Citation: WANG Zhi-Hua, WANG Xin-Peng, ZHAO Sheng-Neng, WANG Qin, MENG Xiang-Gao, JIN Su-Rong. Synthesis, Crystal Structure and Electrochemical Property of a Copper Coordination Polymer Containing Molybdophosphate and 2,2’-Bipyridine-3,3’-dicarboxylic Acid Ligands[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(9): 1877-1881. doi: 10.3969/j.issn.1001-4861.2013.00.271 shu

Synthesis, Crystal Structure and Electrochemical Property of a Copper Coordination Polymer Containing Molybdophosphate and 2,2’-Bipyridine-3,3’-dicarboxylic Acid Ligands

1.
1 School of Science, Wuhan University of Technology, Wuhan 430070, China;

Received Date: 21 July 2012
Available Online: 4 May 2013
Fund Project: 中央高校基本科研业务费专项资金(批准号:2012-Ia-042)资助项目。 (批准号:2012-Ia-042)

A complex {[Cu₄(PMo₁₂O₄₀)(H₂O)₅(H₂bpdc)(Hbpdc)(bpdc)₂]·6H₂O}_n was synthesized under hydrothermal condition using H₃PMo₁₂O₄₀·xH₂O,H₂bpdc, CuSO₄·5H₂O as raw materials and characterized by elemental analysis, IR,TG and single-crystal X-ray diffraction. The title compound consists of polyoxoanion[PMo₁₂O₄₀]^3-, cations[Cu₄(H₂O)₅(H₂bpdc)(Hbpdc)(bpdc)₂]³⁺ and lattice water molecules. The structure refinement indicates that the title compound forms a one-dimensional chain from the polyanions and[Cu₄(H₂O)₅(H₂bpdc)(Hbpdc)(bpdc)₂]³⁺ through O bridge. The cyclic voltammogram indicates that three couples redox waves are observed on the compound modified carbon paste electrode. CCDC: 748899.
- polyoxometalate;copper coordination polymer;hydrothermal synthesis;crystal structure
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沈阳化工大学材料科学与工程学院沈阳 110142