2001, 286:139-142
-
[6]
[6] Yan H, Toshima N. Chem. Lett., 1999,28:1217-1218
-
[7]
[7] Toshima N. Macromol. Symp., 2002,186:81-86
-
[8]
[8] Sun Y N, Wei Z M, Xu W, et al. Synth. Metal, 2010,160: 2371-2376
-
[9]
[9] Yao Q, Chen L, Xu X, et al. Chem. Lett., 2005,34:522-523
-
[10]
[10] Yan H, Sada N, Toshima N. J. Therm. Anal. Calorim., 2002, 69:881-887
-
[11]
[11] Yoon C, Reghu M, Moses D, et al. Synth. Metal, 1995,69: 273-274
-
[12]
[12] Yakuphanoglu F, Senkal B F, Sarac A. J. Electron. Mater., 2008,37:930-934
-
[13]
[13] Li J, Tang X, Li H, et al. Synth. Metal, 2010,160:1153-1158
-
[14]
[14] Joo J, Long S M, Pouget J P, et al. Phys. Rev. B, 1998,57: 9567-9580
-
[15]
[15] WANG Feng-Chun(王凤春), LÜ Ying(吕莹), XU Min(徐敏) et al. Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2009, 25(3):465-468
-
[16]
[16] Kang E T, Neoh K G, Tan K L. Prog. Polym. Sci., 1998,23: 277-324
-
[17]
[17] ZHU Dao-Ben(朱道本), WAMG Fo-Song(王佛松). Organic Solids(有机固体). Shanghai: Shanghai Science and Technology Press, 1999.
-
[18]
[18] HUANG Hui(黄惠), XU Jin-Quan(许金泉), LIU Xiao-Li (刘小丽) et al. Chemistry (Huaxue Tongbao). 2009,8:744-748
-
[19]
[19] HUANG Hui(黄惠), GUO Zhong-Cheng(郭忠诚). Preparation and Application of Conductive Polyaniline(导电 聚苯胺的制备及应用). Beijing: Science Press, 2010.
-
[20]
[20] Jin J Z, Wang Q, Haque M A. Org. Electrn., 2010,11:29-35
-
[21]
[21] LI Jun-Jie(李珺杰), TANG Xin-Feng(唐新峰). J. Mater. Sci. & Eng. (Cailiao Kexue Yu Gongcheng Xuebao), 2010,28: 263-266
-
[1]
-
-
[1]
Jiahong ZHENG , Jiajun SHEN , Xin BAI . Preparation and electrochemical properties of nickel foam loaded NiMoO4/NiMoS4 composites. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 581-590. doi: 10.11862/CJIC.20230253
-
[2]
Limei CHEN , Mengfei ZHAO , Lin CHEN , Ding LI , Wei LI , Weiye HAN , Hongbin WANG . Preparation and performance of paraffin/alkali modified diatomite/expanded graphite composite phase change thermal storage material. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 533-543. doi: 10.11862/CJIC.20230312
-
[3]
Chuanming GUO , Kaiyang ZHANG , Yun WU , Rui YAO , Qiang ZHAO , Jinping LI , Guang LIU . Performance of MnO2-0.39IrOx composite oxides for water oxidation reaction in acidic media. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1135-1142. doi: 10.11862/CJIC.20230459
-
[4]
Kai CHEN , Fengshun WU , Shun XIAO , Jinbao ZHANG , Lihua ZHU . PtRu/nitrogen-doped carbon for electrocatalytic methanol oxidation and hydrogen evolution by water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1357-1367. doi: 10.11862/CJIC.20230350
-
[5]
Yonghui ZHOU , Rujun HUANG , Dongchao YAO , Aiwei ZHANG , Yuhang SUN , Zhujun CHEN , Baisong ZHU , Youxuan ZHENG . Synthesis and photoelectric properties of fluorescence materials with electron donor-acceptor structures based on quinoxaline and pyridinopyrazine, carbazole, and diphenylamine derivatives. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 701-712. doi: 10.11862/CJIC.20230373
-
[6]
Zhaomei LIU , Wenshi ZHONG , Jiaxin LI , Gengshen HU . Preparation of nitrogen-doped porous carbons with ultra-high surface areas for high-performance supercapacitors. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 677-685. doi: 10.11862/CJIC.20230404
-
[7]
Jin CHANG . Supercapacitor performance and first-principles calculation study of Co-doping Ni(OH)2. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1697-1707. doi: 10.11862/CJIC.20240108
-
[8]
Qingtang ZHANG , Xiaoyu WU , Zheng WANG , Xiaomei WANG . Performance of nano Li2FeSiO4/C cathode material co-doped by potassium and chlorine ions. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1689-1696. doi: 10.11862/CJIC.20240115
-
[9]
Yuanchao LI , Weifeng HUANG , Pengchao LIANG , Zifang ZHAO , Baoyan XING , Dongliang YAN , Li YANG , Songlin WANG . Effect of heterogeneous dual carbon sources on electrochemical properties of LiMn0.8Fe0.2PO4/C composites. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 751-760. doi: 10.11862/CJIC.20230252
-
[10]
Peng XU , Shasha WANG , Nannan CHEN , Ao WANG , Dongmei YU . Preparation of three-layer magnetic composite Fe3O4@polyacrylic acid@ZiF-8 for efficient removal of malachite green in water. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 544-554. doi: 10.11862/CJIC.20230239
-
[11]
Hailang JIA , Hongcheng LI , Pengcheng JI , Yang TENG , Mingyun GUAN . Preparation and performance of N-doped carbon nanotubes composite Co3O4 as oxygen reduction reaction electrocatalysts. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 693-700. doi: 10.11862/CJIC.20230402
-
[12]
Fan JIA , Wenbao XU , Fangbin LIU , Haihua ZHANG , Hongbing FU . Synthesis and electroluminescence properties of Mn2+ doped quasi-two-dimensional perovskites (PEA)2PbyMn1-yBr4. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1114-1122. doi: 10.11862/CJIC.20230473
-
[13]
Xinting XIONG , Zhiqiang XIONG , Panlei XIAO , Xuliang NIE , Xiuying SONG , Xiuguang YI . Synthesis, crystal structures, Hirshfeld surface analysis, and antifungal activity of two complexes Na(Ⅰ)/Cd(Ⅱ) assembled by 5-bromo-2-hydroxybenzoic acid ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1661-1670. doi: 10.11862/CJIC.20240145
-
[14]
Yuhao SUN , Qingzhe DONG , Lei ZHAO , Xiaodan JIANG , Hailing GUO , Xianglong MENG , Yongmei GUO . Synthesis and antibacterial properties of silver-loaded sod-based zeolite. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 761-770. doi: 10.11862/CJIC.20230169
-
[15]
Doudou Qin , Junyang Ding , Chu Liang , Qian Liu , Ligang Feng , Yang Luo , Guangzhi Hu , Jun Luo , Xijun Liu . Addressing Challenges and Enhancing Performance of Manganese-based Cathode Materials in Aqueous Zinc-Ion Batteries. Acta Physico-Chimica Sinica, 2024, 40(10): 2310034-. doi: 10.3866/PKU.WHXB202310034
-
[16]
Qiangqiang SUN , Pengcheng ZHAO , Ruoyu WU , Baoyue CAO . Multistage microporous bifunctional catalyst constructed by P-doped nickel-based sulfide ultra-thin nanosheets for energy-efficient hydrogen production from water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1151-1161. doi: 10.11862/CJIC.20230454
-
[17]
Ming ZHENG , Yixiao ZHANG , Jian YANG , Pengfei GUAN , Xiudong LI . Energy storage and photoluminescence properties of Sm3+-doped Ba0.85Ca0.15Ti0.90Zr0.10O3 lead-free multifunctional ferroelectric ceramics. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 686-692. doi: 10.11862/CJIC.20230388
-
[18]
Wen YANG , Didi WANG , Ziyi HUANG , Yaping ZHOU , Yanyan FENG . La promoted hydrotalcite derived Ni-based catalysts: In situ preparation and CO2 methanation performance. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 561-570. doi: 10.11862/CJIC.20230276
-
[19]
Youlin SI , Shuquan SUN , Junsong YANG , Zijun BIE , Yan CHEN , Li LUO . Synthesis and adsorption properties of Zn(Ⅱ) metal-organic framework based on 3, 3', 5, 5'-tetraimidazolyl biphenyl ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1755-1762. doi: 10.11862/CJIC.20240061
-
[20]
Zizheng LU , Wanyi SU , Qin SHI , Honghui PAN , Chuanqi ZHAO , Chengfeng HUANG , Jinguo PENG . Surface state behavior of W doped BiVO4 photoanode for ciprofloxacin degradation. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 591-600. doi: 10.11862/CJIC.20230225
-
[1]
Metrics
- PDF Downloads(0)
- Abstract views(282)
- HTML views(10)