Citation: NIE Xiao-Li, HUO Yan-Ping, LU Tian-Hua, HU Sheng, YI Guo-Bin, YUAN Guo-Zan. Synthesis and Photophysics of Novel Zn Metal Complex Based on 2-Substituted-8-hydroxyquinoline with Trifluoromethylbenzene Group[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(9): 1805-1812. doi: 10.3969/j.issn.1001-4861.2013.00.254 shu

Synthesis and Photophysics of Novel Zn Metal Complex Based on 2-Substituted-8-hydroxyquinoline with Trifluoromethylbenzene Group

1.
1 School of Light Idustry and Chemical Engineering, Guangdong University of Technology, Guangzhou 510006, China;

Received Date: 20 November 2012
Available Online: 12 April 2013
Fund Project: 国家自然科学基金(Nos.21172047, 21001030, 51273048)资助项目。 (Nos.21172047, 21001030, 51273048)

A novel 8-hydroxyquinoline derivative ligand containing trifluoromethylbenzene Group: (E)-2-[2-(2-trifluromethylphenyl)vinyl]-8-hydroxyquinoline(4) and its zinc complex(5) have been synthesized and identified by ¹H NMR, FFIR, MS techniques and elemental analyses. The crystal structure of ligand 4 was determined by X-ray single crystal diffraction, and its network structure is special spiral. The aggregation behavior of Zn(AcO)₂·2H₂O and the ligand 4 in solvents was investigated by UV-Vis, fluorescence spectrum and ¹H NMR spectra titration. Fluorescence emission results showed that the λ_max of ligand 4 and complex 5 were 474 nm and 601 nm, respectively. The fluorescence lifetime of ligand 4 and complex 5 were investigated in the solid state, their values are 15.6 ms and 18.1 ms, respectively. CCDC: 910120.
- 8-hydroxyquinoline;trifluoromethylbenzene;zinc complex;fluorescence;fluorescence lifetime
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沈阳化工大学材料科学与工程学院沈阳 110142