Citation: KONG Zhi-Guo, SUN Xu-Ran, LI He, FAN Yan-Jia, ZHANG Lin. Synthesis, Structure and Characterization of Pb(Ⅱ) Coordination Polymer Constructed by 1,10-Phenanthroline Derivative and Succinic Acid[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(9): 1942-1946. doi: 10.3969/j.issn.1001-4861.2013.00.249 shu

Synthesis, Structure and Characterization of Pb(Ⅱ) Coordination Polymer Constructed by 1,10-Phenanthroline Derivative and Succinic Acid

1.
Department of Chemistry, Jilin Normal University, Key Laboratory of Preparation and Applications of Environmental Friendly Materials (Jilin Normal University), Ministry of Education, Siping, Jilin 136000, China

Received Date: 18 October 2012
Available Online: 28 March 2013
Fund Project: 吉林省科技发展计划项目基金(No.201105085)资助项目。 (No.201105085)

A coordination polymer,[Pb₂(L1)₂(L2)₂] (1) (H₂L1=succinic acid and L2=2-(4-fluorophenyl)-1H-imidazo[4,5-f][1,10]phenanthroline), has been hydrothermally synthesized and characterized by elemental analysis, IR spectroscopy, TGA and single-crystal X-ray diffraction. Crystal data: C₄₆H₃₀F₂N₈O₈Pb₂, monoclinic, space group P2₁/c, a=0.795 40(10) nm, b=2.649 0(3) nm, c=1.996 9(2) nm, β=99.784(2)°, V=4.146 3(9) nm³, Z=4, R=0.038 0, wR=0.0845. In 1, each L1 anion in a bis-chelating mode bridges Pb(Ⅱ) atoms to afford a one-dimensional (1D) chain structure. Neighboring 1D chains are linked together by π-π stackings among L2 ligands to yield a 3D supramolecular architecture. Finally, the N-H…O hydrogen-bonding interactions further stabilize the 3D supramolecular structure of 1.
- crystal structure;coordination polymer;succinic acid;1,10-phenanthroline derivative
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沈阳化工大学材料科学与工程学院沈阳 110142