Citation: MA Zhi-Hong, WANG Na, GUO Kai-Ming, LIN Jin, ZHENG Xue-Zhong. Synthesis and Structures of Substituted Tetramethylcyclopentadienyl Diruthenium Complexes[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(9): 1882-1886. doi: 10.3969/j.issn.1001-4861.2013.00.237 shu

Synthesis and Structures of Substituted Tetramethylcyclopentadienyl Diruthenium Complexes

1.
1 College of Chemistry & Material Science,Hebei Normal University,Shijiazhuang 050024, China;

Received Date: 11 September 2012
Available Online: 26 February 2013
Fund Project: 河北省自然科学基金(No.B2008000150) (No.B2008000150)河北师范大学重点基金(No.L2009Z06)资助项目。 (No.L2009Z06)

The ligands[C₅Me₄HR] (R=cyclopentyl,cyclohexyl,ⁿPr) reacted with Ru₃(CO)₁₂ in refluxing xylene to give three new substituted tetramethylcyclopentadienyl diruthenium metal carbonyl complexes[(η⁵-C₅Me₄R)Ru(CO)(μ-CO)]₂ (R=cyclopentyl (1),cyclohexyl (2),ⁿPr (3)),respectively. The three new complexes were characterized by IR,elemental analysis and ¹H NMR spectra. The crystal structure of complexes 1 and 2 was determined by X-ray single crystal diffraction. CCDC: 891140, 1; 837727, 2.
- ruthenium carbonyl;cyclopentadienyl;structure;X-ray single crystal diffraction
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沈阳化工大学材料科学与工程学院沈阳 110142