Citation: WANG Hui-Sheng, PAN Zhi-Quan. Synthesis, Crystal Structure, and Magnetic Properties of a Mn-Ce Mixed-Metal Complex Containing Benzoic Ligands[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(7): 1459-1464. doi: 10.3969/j.issn.1001-4861.2013.00.255 shu

Synthesis, Crystal Structure, and Magnetic Properties of a Mn-Ce Mixed-Metal Complex Containing Benzoic Ligands

1.
Key Laboratory for Green Chemical Process of Ministry of Education, School of Chemical Engineering & Pharmacy, Wuhan Institute of Technology, Wuhan 430073, China

Received Date: 1 December 2012
Available Online: 9 May 2013
Fund Project: 国家自然科学基金(No.21201136) (No.21201136)武汉工程大学科学研究基金(No.10122012)资助项目。 (No.10122012)

In this paper, a novel Mn-Ce mixed-metal complex [Mn₃Ce₂(O)₅(O₂CPh)₉(CH₃OH)₃]·2CH₃CN (1·2CH₃CN, HO₂CPh is benzoic acid) has been synthesized using the synthetic method of oxidation Mn²⁺ ions by (NH₄)₂Ce(NO₃)₆. The obtained complex were fully characterized by X-ray single crystal structural diffraction, IR, elemental analysis, and magnetic investigation. The structure analysis indicates that the complex crystallizes in triclinic system, P1 space group. In the complex, two Mn⁴⁺ ions, two Ce⁴⁺ ions and four bridging μ₃-O atoms comprise an irregular cubane which is further linked to the other Mn³⁺ ion by another μ₃-O atom. There are no hydrogen bonds but slightly strong π-π stacking interactions between clusters in the crystal cell. Magnetic investigation shows that weak ferromagnetic interactions between Mn ions are present within the cluster, and the values of the spin ground state S and magnetic anisotropy are 5 and-0.31 cm^-1, respectively. The complex do not possess frequency-dependent on alternating-current magnetic susceptibilities. CCDC: 912993.
- Mn-Ce mixed-metal complex;crystal structure;magnetic property;benzoic acid
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沈阳化工大学材料科学与工程学院沈阳 110142