Citation: ZHANG Fu-Xing, KUANG Dai-Zhi, FENG Yong-Lan, WANG Jian-Qiu, YU Jiang-Xi, JIANG Wu-Jiu, ZHU Xiao-Ming. Synthesis, Crystal Structure and Properties of the Tricyclohexyltin R-Mandeliate[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(10): 2099-2104. doi: 10.3969/j.issn.1001-4861.2013.00.263
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The tricyclohexyltin R-mandeliate was synthesized by the reaction of the tricyclohexyltin hydroxide with the R-mandelic acid. Its structure has been determined by X-ray single crystal diffraction. The crystal belongs to orthorhombic with space group P21212 a=0.80641(4) nm, b=1.76868(9) nm, c=1.83479(8) nm, V=2.6169(2) nm3, Z=4, Dc=1.318 g·cm-3, μ(Mo Kα)=9.98 cm-1, F(000)=1080, R1=0.0390, wR2=0.1039. The tin atom has a distorted tetrahedral geometry.The study on title complex has been performed,with quantum chemistry calculation by means of G03Wpackage and taking Lanl2dz basis set. The stabilities of the complex,the orbital energies and composition characteristics of some frontier molecular orbitals have been investigated. The properties of thermogravimetric analysis and photoluminescent behavior and electrochemical of the complex have also been discussed.
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[1] Chandrasekhar V, Thirumoorthi R, Metre R K, et al. J. Organomet. Chem., 2011,696:600-606 [2] Effendy, Marchetti F, Marinelli A, et al. J. Inorg. Chem. Acta., 2011,366,388-393 [3] Hanif M, Hussain M, Ali S, et al. J. Polyhedron., 2010,29: 613-619 [4] ZHANG Xiao-Yan(张晓燕), YANG Guang(杨光), ZHANG Jun(张俊), et al. Chem. J. Chinese Universuties(Gaodeng Xuexiao Huaxue Xuebao), 2010,31(6):1162-1166 [5] Siddiqi Z A, Shahid M, Kumar S, et al. J. Organomet. Chem., 2009,694:3768~3774 [6] Ruan B F, Tian Y U, Zhou H P, et al. J. Chim. Acta., 2011, 365:302-308 [7] ZHANG Fu-Xing(张复兴), KUANG Dai-Zhi(邝代治), WANG Jian-Qiu(王剑秋), et al. Chinese J. Inorg. Chem. (Wuji Huaxue Xuebao), 2006,22(7):1321-1326 [8] YAN Wen-Hua(闫文华), KANG Wan-Li(康万利), LI Jin- Huan(李金环). Chinese J. Appl. Chem.(Yingyong Huaxue), 2007,24(6):660-664 [9] Shujha S, Shah A, Rehman Z U, et al. Eur. J. Med. Chem., 2010,45:2902-2911 [10]ZHANG Fu-Xing(张复兴), KUANG Dai-Zhi(邝代治), WANG Jian-Qiu(王剑秋), et al. Chinese J. Org. Chem. (Youji Huaxue), 2008,28(8):1457-1461 [11]ZHANG Fu-Xing(张复兴), WANG Jian-Qiu(王剑秋), KUANG Dai-Zhi(邝代治), et al. Chinese J. Inorg. Chem. (Wuji Huaxue Xuebao), 2012,28(6):1195-1199 [12]ZHANG Fu-Xing(张复兴), WANG Jian-Qiu(王剑秋), KUANG Dai-Zhi(邝代治), et al. Chinese J. Inorg. Chem. (Wuji Huaxue Xuebao), 2012,28(9):1890-1894. [13]ZHANG Fu-Xing(张复兴), WANG Jian-Qiu(王剑秋), KUANG Dai-Zhi(邝代治), et al. Chinese J. Inorg. Chem. (Wuji Huaxue Xuebao), 2011,27(8):1591-1595 [14]ZHANG Fu-Xing(张复兴), WANG Jian-Qiu(王剑秋), KUANG Dai-Zhi(邝代治), et al. Chinese J. Inorg. Chem. (Wuji Huaxue Xuebao), 2011,27(6):1111-1115 [15]YU Jiang-Xi(庾江喜), KUANG Dai-Zhi(邝代治), YIN Du- Lin(尹笃林), et al. Chinese J. Inorg. Chem. (Wuji Huaxue Xuebao), 2010,26(8):1507-1510 [16]ZHANG Fu-Xing(张复兴), WANG Jian-Qiu(王剑秋), KUANG Dai-Zhi(邝代治), et al. Chinese J. Inorg. Chem. (Wuji Huaxue Xuebao), 2009,25(2):213-217 [17]ZHANG Fu-Xing(张复兴), WANG Jian-Qiu(王剑秋), KUANG Dai-Zhi(邝代治), et al. Chinese. J. Appl. Chem. (Yingyong Huaxue), 2009,26(6):662-666 [18]Zhang F X, Wang J Q, Kuang D Z, et al. Chinese J. Struct. Chem, 2010,29(10):1529-1535
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