Citation: WANG Xiu-Li, ZHAO Dan, TIAN Ai-Xiang, LIU Guo-Cheng. Synthesis, Crystal Structure and Property of a 3D Octamolybdate Coordination Polymer Based on Nickel(Ⅱ)-bis(triazole) System[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(8): 1668-1674. doi: 10.3969/j.issn.1001-4861.2013.00.256
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A new 3D coordination polymer [Ni2(bte)5(γ-Mo8O26)]·5H2O(1) (bte=1, 2-bis(1, 2, 4-triazol-1-y1)ethane), has been synthesized under hydrothermal conditions and characterized by elemental analyses, thermogravimetric analysis (TGA) and single crystal X-ray diffraction. The crystal structure analysis indicates that in compound 1, the bte ligands link the Ni(Ⅱ) ions and construct a unique 2D metal-organic layer. The γ-[Mo8O26]4- anions show two different functions: (i) it acts as a structural directing agent embeding in the 2D metal-organic layer; (ii) it is functionalized by the bte ligands through Mo-N bonds for bridging this 2D metal-organic layer and finally inducing a 3D framework of 1 with the Schläfli symbol of {32·44·54·62·73}{32·46·56·6}2. In addition, the electrochemical and fluorescence properties of the title compound have been studied. CCDC: 881771.
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