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Citation: ZHOU Hong, YU Shan-Shan, DUAN Hai-Bao, REN Xiao-Ming. Crystal Structure, Magnetic, Near-Infrared Absorption and Electrochemical Properties of Two [Ni(mnt)2]-Based Compounds[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(7): 1375-1384. doi: 10.3969/j.issn.1001-4861.2013.00.239 shu

Crystal Structure, Magnetic, Near-Infrared Absorption and Electrochemical Properties of Two [Ni(mnt)2]-Based Compounds

  • 1.

    1 School of Biochemical and Environmental Engineering, Nanjing Xiaozhuang University, Nanjing 211171, China;

  • Received Date: 6 August 2012
    Available Online: 5 April 2013

    Fund Project: 国家自然科学基金(No.21171097,21201103)资助项目。 (No.21171097,21201103)

  • Two ion-pair compounds with the formula of (BMIB)[(Ni(mnt)2]2 (1) and (BMIO)[(Ni(mnt)2]2 (2) (mnt=maleonitrile dithiolate, BMIB=1,4-bis(1-methylimidazolium)butane, BMIO=1,8-bis(1-methylimidazolium)octane) were synthesized and characterized structurally. In 1, the [Ni(mnt)2]-form a trimer anions and a mixed column, respectively. The packing structures of 2 are different from 1, the cations and the anions form the irregular alignments. Compound 1 and 2 show remarkable near-IR absorption behavior in the region of 861 and 857 nm respectively. The electrochemical behaviors in the solid state depend on the hydrocarbon chain length in the countercation moiety. Investigations of variable-temperature magnetic susceptibility indicated that 1 shows weak paramagnetic feature from 2 to 400 K; the magnetic susceptibility data were fit to the Curie-Weiss equation. 2 is a spin gap system but its magnetic behavior does not follow the Blaney-Bowers spin dimer model. CCDC: 908109, 1; 908110, 2.
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