Citation: JI Ning-Ning, ZHANG Ya-Nan, SHI Zhi-Qiang, HE Guo-Fang. Hydrothermal Synthesis, Crystal Structure and Characterization of Two-Dimension Zinc(Ⅱ) Complex Based on p-Chlorophenoxyacetic Acid and 4,4’-Bipyridine[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(9): 1957-1961. doi: 10.3969/j.issn.1001-4861.2013.00.230
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The title complex[Zn(PCPA)2(4,4'-bipy)(H2O)]n with p-chlorophenoxyacetic acid (PCPA), 4,4'-bipyridine (4,4'-bipy) has been hydrothermally synthesized and characterized by elemental analysis, IR spectra, UV spectra, thermal analyses, powder X-ray diffraction and single crystal X-ray diffraction. The zinc(Ⅱ) ion is six-coordinated with two nitrogen atoms from two 4,4'-bipy, three oxygen atoms from three PCPA and one water oxygen atom, forming a slightly distorted octahedral configuration. The complex molecules form a 2D layer structure through bridged PCPA and 4,4'-bipy which is consolidated by O-H…O hydrogen bonds. CCDC: 850113.
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