Citation: WU Bao-Ming, YE Nai-Qing, MA Zhen, HAN Jian-Feng, XU Dong. Low Temperature Combustion Synthesis and Electrochemical Performance of xLi₂MnO_3^-(1-x)LiNi_0.7Co_0.3O₂[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(9): 1835-1841. doi: 10.3969/j.issn.1001-4861.2013.00.275 shu

Low Temperature Combustion Synthesis and Electrochemical Performance of xLi₂MnO_3^-(1-x)LiNi_0.7Co_0.3O₂

WU Bao-Ming ¹ ,
YE Nai-Qing ^1,2 ,
MA Zhen ¹ ,
HAN Jian-Feng ¹ ,
XU Dong ¹

1.
1 College of Material Science and Engineering, Guilin University of Technology, Guilin, Guangxi 541004, China;

Received Date: 9 March 2013
Available Online: 19 April 2013
Fund Project: 广西自然科学基金(No.0832256) (No.0832256)广西研究生教育创新计划(No.2011105960805M16)资助项目。 (No.2011105960805M16)

The cathode materials for lithium ion batteries xLi₂MnO_3^-(1-x)LiNi_0.7Co_0.3O₂ were prepared via low temperature combustion process. The structure, morphology and electrochemical performance of the synthesized materials were studied systematically. The optimal preparing conditions and the optimal ratio of Li₂MnO₃ for the cathode materials were studied by single factor experiment. The experimental results show that the synthesized products have α-NaFeO₂ layered structure, sphere-like morphology and excellent electrochemical performance; the optimal conditions to prepare these materials are to reheat the combustion products at 850℃ for 20 h, the optimal ratio of Li₂MnO₃ is x=0.7. The cathode material 0.7Li₂MnO₃-0.3LiNi_0.7Co_0.3O₂ synthesized under such conditions has the highest discharge capacity of 263.1 mAh·g^-1, excellent cycle and rate performance.
- Lithium-ion batteries;cathode material;xLi₂MnO_3^-(1-x)LiNi_0.7Co_0.3O₂;low temperature combustion synthesis
1. [1]
  [1] DU Ke (杜柯), LIU Yan(刘燕), HU Guo-Rong(胡国荣), et al. Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2010, 26(7):1235-1239
2. [2]
  [2] Xu B, Qian D N, Wang Z Y, et al. Mater. Sci. Eng., R, 2012, 73(5-6):51-65
3. [3]
  [3] Xu K, Jie Z F, Li R H, et al. Electrochim. Acta, 2012,60: 130-133
4. [4]
  [4] ZHAO Yu-Juan(赵煜娟), FENG Hai-Lan(冯海兰), ZHAO Chun-Song(赵春松), et al. J. Inorg. Mater.(Wuji Cailiao Xuebao), 2011,26(7): 673-679.
5. [5]
  [5] Li L J, Li X H, Wang Z X, et al. J. Alloys Compd., 2010, 497(1-2):176-181
6. [6]
  [6] Song G M, Wu Y, Xu Q, et al. J. Power Sources, 2010,195 (12):3913-3917
7. [7]
  [7] Zhi X K, Liang G C, Wang L, et al. J. Alloys Compd., 2010, 195(503):370-374
8. [8]
  [8] Cuisinier M, Martin J, Dupré N, et al. Electrochem. Commun., 2010,12(2):238-241
9. [9]
  [9] West W C, Soler J, Ratnakumar B V. J. Power Sources, 2012,204:200-204
10. [10]
  [10] Wang J, Yuan G X, Zhang M H, et al. Electrochim. Acta, 2012,66:61-66
11. [11]
  [11] Numata K, Sakaki C, Yamanaka S. Chem. Lett., 1997,26(8): 725-726
12. [12]
  [12] Johnson C S, Korte S D, Vaughey J T, et al. J. Power Sources, 1999,81-82:491-495
13. [13]
  [13] Ammundsen B, Paulsen J. Adv. Mater., 2001,13(12-13):943-956
14. [14]
  [14] Tabuchi M, Nakashima A, Shigemura H, et al. J. Electro-chem. Soc., 2002,149(5):A509-A524
15. [15]
  [15] Yu C, Li G S, Guan X F, et al. Electrochim. Acta, 2012,61: 216-224
16. [16]
  [16] Tang Z H, Wang Z X, Li X H, et al. J. Power Sources, 2012,204:187-192
17. [17]
  [17] Li J, Klpsch R, Stan M C, et al. J. Power Sources, 2011,196 (10):4821-4825
18. [18]
  [18] Kim D, Gim J, Lim J, et al. Mater. Res. Bull., 2010,45(3): 252-255
19. [19]
  [19] Zhong Z H, Ye N Q, Wang H, et al. Chem. Eng. J., 2011, 175:579-584
20. [20]
  [20] Park K S, Cho M H, Jin S J, et al. J. Power Sources, 2005, 146(1):281-286
21. [21]
  [21] WANG Zhao(王昭), WU Feng(吴锋), SUN Yun-Feng(苏岳锋), et al. Acta Phys.-Chim. Sin.(Wuli Huaxue Xuebao), 2012,28(4):823-830
22. [22]
  [22] ZHONG Yao-Dong(钟耀东), LI Zhi-Tong(李志同), GUO Yan-Gang(郭远刚), et al. J. Mater. Sci. Eng.(Cailiao Kexue Yu Gongchen Xeubao), 2011,29(5):698-710
23. [23]
  [23] Lu Z H, Dahn J R. J. Electrochem. Soc., 2002,149(7):A815-A822
24. [24]
  [24] Lu Z H, Beaulieu L Y, Donaberger R A, et al. J. Electrochem. Soc., 2002,149(6):A778-A791
25. [25]
  [25] Lu Z H, Chen Z H, Dahn J R. Chem. Mater., 2003,15(16): 3214-3220
26. [26]
  [26] Pramanik A, Ghanty C, Majumder S B. Solid State Sci., 2010,12(10):1797-1802
27. [27]
  [27] Johnson C S, Kim J S, Lefief C, et al. Electrochem. Commun., 2004,6(10):1085-1091
28. [28]
  [28] Martha S K, Nanda J, Veith G M, et al. J. Power Sources, 2012,199:220-226
1. [1]
  Qingtang ZHANG , Xiaoyu WU , Zheng WANG , Xiaomei WANG . Performance of nano Li₂FeSiO₄/C cathode material co-doped by potassium and chlorine ions. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1689-1696. doi: 10.11862/CJIC.20240115
2. [2]
  Siyu Zhang , Kunhong Gu , Bing'an Lu , Junwei Han , Jiang Zhou . Hydrometallurgical Processes on Recycling of Spent Lithium-lon Battery Cathode: Advances and Applications in Sustainable Technologies. Acta Physico-Chimica Sinica, 2024, 40(10): 2309028-. doi: 10.3866/PKU.WHXB202309028
3. [3]
  Qi Li , Pingan Li , Zetong Liu , Jiahui Zhang , Hao Zhang , Weilai Yu , Xianluo Hu . Fabricating Micro/Nanostructured Separators and Electrode Materials by Coaxial Electrospinning for Lithium-Ion Batteries: From Fundamentals to Applications. Acta Physico-Chimica Sinica, 2024, 40(10): 2311030-. doi: 10.3866/PKU.WHXB202311030
4. [4]
  Yuanchao LI , Weifeng HUANG , Pengchao LIANG , Zifang ZHAO , Baoyan XING , Dongliang YAN , Li YANG , Songlin WANG . Effect of heterogeneous dual carbon sources on electrochemical properties of LiMn_0.8Fe_0.2PO₄/C composites. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 751-760. doi: 10.11862/CJIC.20230252
5. [5]
  Xinpeng LIU , Liuyang ZHAO , Hongyi LI , Yatu CHEN , Aimin WU , Aikui LI , Hao HUANG . Ga₂O₃ coated modification and electrochemical performance of Li_1.2Mn_0.54Ni_0.13Co_0.13O₂ cathode material. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1105-1113. doi: 10.11862/CJIC.20230488
6. [6]
  Xiaoning TANG , Shu XIA , Jie LEI , Xingfu YANG , Qiuyang LUO , Junnan LIU , An XUE . Fluorine-doped MnO₂ with oxygen vacancy for stabilizing Zn-ion batteries. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1671-1678. doi: 10.11862/CJIC.20240149
7. [7]
  Junke LIU , Kungui ZHENG , Wenjing SUN , Gaoyang BAI , Guodong BAI , Zuwei YIN , Yao ZHOU , Juntao LI . Preparation of modified high-nickel layered cathode with LiAlO₂/cyclopolyacrylonitrile dual-functional coating. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1461-1473. doi: 10.11862/CJIC.20240189
8. [8]
  Zhihuan XU , Qing KANG , Yuzhen LONG , Qian YUAN , Cidong LIU , Xin LI , Genghuai TANG , Yuqing LIAO . Effect of graphene oxide concentration on the electrochemical properties of reduced graphene oxide/ZnS. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1329-1336. doi: 10.11862/CJIC.20230447
9. [9]
  Doudou Qin , Junyang Ding , Chu Liang , Qian Liu , Ligang Feng , Yang Luo , Guangzhi Hu , Jun Luo , Xijun Liu . Addressing Challenges and Enhancing Performance of Manganese-based Cathode Materials in Aqueous Zinc-Ion Batteries. Acta Physico-Chimica Sinica, 2024, 40(10): 2310034-. doi: 10.3866/PKU.WHXB202310034
10. [10]
  Zhiwen HU , Weixia DONG , Qifu BAO , Ping LI . Low-temperature synthesis of tetragonal BaTiO₃ for piezocatalysis. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 857-866. doi: 10.11862/CJIC.20230462
11. [11]
  Qin ZHU , Jiao MA , Zhihui QIAN , Yuxu LUO , Yujiao GUO , Mingwu XIANG , Xiaofang LIU , Ping NING , Junming GUO . Morphological evolution and electrochemical properties of cathode material LiAl_0.08Mn_1.92O₄ single crystal particles. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1549-1562. doi: 10.11862/CJIC.20240022
12. [12]
  Zhihong LUO , Yan SHI , Jinyu AN , Deyi ZHENG , Long LI , Quansheng OUYANG , Bin SHI , Jiaojing SHAO . Two-dimensional silica-modified polyethylene oxide solid polymer electrolyte to enhance the performance of lithium-ion batteries. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 1005-1014. doi: 10.11862/CJIC.20230444
13. [13]
  Qingyan JIANG , Yanyong SHA , Chen CHEN , Xiaojuan CHEN , Wenlong LIU , Hao HUANG , Hongjiang LIU , Qi LIU . Constructing a one-dimensional Cu-coordination polymer-based cathode material for Li-ion batteries. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 657-668. doi: 10.11862/CJIC.20240004
14. [14]
  Kexin Dong , Chuqi Shen , Ruyu Yan , Yanping Liu , Chunqiang Zhuang , Shijie Li . Integration of Plasmonic Effect and S-Scheme Heterojunction into Ag/Ag₃PO₄/C₃N₅ Photocatalyst for Boosted Photocatalytic Levofloxacin Degradation. Acta Physico-Chimica Sinica, 2024, 40(10): 2310013-. doi: 10.3866/PKU.WHXB202310013
15. [15]
  Wendian XIE , Yuehua LONG , Jianyang XIE , Liqun XING , Shixiong SHE , Yan YANG , Zhihao HUANG . Preparation and ion separation performance of oligoether chains enriched covalent organic framework membrane. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1528-1536. doi: 10.11862/CJIC.20240050
16. [16]
  Wenlong LI , Xinyu JIA , Jie LING , Mengdan MA , Anning ZHOU . Photothermal catalytic CO₂ hydrogenation over a Mg-doped In₂O_3-x catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 919-929. doi: 10.11862/CJIC.20230421
17. [17]
  Mingjiao Lu , Zhixing Wang , Gui Luo , Huajun Guo , Xinhai Li , Guochun Yan , Qihou Li , Xianglin Li , Ding Wang , Jiexi Wang . Boosting the performance of LiNi_0.90Co_0.06Mn_0.04O₂ electrode by uniform Li₃PO₄ coating via atomic layer deposition. Chinese Chemical Letters, 2024, 35(5): 108638-. doi: 10.1016/j.cclet.2023.108638
18. [18]
  Yonghui ZHOU , Rujun HUANG , Dongchao YAO , Aiwei ZHANG , Yuhang SUN , Zhujun CHEN , Baisong ZHU , Youxuan ZHENG . Synthesis and photoelectric properties of fluorescence materials with electron donor-acceptor structures based on quinoxaline and pyridinopyrazine, carbazole, and diphenylamine derivatives. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 701-712. doi: 10.11862/CJIC.20230373
19. [19]
  Guangming YIN , Huaiyao WANG , Jianhua ZHENG , Xinyue DONG , Jian LI , Yi'nan SUN , Yiming GAO , Bingbing WANG . Preparation and photocatalytic degradation performance of Ag/protonated g-C₃N₄ nanorod materials. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1491-1500. doi: 10.11862/CJIC.20240086
20. [20]
  Zeyuan WANG , Songzhi ZHENG , Hao LI , Jingbo WENG , Wei WANG , Yang WANG , Weihai SUN . Effect of I₂ interface modification engineering on the performance of all-inorganic CsPbBr₃ perovskite solar cells. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1290-1300. doi: 10.11862/CJIC.20240021

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(449)
HTML views(60)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Low Temperature Combustion Synthesis and Electrochemical Performance of xLi2MnO3-(1-x)LiNi0.7Co0.3O2

Metrics

通讯作者: 陈斌, bchen63@163.com

Low Temperature Combustion Synthesis and Electrochemical Performance of xLi₂MnO_3^-(1-x)LiNi_0.7Co_0.3O₂