Citation: HU Tuo-Ping, LIU Jian-Feng, LÜ Xu-Yan, XIAO Li-Qun, SONG Jiang-Feng. Syntheses, Crystal Structures and Fluorescent Properties of Two Complexes (Zn(Ⅱ) and Co(Ⅱ)) Based on 2H-Imidazole-4, 5-dicarbonitrile[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(9): 1928-1934. doi: 10.3969/j.issn.1001-4861.2013.00.270
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Two novel metal-organic complexes {[Zn2(IMDN)4(H2O)3]·(H2O)3}n (1) and[Co(IMDN)2(H2O)2]n (2) (HIMDN=2H-imidazole-4,5-dicarbonitrile) based on HIMDN have been synthesized by the method of normal temperature diffusion, and characterized by elemental analysis, FTIR, thermal gravimetric analysis and X-ray diffraction single-crystal structural analysis. The coordination environment of two Zn (Ⅱ) ions is different in 1. One Zn (Ⅱ) ion is four-coordinated and the other is six-coordinated. The central Co (Ⅱ) ion is six-coordinated in 2. Both complexes show one dimensional (1D) chain structure and connected by hydrogen bonds to form three-dimensional structure. Moreover, the fluorescent property of complex 1 had been investigated in the solid state. CCDC: 889348, 1; 889349, 2.
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