Citation: LIANG Han, KANG Jing-Jing, GUO Qiong, ZHANG Qi, FEI Ri-Ling, GUO Zi-Dong, LI Lian-Zhi. Synthesis, Crystal Structure and Spectroscopic Characterization of Two Chiral Oxovanadium Complexes[VO(Naph-Leu)(OMe)(CH3OH)] and[VO(Naph-Phe)(OMe)(CH3OH)][J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(9): 1819-1824. doi: 10.3969/j.issn.1001-4861.2013.00.264
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Two new chiral oxovanadium complexes,[VO(Naph-Leu)(OMe)(CH3OH)] (1) and[VO(Naph-Phe)(OMe)(CH3OH)] (2), (Naph-Leu=Schiff base derived from 2-hydroxy-1-naphthaldehyde and L-leucine, Naph-Phe=Schiff base derived from 2-hydroxy-1-naphthaldehyde and L-phenylalanine), have been synthesized. Single crystal X-ray diffraction analysis showed that complex 1 crystallized in the orthorhombic crystal system, space group P21212 with the cell parameters: a=0.946 80(8) nm, b=3.246 3(3) nm, c=0.662 37(5) nm, V=2.035 9(3) nm3, Z=4, F(000)=864, R1=0.046 3, wR2=0.112 7, S=1.076; and complex 2, crystallized in the monoclinic crystal system, space group P21 with the cell parameters: a=1.113 41(11) nm, b=0.724 09(6) nm, c=1.342 99(12) nm, V=1.047 95(16) nm3, Z=2, F(000)=464, R1=0.035 8, wR2=0.088 8, S=1.024. The IR, UV-Vis and circular dichroism (CD) spectra of the two complexes were measured and discussed. CCDC: 885240, 1; 897188, 2.
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[1]
[1] Vilter H. Phytochemistry, 1984,23:1387-1390
-
[2]
[2] Robson R L, Eady R R, Richardson T H, et al. Nature, 1986, 322:388-390
-
[3]
[3] Dubyak G R, Kleinzeller A. J. Biol. Chem., 1980,255(11): 5306-5312
-
[4]
[4] Thompson K H, Orvig C. J. Inorg. Biochem., 2006,100:1925-1935
-
[5]
[5] Heyliger C E, Tahiliani A G, McNeil J H. Science, 1985, 227:1474-1477
-
[6]
[6] Shechter Y, Karlish S J. Nature, 1980,284:556-558
-
[7]
[7] Thompson K H, McNeill J H, Orvig C. Chem. Rev., 1999, 99:2561-2572
-
[8]
[8] HUANG Yu-Ting(黄玉婷), OUYANG Xing-Mei(欧阳兴梅), Okamura T, et al. Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2005,21(10):1479-1482
-
[9]
[9] Singh H L, Sharma M, Varshney A K. Synth. React. Inorg. Met-Org. Chem., 2000,30:445-456
-
[10]
[10] Nath M, Pokharia S, Yadav R. Coord. Chem. Rev., 2001, 215:99-149
-
[11]
[11] Narla R K, Dong Y, D'Cruz O J, et al. Clin. Cancer Res., 2000,6:1546-1456
-
[12]
[12] Li L Z, Guo Z H, Zhang Q F, et al. Inorg. Chem. Commun., 2010,13(10):1166-1169
-
[13]
[13] Bian L, Li L Z, Zhang Q F, et al. Trans. Met. Chem., 2012, 37:783-790
-
[14]
[14] Xu T, Li L Z, Zhou S F, et al. J. Chem. Crystallogr., 2005, 35(4):263-267
-
[15]
[15] LI Lian-Zhi(李连之), XU Tao(许涛), WANG Da-Qi(王大奇), et al. Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2004, 20(2):236-240
-
[16]
[16] BIAN Lin(边琳), LI Lian-Zhi(李连之), ZHANG Qing-Fu(张 庆富), et al. Acta Chim. Sinica(Huaxue Xuebao), 2011,69 (14):1661-1666
-
[17]
[17] Sheldrick G M. SHELXTL 6.10, Bruker Analytical Instrum-entation, Madison, Wisconsin, USA, 2000.
-
[18]
[18] Kawabe K, Tadokoro M, Hirotsu K, et al. Inorg. Chim. Acta, 2000,305:172-183
-
[19]
[19] ZHAO Xiao-Jing(赵小菁), ZHANG Li-Ying(张丽影), JIN Li-Ming(金黎明), et al. Chinese J. Org. Chem.(Youji Huaxue Xuebao), 2011,31(9):1516-1521
-
[20]
[20] HONG Yong(洪涌), XIAO Jing-Yi(肖静怡), CHEN Shi-Ping (陈世平), et al. Chinese J. Org. Chem.(Youji Huaxue Xuebao), 2008,28(8):1404-1409
-
[21]
[21] LI Xiao-Li(李晓丽), RUAN Wen-Juan(阮文娟), NAN Jing (南晶), et al. Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2005,21(11):1655-1660
-
[1]
-
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